Citation: KONG Zhi-Guo, WANG Wei, ZHANG Bing. Synthesis, Crystal Structure and Luminescence of a New Two-dimensional Pb(II) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1503-1507. doi: 10.14102/j.cnki.0254-5861.2011-0715 shu

Synthesis, Crystal Structure and Luminescence of a New Two-dimensional Pb(II) Coordination Polymer

KONG Zhi-Guo ^a,b,, ,
WANG Wei ^a,b ,
ZHANG Bing ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: KONG Zhi-Guo,
Received Date: 16 March 2015
Available Online: 16 July 2015
Fund Project: Supported by the Institute Foundation of Siping city (No.2013036) (No.2013036)

A new two-dimensional Pb(II) coordination polymer, [Pb₂(L)(tpphz)_1.5(NO₃)₂]·H₂O (1), has been obtained by the hydrothermal reaction of tetrapyrido[3,2-a:2',3'-c:3",2"-h:2"',3"'-j]-phenazine (tpphz) and 2,2'-bipyridyl-3,3'-dicarboxylic acid (H₂L). It crystallizes in monoclinic, space group P2₁/c with a=15.344(3), b=14.111(3), c=21.963(4) Å, β=106.89(3)°, V=4550.1(16) Å³, Z=4, C₄₈H₂₆N₁₃O₁₁Pb₂, M_r=1375.20, D_c=2.007 g/cm³, F(000)=2628, μ(MoKa)=7.471 mm^-1, R=0.0339 and wR=0.0808. In 1, the two crystallographically independent tpphz ligands adopt the same bis-chelating coordination mode, but they play different roles in the structure of 1. One type of tpphz ligands bridge the Pb(II) cations to generate a zigzig chain, where the L anions are located on one side of the chain. Further, adjacent chains are linked by the other type of tpphz ligands into a two-dimensional layer structure. Additionally, the solid state luminescent property of 1 was also studied at room temperature.
- crystal structure,
- coordination polymer,
- tetrapyrido[3,2-a:2',3'-c:3",2"-h:2"',3"'-j]phenazine,
- luminescence
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