Citation:
LI Wen-Bin, GAO Zhu-Qing, GU Jin-Zhong. Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands[J]. Chinese Journal of Structural Chemistry,
;2016, 35(2): 257-263.
doi:
10.14102/j.cnki.0254-5861.2011-0929
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One new mixed-ligand coordination polymer, namely [Co2(btc)(bpdc)0.5(py)3]n (1), was hydrothermally synthesized using biphenyl-2,4,4'-tricarboxylic acid (H3btc) as a main building block, along with two auxiliary ligands (H2bpdc = 2,2'-bipyridine-5,5'-dicarboxylic acid and py = pyridine). The product 1 was characterized by IR spectroscopy, elemental, thermogravimetric, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt(II) units. Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co(II) ions.
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[1]
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