Citation: ZHOU Zhong-Yuan, XING Xiu-Shuang, HAN Yun-Hu, TIAN Chong-Bin, DU Shao-Wu. Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 119-128. doi: 10.14102/j.cnki.0254-5861.2011-0815 shu

Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property

1.
a College of Chemistry, Fuzhou University, Fuzhou 350108, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
3.
c Graduate University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: TIAN Chong-Bin, DU Shao-Wu,
Received Date: 21 May 2015
Available Online: 18 August 2015
Fund Project: This project was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

Two novel coordination compounds, 1 [Zn₄(L₁)₄(NO₃)₂(H₂O)₂](NO₃)₂·2H₂O and 2 [Mn₂(L₂)₂(DMF)(H₂O)₃](ClO₄)₂·DMF (HL₁= N'-[(1E)-pyridine-2-ylmethylidene]pyrazine-2- carbohydrazide, H₂L₂= 2-hydroxy-3-methoxybenzaldehyde(pyrazin-2-ylcarbonyl)hydrazone), based on the N-N bridged ligands were prepared and structurally characterized. Compound 1 represents the [2*2] molecular squares, in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers. The emission of compound 1 exhibits a blue shift, which can be assigned to strong electrostatic interaction between Zn^II ions and the L₁^-1. Compound 2 represents a rare phenol-O bridged Mn₂^II complex. The magnetic investigation indicates weak antiferromagnetic interactions between the Mn^II centers.
- coordination compounds,
- N-N bridged ligands,
- blue shift,
- antiferromagnetic interactions
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