Citation: ZHANG Qing, LI Jian-Yue, YU Ying-Hui, HOU Guang-Feng, GAO Jin-Sheng. Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 818-826. doi: 10.14102/j.cnki.0254-5861.2011-0940 shu

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II

a.
a. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;
b.
b. Engineering Research Centre of Pesticide, Heilongjiang University, Harbin 150080, China

Corresponding author: YU Ying-Hui,
Received Date: 11 August 2015
Available Online: 12 November 2015
Fund Project: Support by National Natural Science Foundation of China (21371052) (21371052)the Scientific Research Fund of Heilongjiang Provincial Education Department (12531512) (12531512)

A novel tetrazylphosphonate ligand, namely ethyl 4-(2-ethyl-2H-1,2,3,4-tetrazol-5-yl) benzylphosphonate (Et-L), was designed and successfully achieved from p-cyano benzyl chloride, based on which a zinc coordination polymer (1) with a 2D layer structure has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The colorless block crystals of H₂L·H₂O were also obtained under the same hydrothermal conditions, which belongs to monoclinic system, space group P2₁/c with a = 13.3141(7), b = 5.1650(3), c = 21.9839(18) Å, β = 115.307(5)°, V = 1366.69(15) Å³, Z = 4, D_c = 1.391 mg/cm^-3, M_r = 349.58, F(000) = 600, R = 0.0748 and wR = 0.1917 for 2392 observed reflections (I > 2σ(I)). The colorless block crystals of complex 1 ([Zn(L)(H₂O)]_n) also belong to monoclinic system, space group P2₁/c with a = 22.7464(10), b = 6.0430(3), c = 9.7704(4) Å, β = 92.525(4)°, V = 1341.70(10) Å³, Z = 4, D_c = 1.731 mg/cm^-3, M_r = 349.58, F(000) = 712, R = 0.0596 and wR = 0.1688 for 2357 observed reflections (I > 2σ(I)). Only the oxygen atoms of phosphonic group are coordinated with the metal zinc probably because the hydrogen atom of tetrazole has been substituted by ethyl group. Photoluminescence properties of the complex are also investigated.
- Zn^II complex,
- crystal structure,
- coordination polymer
1. [1]
  (1) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001-1033.
2. [2]
  (2) Mckinlay, A. C.; Morris, R. E.; Horcajada, P.; Férey, G.; Gref, R.; Couvreur, P.; Serre, C. BioMOFs: metal-organic frameworks for biological and medical applications. Angew. Chem., Int. Ed. 2010, 49, 6260-6266.
3. [3]
  (3) Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D. W. Hydrogen storage in metal-organic frameworks. Chem. Rew. 2012, 112, 782-835.
4. [4]
  (4) Wen, B.; Wang, X. D.; Yu, Y. H.; Gao, J. S.; Hou, G. F. Synthesis, structure and magnetic property of one Ni^IIbased coordination polymer. Chin. J. Struct. Chem. 2014, 33, 1603-1609.
5. [5]
  (5) Pachfule, P.; Banerjee, R. Porous nitrogen rich cadmium-tetrazolate based metal organic framework (MOF) for H₂ and CO₂ uptake. Cryst. Growth Des. 2011, 11, 5176-5181.
6. [6]
  (6) Li, J. R.; Tao, Y.; Yu, Q.; Bu, X. H. A pcu-type metal-organic framework with spindle [Zn₇(OH)₈]⁶⁺ cluster as secondary building units. Chem. Commun. 2007, 1527-1529.
7. [7]
  (7) Hu, T. L.; Tao, Y.; Chang, Z.; Bu, X. H. Zinc(II) complexes with a versatile multitopic tetrazolate-based ligand showing various structures: impact of reaction conditions on the final product structures. Inorg. Chem. 2011, 50, 10994-11003.
8. [8]
  (8) Cao, D. K.; Hou, S. Z.; Li, Y. Z.; Zheng, L. M. Lanthanide carboxyphosphonates Ln(O₃PCH₂-NC₅H₉-COO)(H₂O)₂·xH₂O with open framework structures containing parallelogram-like channels. Cryst. Growth Des. 2009, 9, 4445-4449.
9. [9]
  (9) Fu, R. B.; Hu, S. M.; Wu, X. T. Mix-solvothermal syntheses, characterization, and properties of new zinc diphosphonates with Zn-O-P chains, layers, and 3D frameworks. Cryst. Growth Des. 2007, 7, 1134-1144.
