Citation: JIA Hong-Yun, GONG Ya-Qiong, ZHANG Shu-Hai. Synthesis, Structure and Magnetic Properties of a 3D Interpentrating Network Based on 4-4-Imidazol-1-yl-benzoic Acid and Azide Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 34(10): 1565-1570. doi: 10.14102/j.cnki.0254-5861.2011-0668 shu

Synthesis, Structure and Magnetic Properties of a 3D Interpentrating Network Based on 4-4-Imidazol-1-yl-benzoic Acid and Azide Ligands

1.
a Industry and Ecology Institute, North University of China, Taiyuan 030051, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 5 February 2015
Available Online: 10 July 2015
Fund Project: This work was supported by the Natural Science Foundation of Shanxi (2012021005-2) (2012021005-2)

A new Co^Ⅱ coordination complex, namely [Co(iba)(N₃)]_n, was prepared by the hydrothermal reaction of Co(NO₃)₂·6H₂O with NaN₃ in the presence of 4-imidazol-1-yl-benzoic acid (Hiba). Compound 1 crystallizes in orthorhombic, space group Pbca with a=6.782(2), b=19.93(5), c=15.96(4) Å, V=2157.2(3) Å³, Z=8, C₁₀H₇O₂N₅Co, M_r=228.14, D_c=1.774 g/cm³, F(000)=1160, μ(MoKα)=1.592 mm^-1. The final R and wR are 0.0706 and 0.1990 for 1160 observed reflections with I>2σ(I). Each iba-coordinates in a bidentate fashion with two Co^Ⅱ ions and every two adjacent Co^Ⅱ ions were connected by one azido ion to form a 3D two-fold interpenetrating framework. Thermogravimeteric analysis (TGA) of compound 1 reveals that the loss of moiety of azido ion occurs from 200 ℃ to about 260 ℃ and the framework begins to decompose above 300 ℃. The magnetic property investigation of compound 1 demonstrates that it displays ferromagnetic coupling between Co^Ⅱ ions.
- solvothermal,
- cobalt,
- crystal structure,
- magnetic properties
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