Citation: ZHANG Mei-Li, GAO Na, GAO Lou-Jun. A Cd(II) Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 143-149. doi: 10.14102/j.cnki.0254-5861.2011-0795 shu

A Cd(II) Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Shaanxi 716000

Received Date: 4 May 2015
Available Online: 21 July 2015
Fund Project: This project was supported by the Natural Science Foundation of Yan'an University (YD2014-06) (YD2014-06) the Natural Scientific Research Foundation of Yan'an City Technology Division (2014ZC-3)，and the Provincial College Students' Innovation and Entrepreneurship Training Program(1452) (2014ZC-3)

A new Cd(II) coordination polymer, {[Cd(pda)(bimb)]·(H₂O)_0.5}_n (1, H₂pda = 1,3- phenylenediacetic acid, bimb = 4,4-bis(1-imidazolyl)biphenyl), has been synthesized and charac- terized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD) analyses and single-crystal X-ray diffraction techniques. Complex 1 shows a 4-connected two-fold interpene- trated three-dimensional (3-D) cds topology. In additional, photoluminescent properties of 1 and its dehydrated product have also been studied.
- coordination polymer,
- synthesis,
- crystal structure,
- luminescent properties
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沈阳化工大学材料科学与工程学院沈阳 110142