Citation: CHEN Xin, ZHANG Ming-Xing, HUANG Kun-Lin. A Novel Chiral Cd-organic Network Based on Flexible Coupled Cinnamic Acid[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 805-810. doi: 10.14102/j.cnki.0254-5861.2011-0954 shu

A Novel Chiral Cd-organic Network Based on Flexible Coupled Cinnamic Acid

1.
Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

Corresponding author: HUANG Kun-Lin,
Received Date: 21 August 2015
Available Online: 11 December 2015
Fund Project:

A new metal-organic network, [Cd(CH₃OH)₂(epa)]_n (1), was synthesized from an achiral coupled cinnamic acid, 3,3'-((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))diacrylic acid (H₂epa), and Cd(NO₃)₂·4H₂O under solvothermal conditions. The complex crystallizes in orthorhombic, space group P2₁2₁2 with a = 9.8286(8), b = 21.0004(16), c = 5.5169(4) Å, V = 1138.71(15) Å³, M_r = 528.81, D_c = 1.542 Mg/cm³, F(000) = 536, Z = 2, the final R = 0.0345 and wR = 0.1101 for 2006 observed reflections (I> 2σ(I)). In 1 the epa²⁺ anions alternately bridge the Cd(II) cations to form a one-dimensional (1D) infinite homochiral helical chain of [Cd(epa)]_n. The chiral homohelical chains via hydrogen bonds formed a two-dimensional (2D) network. The photoluminescence of 1 was also investigated in solid state at ambient temperature.
- helical motif,
- chirality,
- coupled cinnamic acid,
- cadmium
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沈阳化工大学材料科学与工程学院沈阳 110142