10. [10]
  (10) Mao, J. G.; Wang, Z. K.; Clearfield, A. Synthesis, characterization, and crystal structures of two divalent metal diphosphonates with a layered and a 3D network structure. Inorg. Chem. 2002, 41, 2334-2340.
11. [11]
  (11) Tang, S. F.; Song, J. L.; Li, X. L.; Mao, J. G. Luminescent lanthanide(III) carboxylate-phosphonates with helical tunnels. Cryst. Growth Des. 2006, 6, 2322-2326.
12. [12]
  (12) Kong, D. Y.; Clearfield, A. Supramolecular hydrogen-bonded frameworks from 6-phosphonopyridine-2-carboxylic acid and transition metal ions. Cryst. Growth Des. 2005, 5, 1263-1270.
13. [13]
  (13) Kedrowski, S. M. A.; Dougherty, D. A. Room-temperature alternative to the Arbuzov reaction: the reductive deoxygenation of acyl phosphonates. Org. Lett. 2010, 12, 3990-3993.
14. [14]
  (14) Crosignani, S.; Jorand-Lebrun, C.; Campbell, G.; Pretre, A.; Grippi-Vallotton, T.; Quattropani, A.; Bouscary-Desforges, G.; Bombrun, A.; Missotten, M.; Humbert, Y.; Fremaux, C.; Paquet, M.; El Harkani, K.; Bradshaw, C. G.; Cleva, C.; Abla, N.; Da , H.; Schott, O.; Pittet, P. A.; Arrighi, J. F.; Gaudet, M.; Johnson, Z. Discovery of a novel series of CRTH2 (DP2) receptor antagonists devoid of carboxylic acids. Med. Chem. Lett. 2011, 2, 938-942.
15. [15]
  (15) Sheldrick, G. M. A short history of SHELX. Acta Cryst. 2008, A64, 112-122.
16. [16]
  (16) Blatov, V. A. IUCr CompComm Newsletter, 2006, 7, 4; http://www.topos.ssu.samara.ru.
17. [17]
  (17) Fu, R. B.; Hu, S. M.; Wu, X. T. New 3D metal phosphonates with bright tunable luminescence for the reversible sensing of nitrobenzene. Cryst. Eng. Comm. 2012, 14, 5761-5764.
18. [18]
  (18) Feng, R.; Yan, C. F.; Chen, L.; Wu, M. Y.; Jiang, F. L.; Hong, M. C. Synthesis and crystal structure of a new Zn(II) complex exhibiting strong luminescence. Chin. J. Struct. Chem. 2010, 29, 57-62.
19. [19]
  (19) Huang, N. N.; Wang, X. D.; Yu, Y. H.; Gao, J. S.; Hou, G. F. A three-dimensional Zn^II based coordination polymer with 2-fold interpenetrated topology displaying luminescent property. Chin. J. Struct. Chem. 2015, 34, 292-298.
20. [20]
  (20) Liu, H. Y. Synthesis and properties of functional phosphonate transition metal coordination compounds. Nankai University Dissertation 2009.
21. [21]
  (21) Song, J. L.; Zhao, H. H.; Mao, J. G.; Dunbar, K. R. New types of layered and pillared layered metal carboxylate-phosphonates based on the 4,4'-bipyridine ligand. Chem. Mater. 2004, 16, 1884-1889.
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
3. [3]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
4. [4]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
7. [7]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
8. [8]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
9. [9]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
10. [10]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
11. [11]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
12. [12]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
13. [13]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
14. [14]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
15. [15]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
16. [16]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
17. [17]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
18. [18]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
19. [19]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
20. [20]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(701)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on ZnII

Metrics

通讯作者: 陈斌, bchen63@163.com

Syntheses and Structures of a New Tetrazylphosphonate Ligand and the Coordination Polymer Based on Zn^II