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Citation: CHI Yang, SUN Jiao, GUO Sheng-Ping. Synthesis, Crystal Structure and Magnetic Property of Ternary Neodymium Zirconium Sulfide, Nd2ZrS5[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 713-717. doi: 10.14102/j.cnki.0254-5861.2011-0955 shu

Synthesis, Crystal Structure and Magnetic Property of Ternary Neodymium Zirconium Sulfide, Nd2ZrS5

  • 1.

    College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

  • Corresponding author: GUO Sheng-Ping, 
  • Received Date: 28 August 2015
    Available Online: 17 November 2015

    Fund Project: The project was supported by the National Natural Science Foundation of China (No. 21272052, 21472034) (No. 21272052, 21472034) Natural Science Foundation of Hebei Province (No. 14272604D B2014208138) (No. 14272604D B2014208138) the Foundation of the Education Department of Hebei Province (No. ZH2012025, ZD2014017) (No. ZH2012025, ZD2014017)

  • A new ternary neodymium zirconium sulfide Nd2ZrS5 was synthesized by high-temperature solid-state reaction and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the orthorhombic space group Pnma (No. 62) belonging to the Y2HfS5 structure-type with a = 11.461(4), b = 8.009(3), c = 7.315(3) Å, Z = 2 and V = 671.5(4) Å3. Its structure features NdS8 and ZrS7 polyhedra-constructed a 3-D network. The data of magnetic susceptibility indicate its antiferromagnetic-like behavior without magnetic order down to 2 K.
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    1. [1]

      (1) (a) Mitchell, K.; Ibers, J. A. Rare-earth transition-metal chalcogenides. Chem. Rev. 2002, 102, 1929-1952.

    2. [2]

      (b) Choudhury, A.; Dorhout, P. K. Noncentrosymmetric rare-earth copper gallium chalcogenides RE3CuGaCh7 (RE = La-Nd; Ch= S, Se): an unexpected combination. Inorg. Chem. 2015, 54, 1055-1065.

    3. [3]

      (c) Guo, S. P.; Wang, G. E.; Zhang, M. J.; Wu, M. F.; Liu, G. N.; Jiang, X. M.; Guo, G. C.; Huang, J. S. Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors. Dalton Trans. 2013, 42, 2679-2682.

    4. [4]

      (2) (a) Donohue, P. C.; Jeitschko, W. The preparation of Ln2MX5 where Ln = rare earths, M = Zr and Hf, and X = S, Se. Mat. Res. Bull. 1974, 9, 1333-1336.

    5. [5]

      (b) Moseley, P. T.; Brown, D.; Whittaker, B. The crystal structure of triuranium pentaselenide. Acta Cryst. B 1972, 28, 1816-1821.

    6. [6]

      (c) Deszkiewicz, M.; Gulay, L. D.; Shemet, V. Y. Crystal architecture of R2SnS5 (R = Pr, Nd, Gd and Tb): crystal structure relationships in chalcogenides. Acta Crystallogr. B 2008, 64, 172-176.

    7. [7]

      (3) (a) Jaulmes, S. Structure cristalline du sulfure d'étain et de lanthane, La2SnS5. Acta Crystallogr. B 1974, 30, 2283-2285.

    8. [8]

      (b) Julien-Pouzol, M.; Jaulmes, S. Structure du pentasulfure de disamarium et d'étain. Acta Crystallogr. B 1979, 35, 2672-2674.

    9. [9]

      (c) Jaulmes, S.; Julien-Pouzol, M.; Laruelle, P.; Guittard, M. Structure du pentasulfure d'europium et d'étain Eu2SnS5. Acta Crystallogr. B 1982, 38, 79-82.

    10. [10]

      (4) Gauthier, G.; Jobic, S.; Evain, M.; Koo, H. J.; Whangbo, M. H.; Fouassier, C.; Brec, R. Syntheses, structures, and optical properties of yellow Ce2SiS5, Ce6Si4S17, and Ce4Si3S12 materials. Chem. Mater. 2003, 15, 828-837.

    11. [11]

      (5) Mazurier, A.; Etienne, J. Structure cristalline de La2GeS5. Acta Crystallogr. B 1973, 29, 817-821.

    12. [12]

      (6) Schmitz, D. Vergleich der kristallstrukturen von (NH4)3ZnCl5 und Ba3SiS5. Acta Crystallogr. B 1981, 37, 518-525.

    13. [13]

      (7) Johrendt, D.; Tampier, M. Strontium selenogermanate(III) and barium selenogermanate (II, IV): synthesis, crystal structures, and chemical bonding. Chem. Eur. J. 2000, 6, 994-998.

    14. [14]

      (8) (a) Rigaku, CrystalClear Version 1.3.5, Rigaku Corporation, 2002; (b) Rigaku, CrystalStructure Version 3.6.0, Rigaku Corporation 2002.

    15. [15]

      (9) Siemens, SHELXTLTM Version 5 Reference Manual, Siemens Energy & Automation Inc., Madison, Wisconsin, USA 1994.

    16. [16]

      (10) Boudreaux, E. A.; Mulay, J. N. Theory and Application of Molecular Paramagnetism. J. Wiley and Sons, New York 1976.

    17. [17]

      (11) Guo, S. P.; Guo, G. C.; Wang, M. S.; Zou, J. P.; Xu, G.; Wang, G. J.; Long, X. F.; Huang, J. S. A series of new infrared NLO semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1-y)S7, and Al0.33Sm3SiS7. Inorg. Chem. 2009, 48, 7059-7065.

    18. [18]

      (12) Guo, S. P.; Guo, G. C.; Wang, M. S.; Zou, J. P.; Zeng, H. Y.; Cai, L. Z.; Huang, J. S. A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate. Chem. Commun. 2009, 29, 4366-4368.

    19. [19]

      (13) Guo, S. P.; Guo, G. C. Crystal structure and magnetic and photocatalytic properties of a new ternary rare-earth mixed chalcogenide, Dy4S4Te3. J. Mater. Chem. A 2014, 2, 20621-20628.

    20. [20]

      (14) Daszkiewicz, M.; Marchuk, O. V.; Gulay, L. D.; Kaczorowski, D. Crystal structures and magnetic properties of R2PbSi2S8 (R = Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho), R2PbSi2Se8 (R = La, Ce, Pr, Nd, Sm, Gd) and R2PbGe2S8 (R = Ce, Pr) compounds. J. Alloys Compd. 2012, 519, 85-91.

    21. [21]

      (15) (a) Smart, J. S. Effective Field Theories of Magnetism. Saunders: Philadelphia, PA 1966.

    22. [22]

      (b) Kittel, C. Introduction to Solid State Physics, 7th ed.; John Wiley and Sons: Hoboken, NJ 1996.

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