Citation: LI Wen-Bin, GAO Zhu-Qing, GU Jin-Zhong. Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(2): 257-263. doi: 10.14102/j.cnki.0254-5861.2011-0929 shu

Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands

  • Corresponding author: GAO Zhu-Qing, 
  • Received Date: 5 August 2015
    Available Online: 12 October 2015

    Fund Project: This project was supported by the Natural Science Foundation of Shanxi Province (No. 2013011011-6) (No. 2013011011-6)

  • One new mixed-ligand coordination polymer, namely [Co2(btc)(bpdc)0.5(py)3]n (1), was hydrothermally synthesized using biphenyl-2,4,4'-tricarboxylic acid (H3btc) as a main building block, along with two auxiliary ligands (H2bpdc = 2,2'-bipyridine-5,5'-dicarboxylic acid and py = pyridine). The product 1 was characterized by IR spectroscopy, elemental, thermogravimetric, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt(II) units. Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co(II) ions.
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    1. [1]

      (1) Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Van Duyne, R. P.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105-1125.

    2. [2]

      (2) Anderson, J. S.; Gallagher, A. T.; Mason, J. A.; Harris, T. D. A five-coordinate heme dioxygen adduct isolated within a metal-organic framework. J. Am. Chem. Soc. 2014, 136, 16489-16492.

    3. [3]

      (3) Cowan, M. G.; Miller, R. G.; Southon, P. D.; Price, J. R.; Yazaydin, Q.; Lane, J. R.; Kepert, C. J.; Brooker, S. Selective gas adsorption in a pair of robust isostructural MOFs differing in framework charge and anion loading. Inorg. Chem. 2014, 53, 12076-12083.

    4. [4]

      (4) Stck, N.; Biawas, S. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2012, 112, 933-969.

    5. [5]

      (5) Cheon, Y. E.; Suh, M. P. Enhanced hydrogen storage by palladium nanoparticles fabricated in a redox-active metal-organic framework. Angew. Chem. Int. Ed. 2009, 48, 2899-2903.

    6. [6]

      (6) Chen, B.; Xiang, S.; Qian, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115 -1124.

    7. [7]

      (7) Dong, X. Y.; Hu, X. P.; Yao, H. C.; Zang, S. Q.; Hou, H. W.; Mak, T. C. Alkaline earth metal (Mg, Sr, Ba)-organic frameworks based on 2,2',6,6'-tetracarboxybiphenyl for proton conduction. Inorg. Chem. 2014, 53, 12050-12057.

    8. [8]

      (8) Karmakar, S.; Maity, D.; Mardanya, S.; Baitalik, S. Multichromophoric bimetallic Ru(II) terpyridine complexes based on pyrenyl-bis-phenylimidazole spacer: synthesis, photophysics, spectroelectrochemistry, and TD-DFT calculations. Inorg. Chem. 2014, 53, 12036-12049.

    9. [9]

      (9) Ordonez, C.; Fonari, M.; Lindline, J.; Wei, Q.; Timofeeva, T. How structure-directing cations tune the fluorescence of metal-organic frameworks. Cryst. Growth Des. 2014, 14, 5452-5465.

    10. [10]

      (10) Sun, J. K.; Chen, C.; Cai, L. X.; Ren, C. X.; Tan, B.; Zhang, J. Mechanical grinding of a single-crystalline metal-organic framework triggered emission with tunable violet-to-orange luminescence. Chem. Commun. 2014, 50, 15956-15959.

    11. [11]

      (11) Zhang, Q.; Yu, J. C.; Cai, J. F.; Song, R. J.; Cui, Y. J.; Yang, Y.; Chen, B. L.; Qian, G. D. A porous metal-organic framework with -COOH groups for highly efficient pollutant removal. Chem. Commun. 2014, 50, 14455-14459.

    12. [12]

      (12) Cui, L. T.; Niu, Y. F.; Han, J.; Zhao, X. L. Ancillary ligand-assisted assembly of C3-symmetric 4,4',4''-nitrilotribenzoic acid with divalent Zn2+ ions: syntheses, topological structures, and photoluminescence properties. J. Solid State Chem. 2015, 227, 155-164.

    13. [13]

      (13) Sen, S.; Neogi, S.; Rissanen, K.; Bharadwaj, P. K. Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework. Chem. Commun. 2015, 51, 3173-3176.

