Citation: ZHANG Mei-Li, GAO Na, GAO Lou-Jun. A Cd(II) Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(1): 143-149. doi: 10.14102/j.cnki.0254-5861.2011-0795 shu

A Cd(II) Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Shaanxi 716000

Received Date: 4 May 2015
Available Online: 21 July 2015
Fund Project: This project was supported by the Natural Science Foundation of Yan'an University (YD2014-06) (YD2014-06) the Natural Scientific Research Foundation of Yan'an City Technology Division (2014ZC-3)，and the Provincial College Students' Innovation and Entrepreneurship Training Program(1452) (2014ZC-3)

A new Cd(II) coordination polymer, {[Cd(pda)(bimb)]·(H₂O)_0.5}_n (1, H₂pda = 1,3- phenylenediacetic acid, bimb = 4,4-bis(1-imidazolyl)biphenyl), has been synthesized and charac- terized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD) analyses and single-crystal X-ray diffraction techniques. Complex 1 shows a 4-connected two-fold interpene- trated three-dimensional (3-D) cds topology. In additional, photoluminescent properties of 1 and its dehydrated product have also been studied.
- coordination polymer,
- synthesis,
- crystal structure,
- luminescent properties
1. [1]
  (1) Yaghi, O. M.; O'Keefe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Reticular synthesis and the design of new materials. Nature 2003, 423, 705-714.
2. [2]
  (2) Ye, B. H.; Tong, M. L.; Chen, X. M. Metal-organic molecular architectures with 2,2'-bipyridyl-like and carboxylate ligands. Coord. Chem. Rev. 2005, 249, 545-565.
3. [3]
  (3) Kitagawa, S.; Matsuda, R. Chemistry of coordination space of porous coordination polymers. Coord. Chem. Rev. 2007, 251, 2490-2509.
4. [4]
  (4) Feng, J.; Zhang, H. J. Hybrid materials based on lanthanide organic complexes: a review. Chem. Soc. Rev. 2013, 42, 387-410.
5. [5]
  (5) Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long J. R. Carbon dioxide capture in metal-organic frameworks. Chem. Rev. 2012, 112, 724-781.
6. [6]
  (6) Rivesta, J. B.; Jain, P. K. Cation exchange on the nanoscale: an emerging technique for new material synthesis, device fabrication, and chemical sensing. Chem. Soc. Rev. 2013, 42, 89-96.
7. [7]
  (7) Sartorel, A.; Bonchio, M.; Campagna, S.; Scandola, F. Tetrametallic molecular catalysts for photochemical water oxidation. Chem. Soc. Rev. 2013, 42, 2262-2280.
8. [8]
  (8) Zhang, P.; Guo, Y. N.; Tang, J. Recent advances in dysprosium-based single molecule magnets: structural overview and synthetic strategies. Coord. Chem. Rev. 2013, 257, 1728-1763.
9. [9]
  (9) Du, M.; Li, C. P.; Chen, M.; Ge, Z. W.; Wang, X.; Wang, L.; Liu, C. S. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO₂ sorption selectivity. J. Am. Chem. Soc. 2014, 136, 10906-10909.
10. [10]
  (10) Pan, M.; Su, C. Y. Coordination assembly of Borromean structures. CrystEngComm. 2014, 16, 7847-7859.
11. [11]
  (11) Yang, G. P.; Hou, L.; Luan, X. J.; Wu, B.; Wang, Y. Y. Molecular braids in metal-organic frameworks. Chem. Soc. Rev. 2012, 41, 6992-7000.
12. [12]
  (12) Li, C. P.; Du, M. Role of solvents in coordination supramolecular systems. Chem. Commun. 2011, 47, 5958-5972.
13. [13]
  (13) Hu, T. L.; Zou, R. Q.; Li, J. R.; Bu, X. H. d¹⁰ metal complexes assembled from isometric benzenedicarboxylates and 3-(2-pyridyl) pyrazole showing 1D chain structures syntheses, structures and luminescent properties. Dalton Trans. 2008, 1302-1311.
14. [14]
  (14) Su, K. Z.; Jiang, F. L.; Qian, J. J.; Wu, M. Y.; Xiong, K. C.; Gai, Y. L.; Hong, M. C. Thiacalix arene-supported kite-like heterometallic tetranuclear Zn^IILn^III3 (Ln = Gd, Tb, Dy, Ho) complexes. Inorg. Chem. 2013, 52, 3780-3786.
15. [15]
  (15) Yang, W. T.; Guo, M.; Yi, F.Y.; Sun, Z. M. Construction of three-dimensional cobalt(II)-based metal-organic frameworks by synergy between rigid and semirigid ligands. Cryst. Growth Des. 2012, 12, 5529-5534.
16. [16]
  (16) SAINT Software Reference Manual. Bruker AXS: Madison, WI 1998.
17. [17]
  (17) Sheldrick, G. M. SADABS, Siemens Area Detector Absorption Corrected Software. University of Göttingen: Göttingen, Germany 1996.
18. [18]
  (18) Sheldrick, G. M. SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures. University of Göttingen: Göttingen, Germany 1997.
19. [19]
  (19) Tripuramallu, B. K.; Manna, P.; Reddy, S. N.; Das, S. K. Factors affecting the conformational modulation of flexible ligands in the self-assembly process of coordination polymers: synthesis, structural characterization, magnetic properties, and theoretical studies of [Co(pda)(bix)]_n, [Ni(pda)(bix)(H₂O)]_n, [Cu(pda)(bix)₂(H₂O)₂]_n·8nH₂O, [Co₂(μ-OH)(pda)(ptz)]_n·nH₂O, [Co(hfipbb)(bix)_0.5]_n, and [Co(2,6-pydc)(bix)_1.5]n·4nH₂O. Cryst. Growth Des. 2012, 12, 777-792.
20. [20]
  (20) McGarrah, J. E.; Kim, Y. J.; Hissler, M.; Eisenberg, R. Toward a molecular photochemical device: a triad for photoinduced charge separation based on a platinum diimine bis(acetylide) chromophore. Inorg. Chem. 2001, 40, 4510-4511.
21. [21]
  (21) Wu, J. Y.; Yuan, P. T.; Hsiao, C. C. Positional isomerism of unsymmetrical semirigid ligands toward the construction of discrete and infinite coordination architectures of zinc(II) and cadmium(II) complexes. CrystEngComm. 2014, 16, 3128-3140.
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
3. [3]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
4. [4]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
5. [5]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
6. [6]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
7. [7]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
8. [8]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
9. [9]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
10. [10]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
13. [13]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
18. [18]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
19. [19]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(723)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142