Citation: LI Jia-Ming, SHI Zhong-Feng, HE Kun-Huan. Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 135-142. doi: 10.14102/j.cnki.0254-5861.2011-0797 shu

Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands

1.
College of Petroleum and Chemical Engineering, Qinzhou University, Qinzhou 535000, China

Received Date: 5 May 2015
Available Online: 23 September 2015
Fund Project: This work was supported by Guangxi Provincial Department of Education (No. KY2015ZD130) (No. KY2015ZD130)the Natural Science Foundation of Guangxi Province (No. 2013GXNSFBA019030). The authors also acknowledge the financial support from the Natural Science Foundation of Qinzhou University (No. 2014PY-GJ05) (No. 2013GXNSFBA019030)

A new binuclear Zn^II coordination complex, Zn₂(bta)(phen)₂(Cl)₃ (1, Hbta = 2-(1H- benzotriazol-1-yl)acetic acid and phen = 1,10-phenanthroline), has been synthesized and characteri- zed by single-crystal X-ray diffraction, IR spectroscopy, elemental, and photoluminescent analysis. Complex 1 crystallizes in triclinic system, space group P with a = 9.3040(19), b = 10.694(2), c = 16.841(3) Å, α = 101.18(3), β = 105.77(3), γ = 91.72(3)°, V = 1575.8(5) Å³, C₃₂H₂₂Zn₂Cl₃N₇O₂, M_r = 773.66, D_c = 1.631 g/cm³, Z = 2, F(000) = 780, μ = 1.820 mm^-1, the final R = 0.1238 and wR = 0.1131. X-ray diffraction analyses indicate that 1 displays two crystallographic independent Zn^II metal centers with a distorted tetragonal pyramidal (ZnN₄O) and a tetrahedral (ZnNCl₃) geometries, respectively. The phen serves as a common N,N'-bidentate ligand, and the bta^- as a unique N,O-bridged ligand in 1. In the crystal, 1 forms a stable 3D supramolecular architecture by trifurcated hydrogen bonding C-H…Cl interactions and C-H…π, π…π stacking. 1 showed photo-electric conversion properties.
- photo-electric property,
- zinc(II) complex,
- 2-(1H-benzotriazol-1-yl)acetic acid,
- synthesis,
- crystal structure
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