    14. [14]

      (14) Zhang, J.; Zheng, B.; Zhao, T.; Li, G.; Huo, Q.; Liu, Y. Topological diversities and luminescent properties of lanthanide metal-organic frameworks based on a tetracarboxylate ligand. Cryst. Growth Des. 2014, 14, 2394-2400.

    15. [15]

      (15) Zang, S. Q.; Dong, M. M.; Fan, Y. T.; Hou, H. W.; Mak, T. C. T. Four cobaltic coordination polymers based on 5-iodo-isophthalic acid: halogen-related interaction and solvent effect. Cryst. Growth Des. 2012, 12, 1239-1246.

    16. [16]

      (16) Mu, Y.; Xie, J.; Ran, Y.; Han, B.; Qin, G. F. A series of entangled Cd(II) coordination polymers assembled from different dicarboxylate acids and a flexible imidazole-based ligand. Polyhedron 2015, 89, 20-28.

    17. [17]

      (17) Gu, J. Z.; Kirillov, A. M.; Wu, J.; Lv, D. Y.; Tang, Y.; Wu, J. C. Synthesis, structural versatility, luminescent and magnetic properties of a series of coordination polymers constructed from biphenyl-2,4,4'-tricarboxylate and different N-donor ligands. CrystEngComm. 2013, 15, 10287-10303.

    18. [18]

      (18) Gu, J. Z.; Gao, Z. Q.; Tang, Y. pH and auxiliary ligand influence on the structural variations of 5(2'-carboxylphenyl) nicotate coordination polymers. Cryst. Growth Des. 2012, 12, 3312-3323.

    19. [19]

      (19) Gao, Z. Q.; Li, H. J.; Alexander, M. K.; Gu, J. Z. Syntheses, crystal structures and luminescent properties of lead(II) and cadmium(II) coordination polymers constructed from biphenyl-2,5,3'-tricarboxylate. Chin. J. Struct. Chem. 2014, 33, 888-896.

    20. [20]

      (20) Tian, D.; Pang, Y.; Zhou, Y. H.; Guan, L.; Zhang, H. A series of complexes based on biphenyl-2,5,2',5'-tetracarboxylic acid: syntheses, crystal structures, luminescent and magnetic properties. CrystEngComm. 2011, 13, 957-966.

    21. [21]

      (21) Wen, L. L.; Wang, F.; Leng, X. K.; Wang, C. G.; Wang, L. Y.; Gong, J. M.; Li, D. F. Efficient detection of organophosphate pesticide based on a metal-organic framework derived from biphenyltetracarboxylic acid. Cryst. Growth Des. 2010, 10, 2835-2838.

    22. [22]

      (22) Saines, P. J.; Barton, P. T.; Jain, P.; Cheetham, A. K. Structures and magnetic properties of Mn and Co inorganic-organic frameworks with mixed linear dicarboxylate ligands. CrystEngComm. 2012, 14, 2711-2720.

    23. [23]

      (23) Wu, G. Y.; Ren, Y. X.; Yin, Z.; Sun, F.; Zeng, M. H.; Kurmoo, M. Effects of substituent groups on the structures and luminescence properties of 2D/3D Cd(II) complexes with mixed rigid and flexible carboxylate ligands. RSC Adv. 2014, 4, 24183-24188.

    24. [24]

      (24) Sheldrick, G. M. SHELXS 97, Program for Solution of Crystal Structure. University of Göttingen, Germany 1997.

    25. [25]

      (25) Sheldrick, G. M. SHELXL 97, Program for Refinement of Crystal Structure. University of Göttingen, Germany 1997.

    26. [26]

      (26) Zhao, Y.; He, L. L.; Xu, H.; Li, X. Y.; Zang, S. Q. Two metal-organic coordination polymers assembled from a flexible iodo-dicarboxylate ligand and N-donor ancillary ligands. Inorg. Chim. Acta 2013, 404, 201-205.

    27. [27]

      (27) Jing, X. H.; Yi, X. C.; Gao, E. Q.; Blatov, V. A. Synthesis, structure, topology and magnetic properties of cobalt(II) coordination polymers with 2-nitrobiphenyl-4,4'-dicarboxylic acid and bis(pyridyl) ligands. Dalton Trans. 2012, 41, 14316-14328.

    28. [28]

      (28) Zhang, Q. F.; Zhang, H. N.; Zeng, S. Y.; Sun, D. Z.; Zhang, C. A chain-based 2D cobalt(II) coordination polymer with a “crab-like” flexible dicarboxylate ligand: a weak ferromagnetic single-chain magnet. Chem. Asian J. 2013, 8, 1985-1989.

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