Citation: ZHU Xiao-Fei, XIE Xiao-Yan, BI Yan-Feng, YANG Yu, ZHOU De-Feng. A New Europium Coordination Compound Supported by 4,6-Dibenzoylisophthalic Acid LigandsTwo Metal-organic Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 758-764. doi: 10.14102/j.cnki.0254-5861.2011-0938 shu

A New Europium Coordination Compound Supported by 4,6-Dibenzoylisophthalic Acid LigandsTwo Metal-organic Coordination Polymers

a.
a. School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China;
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b. College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China

Corresponding author: BI Yan-Feng,
Received Date: 10 August 2015
Available Online: 19 November 2015
Fund Project: the Graduate Student (B2015209299)

A unique metal-organic framework (MOF) [Eu₂(L)₃(phen)₂]_n (1, H₂L = 4,6-diben-zoylisophthalic acid, phen = 1,10-phenanthroline) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray analysis, elemental analyses, powder X-ray diffraction, TGA measurement as well as IR spectra. The crystal is of triclinic system, space group P , C₉₀H₅₂Eu₂N₄O₁₈, M_r = 1781.32, a = 9.8697(4), b = 16.7466(6), c = 22.2556(10) Å, α = 87.113(3), β = 77.575(5), γ = 89.458(3)°, V = 3587.8(3) Å³, Z = 2, D_c = 1.649 g/cm³, F(000) = 1780, μ(MoKa) = 1.813 mm^-1, R_int = 0.0181, R = 0.0260 and wR = 0.0592 for 14000 observed reflections with I> 2σ(I). X-ray analysis shows that the title compound exhibits a 2D layer structure linked by L ligands with two coordination modes and two distinguished conformations, and further linked into a 3D supramolecular architecture through C–H…O weak interactions between hydrogen of phen phenyl ring and the carboxylate oxygen atom of adjacent sheets. In addition, the luminescence property of 1 was investigated.
- 4,
- 6-dibenzoylisophthalic acid,
- europium,
- coordination modes,
- hydrothermal
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