Citation: LU Ying-Bing, GU Ya-Bin, LONG Jia-Ting, XIE Yong-Rong, LIU Hui-Jin. Syntheses, Crystal Structures and Photoluminescent Properties of Two New 1-D d¹⁰ Metal Complexes Based on Tetrazole 1-Acetato Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1777-1786. doi: 10.14102/j.cnki.0254-5861.2011-0943 shu

Syntheses, Crystal Structures and Photoluminescent Properties of Two New 1-D d¹⁰ Metal Complexes Based on Tetrazole 1-Acetato Ligand

1.
a Jiangxi Key Laboratory of Function of Materials Chemistry, College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 17 August 2015
Available Online: 20 September 2016
Fund Project: This project was supported by the NSF of Jiangxi Province (51302041) (51302041) the Fujian Institute of Research on the Structure of Matter (20140014) (20140014)

Two new tetrazole 1-acetato complexes,[Ag(1-tza)(phen)]_∞ (1) and [Cd(1-tza)₂(2,2'-bipy)]_∞ (2) (1-Htza=tetrazole 1-acetato, phen=1,10-phenanthroline, 2,2'-bipy=2,2'-bipyridine), have been synthesized by solvothermal synthesis and structurally characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. Complex 1 shows a 1-D chained structure, while the structure of 2 contains two 1-D chains, which is the first 1-tza-based complex containing three different coordination modes of the 1-tza ligand. The aromatic stacking effects play an important role in the formation of supramolecular frameworks of these two complexes. Photoluminescent studies show that the two complexes exhibit efficient luminescence. In addition, optical diffuse reflectance spectra and thermogravimetric analyses of 1 and 2 have also been investigated.
- silver(I),
- cadmium(II),
- crystal structure,
- tetrazole 1-acetato,
- photoluminescence
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