Citation: ZHANG Qing, LI Jian-Yue, YU Ying-Hui, HOU Guang-Feng, GAO Jin-Sheng. Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 818-826. doi: 10.14102/j.cnki.0254-5861.2011-0940 shu

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II

a.
a. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;
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b. Engineering Research Centre of Pesticide, Heilongjiang University, Harbin 150080, China

Corresponding author: YU Ying-Hui,
Received Date: 11 August 2015
Available Online: 12 November 2015
Fund Project: Support by National Natural Science Foundation of China (21371052) (21371052)the Scientific Research Fund of Heilongjiang Provincial Education Department (12531512) (12531512)

A novel tetrazylphosphonate ligand, namely ethyl 4-(2-ethyl-2H-1,2,3,4-tetrazol-5-yl) benzylphosphonate (Et-L), was designed and successfully achieved from p-cyano benzyl chloride, based on which a zinc coordination polymer (1) with a 2D layer structure has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The colorless block crystals of H₂L·H₂O were also obtained under the same hydrothermal conditions, which belongs to monoclinic system, space group P2₁/c with a = 13.3141(7), b = 5.1650(3), c = 21.9839(18) Å, β = 115.307(5)°, V = 1366.69(15) Å³, Z = 4, D_c = 1.391 mg/cm^-3, M_r = 349.58, F(000) = 600, R = 0.0748 and wR = 0.1917 for 2392 observed reflections (I > 2σ(I)). The colorless block crystals of complex 1 ([Zn(L)(H₂O)]_n) also belong to monoclinic system, space group P2₁/c with a = 22.7464(10), b = 6.0430(3), c = 9.7704(4) Å, β = 92.525(4)°, V = 1341.70(10) Å³, Z = 4, D_c = 1.731 mg/cm^-3, M_r = 349.58, F(000) = 712, R = 0.0596 and wR = 0.1688 for 2357 observed reflections (I > 2σ(I)). Only the oxygen atoms of phosphonic group are coordinated with the metal zinc probably because the hydrogen atom of tetrazole has been substituted by ethyl group. Photoluminescence properties of the complex are also investigated.
- Zn^II complex,
- crystal structure,
- coordination polymer
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on ZnII

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通讯作者: 陈斌, bchen63@163.com

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II