Citation: JIA Wei-Guo, DAI Yuan-Chen, LI Dan-Dan, WANG Dong-Sheng, SHENG En-Hong. Zinc Complexes Based on Organochalcogen Ligand Mbit: Syntheses, Structures and Photocatalytic Properties[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1099-1106. doi: 10.14102/j.cnki.0254-5861.2011-0597 shu

Zinc Complexes Based on Organochalcogen Ligand Mbit: Syntheses, Structures and Photocatalytic Properties

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College of Chemistry and Materials Science, Center for Nano Science and Technology, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-based Materials, Anhui Normal University, Wuhu 241000, China

Corresponding author: JIA Wei-Guo, SHENG En-Hong,
Received Date: 8 December 2014
Available Online: 2 June 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (21102004) (21102004) and Training Programs of Innovation and Entrepreneurship of Anhui Province for Undergraduates (AH₂01410370040) (201410370040)

The zinc complex with neutral organochalcogen ligand Mbit, [(Mbit)₂Zn](ClO₄)₂ (1, Mbit=1,1'-methylenebis(3-methyl-imidazole-2-thione)), has been synthesized and characterized. The complex has been characterized by elemental analysis, NMR and IR spectra. The molecular structure of 1 has been determined by X-ray crystallography. For the complex, C₁₈H₂₄Cl₂N₈O₈S₄Zn, M_r=744.96, triclinic, space group P1, a=11.2923(18), b=11.9353(19), c=13.837(3)Å, α=114.763(2), β=92.132(2), γ=116.039(2)°, V=1464.6(5)Å³, Z=2, D_c=1.689 g/cm³, λ=1.54184Å, μ=1.363 mm^-1, F(000)=760, S=1.098, the final R=0.0554 and wR=0.0.1579. Complex 1 exhibits photocatalytic activity for methyl orange (MO) degradation under UV light and shows good stability toward photocatalysis.
- zinc,
- organochalcogen,
- structure,
- photocatalytic
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