Citation: YANG Yu-Ting, TU Chang-Zheng, MIAO Jiao-Jiao, LI Jun-Li, CHEN Guang. Temperature-dependent Hydrothermal Synthesis of Two Distinct Three-dimensional Copper Complexes[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 597-604. doi: 10.14102/j.cnki.0254-5861.2011-0884 shu

Temperature-dependent Hydrothermal Synthesis of Two Distinct Three-dimensional Copper Complexes

1.
Department of Chemistry and Engineering, Qujing Normal University, Qujing 655011, China

Corresponding author: YANG Yu-Ting,
Received Date: 6 July 2015
Available Online: 15 October 2015
Fund Project: and the major project of Qujing Normal University (2012ZD002) (201401CB00299)

Two distinct copper coordination polymers, namely[Cu^Ⅱ₂(2,5-pydc)₂(bpp)₂]·H₂O (1) and Cu₂^ⅠCu^Ⅱ(2,5-pydc)₂(bpp)₂ (2) (2,5-pydc=pyridine-2,5-dicarboxylic acid, bpp=1,3-bi(4-pyridyl)propane), have been successfully synthesized through hydrothermal conditions under different temperatures. Single-crystal X-ray structural analysis revealed that both complexes 1 and 2 are 3D frameworks. Complex 1 is an 8-connected 2-fold interpenetrating network based on[Cu(2,5-pydc)]4 molecular building block (MBB), and also can be simplified as a 4-connected net if the Cu(Ⅱ) ion is regarded as an independent node, whereas 2 shows a (4,4)-connected non-interpenetrated framework which contains mixed valence Cu(Ⅰ/Ⅱ) centers. The results demonstrate that temperature plays a significant role in the final structures of the complexes.
- copper,
- coordination polymer,
- temperature,
- hydrothermal reactions,
- mixed valence
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沈阳化工大学材料科学与工程学院沈阳 110142