Citation: REN Yi-Xia, AN Miao, GAO Lou-Jun, CHAI Hong-Mei, HOU Xiang-Yang, ZHOU Gui-Jiang. Structural Diversity and Photoluminescent Properties of Two Mn(II) Sulfoterephthalate Complexes from Multi-pyridine N-containing Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 550-558. doi: 10.14102/j.cnki.0254-5861.2011-0874 shu

Structural Diversity and Photoluminescent Properties of Two Mn(II) Sulfoterephthalate Complexes from Multi-pyridine N-containing Ligands

1.
a Department of Chemistry, Faculty of Science, Xi'an Jiaotong University, Xi'an 710049, China;
2.
b College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: REN Yi-Xia,
Received Date: 30 June 2015
Available Online: 8 October 2015
Fund Project: This project is supported by the Postdoctoral Science Foundation of China (No. 2014M562403) (No. 2014M562403)National Natural Science Foundation of China (No. 21573189) (No. 21573189)

Solvothermal reaction of manganese(Ⅱ) salt with monosodium 2-sulfoterephthalate (2-NaH₂stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with[Mn₂(Hstp)₂(bpp)₂(H₂O)₄] (1) and[Mn₃(stp)₂(tpy)₃(H₂O)](H₂O)₅ (2) (bpp=benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy=2,2':6',2"-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(Ⅱ) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(Ⅱ) ions. The photoluminescent properties could be assigned to the π-π^* transition of 2-sulfoterephthalate ligands.
- solvothermal reaction,
- structural diversity,
- photoluminescent property
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