Citation: ZHAO Qiang, SHEN Zhi, YANG Hao, SONG Hui-Zhen. Coordination Modes of Polypyridyl Quinoxaline with Hg(II), Pb(II), Co(II) and Mn(II)[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 69-76. doi: 10.14102/j.cnki.0254-5861.2011-0900 shu

Coordination Modes of Polypyridyl Quinoxaline with Hg(II), Pb(II), Co(II) and Mn(II)

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China

Received Date: 16 June 2015
Available Online: 18 September 2015
Fund Project: This work was supported by the NNSFC (21301100) (21301100)the Education Department Fund of Henan (13A150819) (13A150819)Special fund of Nanyang Normal University (ZX2013029) (ZX2013029)

The interaction of metal ions (Hg²⁺, Pb²⁺, Co²⁺, Mn²⁺) with polypyridyl quinoxaline ligand 2,3,6,7,10,11-hexakis(2-pyridyl)dipyrazino[2,3-f:20,30-h]quinoxaline (HPDQ) was investi- gated, and four new complexes have been synthesized and characterized. Complex 1 exhibits a 0 dimensional dual-core structure, 2 is a one-dimensional chain structure based on a dual-core Pb unit, while 3 and 4 show a 0 dimensional single-core structural unit. Complex 1 is of monoclinic system, space group C2/c with a = 19.211(4), b = 23.896(5), c = 12.698(3) Å, β = 120.11(3)°, V = 5043.0(17) Å³, Z = 4, S = 1.053, F(000) = 2976, R^a = 0.0637 and wR^b = 0.1068 (I > 2σ(I)). Complex 2 adopts triclinic system, space group P1 with a = 10.370(2), b = 12.195(2), c = 21.033(4) Å, α = 80.87(3), β = 81.22(3), γ = 82.38(3)°, V = 2579.3(8) Å³, Z = 2, S = 1.099, F(000) = 1328, R^a = 0.0609 and wR^b = 0.1365 (I > 2σ(I)). Complex 3 is of monoclinic system, space group C2/c with a = 14.166(3), b = 16.621(3), c = 20.248(4) Å, β = 92.18(3)°, V = 4764.0(16) Å³, Z = 4, S = 1.005, F(000) = 2108, R^a = 0.0589 and wR^b = 0.1332 (I > 2σ(I)). Complex 4 belongs to the monoclinic system, space group C2/c with a = 14.404(3), b = 16.626(3), c = 20.346(4) Å, β = 92.43(3)°, V = 4868.2(17) Å³, Z = 4, S = 1.068, F(000) = 2108, R^a = 0.0833 and wR^b = 0.1591 (I > 2σ(I)). Furthermore, the behavior of HPDQ with Hg²⁺, Pb²⁺, Co²⁺ and Mn²⁺ in the solution was also investigated, and the result shows after the metal ions were added respectively, the emission of all solutions shows fluorescence quenching and has a red shift compared with that of the HPDQ ligand.
- polypyridyl quinoxaline,
- mercury(II),
- lead(II),
- cobalt(II),
- manganese(II)
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