Citation: LI Wen-Bin, GAO Zhu-Qing, GU Jin-Zhong. Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 257-263. doi: 10.14102/j.cnki.0254-5861.2011-0929 shu

Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands

1.
a School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;
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b College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GAO Zhu-Qing,
Received Date: 5 August 2015
Available Online: 12 October 2015
Fund Project: This project was supported by the Natural Science Foundation of Shanxi Province (No. 2013011011-6) (No. 2013011011-6)

One new mixed-ligand coordination polymer, namely [Co₂(btc)(bpdc)_0.5(py)₃]_n (1), was hydrothermally synthesized using biphenyl-2,4,4'-tricarboxylic acid (H₃btc) as a main building block, along with two auxiliary ligands (H₂bpdc = 2,2'-bipyridine-5,5'-dicarboxylic acid and py = pyridine). The product 1 was characterized by IR spectroscopy, elemental, thermogravimetric, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt(II) units. Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co(II) ions.
- metal-organic framework,
- carboxylate ligand,
- magnetic properties
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