Citation: FAN Guang, DENG Ling-Juan, MA Zhan-Ying, LI Xiao-Bo, ZHANG Yin-Li, SUN Jia-Juan. Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 100-106. doi: 10.14102/j.cnki.0254-5861.2011-0804 shu

Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

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College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China

Received Date: 11 May 2015
Available Online: 7 July 2015
Fund Project: Supported by the National Natural Science Foundation of China (No. 21203160) (No. 21203160) Education Department Foundation of Shaanxi Province (No. 12JK0631) (No. 12JK0631) Natural Science Foundation of Shaanxi Province (No. 2013JM2013) (No. 2013JM2013)

A novel thiocyanate-controlled copper(II)-L-arginine complex with the formula of Cu(Arg)(SCN)₂ (1, Arg: L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method. Crystal data: orthorhombic, space group P2₁2₁2₁, a = 6.0156(5), b = 12.1905(11), c = 18.4203(16) Å, V = 1350.8(2) Å³, Z = 4, μ = 1.933 mm^-1, F(000) = 724, S = 1.084, the final R = 0.0410, wR = 0.0754 for 1893 observed reflections with I > 2σ(I), and R = 0.0559, wR = 0.0820 for all reflections. In addition, elemental analysis, IR, TG-DTG and magnetism characterization are presented.
- L-arginine,
- copper complex,
- crystal structure,
- single-crystal X-ray diffraction
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