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Citation: LIANG Xiao-Qiang, FAN Zeng-Lu. A Metal-organic Framework with Alternately Hydrophilic and Hydrophobic Layers Based on Tetrazole Derivative: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1901-1907. doi: 10.14102/j.cnki.0254-5861.2011-0771 shu

A Metal-organic Framework with Alternately Hydrophilic and Hydrophobic Layers Based on Tetrazole Derivative: Synthesis, Structure and Luminescent Property

LIANG Xiao-Qiang ^a,c ,
FAN Zeng-Lu ^b

a.
a. College of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, China;
b.
b. College of Textile & Material, Xi'an Polytechnic University, Xi'an 710048, China;
c.
c. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 20 April 2015
Available Online: 7 July 2015
Fund Project: This work was supported by National Natural Science Foundation of China (21401147) (21401147) Basic Research Program of Natural Science from Shaanxi Provincial Government (2015JQ2032) (2015JQ2032) Scientific Research Program from Education Department of Shaanxi Provincial Government (2013JK0654) (2013JK0654) Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University (201219) (201219)

A new metal-organic framework based on ethyl 1H-tetrazole-5-acetate (Hetza), [Ag₄(etza)₄] (1), has been synthesized and characterized by elemental analysis, IR, thermal gravimetric and X-ray structural analysis. Crystal data for the title complex are as follows: triclinic system, space group P1 with a=11.0771(6), b=11.6636(6), c=13.2925(8), α=102.3710(10), β=103.3810(10), γ=90.0890(10)°, V=1629.60(16) Ǻ³, M_r=1052.06, Z=2, F(000)=1024, D_c=2.144 g/cm³, μ(MoKα)=2.438 mm^-1, the final R=0.0538 and wR=0.1475 (I>2σ(I)). Complex 1 adopts the (4·8²) topological network and the alternately hydrophilic-hydrophilic and hydrophobic- hydrophobic arrangements. The luminescent properties of complex 1 and the free Hetza ligand have been studied in the solid states.
- coordination network,
- ethyltetrazole-5-acetate,
- fluorescence,
- hydrophilic interaction,
- hydrophobic effect
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