{"进展评述":[{"abstractInfo":"稀土上转换纳米材料（UpconversionNanoparticles，UCNPs）可将近红外光转换为可见光，其发光性能优异、化学性质稳定、激发光能有效避免自荧光，因此在生物医学领域应用广泛。但UCNPs的低发光效率限制了其进一步发展。本文综述了近年来研究较多的几种优化稀土上转换纳米材料发光的方法，主要包括调整基质材料和掺杂离子、过渡金属离子与镧系离子共掺杂、引入协同敏化剂减少热效应、有机染料与UCNPs协同作用以及金属表面等离子体共振增强法等。文中分别论述了上述方法的最新研究进展，并总结了这些方法目前存在的问题，指出上转换发光领域的研发重点：一是着重分析各种优化发光方法的作用机理，提出更加完备清晰的理论体系；二是探索更容易被生物体降解的UCNPs，使其副作用降到最低。","abstractInfoCn":"稀土上转换纳米材料（Upconversion Nanoparticles，UCNPs）可将近红外光转换为可见光，其发光性能优异、化学性质稳定、激发光能有效避免自荧光，因此在生物医学领域应用广泛。但UCNPs的低发光效率限制了其进一步发展。本文综述了近年来研究较多的几种优化稀土上转换纳米材料发光的方法，主要包括调整基质材料和掺杂离子、过渡金属离子与镧系离子共掺杂、引入协同敏化剂减少热效应、有机染料与UCNPs协同作用以及金属表面等离子体共振增强法等。文中分别论述了上述方法的最新研究进展，并总结了这些方法目前存在的问题，指出上转换发光领域的研发重点：一是着重分析各种优化发光方法的作用机理，提出更加完备清晰的理论体系；二是探索更容易被生物体降解的UCNPs，使其副作用降到最低。","abstractInfoEn":"Rare earth upconversion nanoparticles (UCNPs), which can convert visible light into near infrared light, have excellent luminescence properties, stable chemical properties, and can avoid self-fluorescence interference. Therefore, they can be widely used in biomedical fields. However, the low luminescence efficiency of UCNPs restricts its further development. In this paper, several methods for optimizing the luminescence of rare earth upconversion nanoparticles are reviewed, including adjusting matrix and doping ions, co-doping transition metal ions with lanthanide ions, introducing the synergistic sensitizers to reduce the thermal effect, and synergistic effect of organic dyes and UCNPs, metal surface plasmon resonance enhancement method, etc. This review discusses the latest research progress of the above methods, summarizes the problems existing in these methods, and points out the research and development focus on upconversion luminescence field. One is to analyze the mechanism of various optimized luminescence methods, and put forward a more complete and clear theoretical system. The other is to explore UCNPs which are degradable by organisms, in order to minimize the side effects.","articleNo":"","authorCnList":["徐榕"," 冯爱玲"," 王彦妮"," 夏候平"],"authorEnList":["Xu Rong"," Feng Ailing"," Wang Yanni"," Xia Houping"],"authorList":["徐榕"," 冯爱玲"," 王彦妮"," 夏候平"],"authors":"徐榕, 冯爱玲, 王彦妮, 夏候平","authorsCn":"徐榕, 冯爱玲, 王彦妮, 夏候平","authorsEn":"Xu Rong, Feng Ailing, Wang Yanni, Xia Houping","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"徐榕, 冯爱玲, 王彦妮, 夏候平. 优化稀土上转换纳米材料发光的方法. 化学通报, 2018, 81(12): 1059-1071.","citationCn":"徐榕, 冯爱玲, 王彦妮, 夏候平. 优化稀土上转换纳米材料发光的方法. 化学通报, 2018, 81(12): 1059-1071.","citationEn":"徐榕, 冯爱玲, 王彦妮, 夏候平. Methods for Optimizing Luminescence of Rare Earth Upconversion Nanoparticles. Chemistry, 2018, 81(12): 1059-1071.","doi":"","figContent":"hxtb-81-12-1059-1.jpg$$hxtb-81-12-1059-2.jpg$$hxtb-81-12-1059-3.jpg$$hxtb-81-12-1059-4.jpg$$hxtb-81-12-1059-5.jpg$$hxtb-81-12-1059-6.jpg$$hxtb-81-12-1059-7.jpg","figList":["hxtb-81-12-1059-1.jpg","hxtb-81-12-1059-2.jpg","hxtb-81-12-1059-3.jpg","hxtb-81-12-1059-4.jpg","hxtb-81-12-1059-5.jpg","hxtb-81-12-1059-6.jpg","hxtb-81-12-1059-7.jpg"],"firstFig":"hxtb-81-12-1059-1.jpg","fpage":"1059","highCitedState":"","htmlCount":89,"htmlFile":"","id":"0106c8fd-e0b4-49c0-9fe0-e37318de0c02","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"稀土, 上转换, 纳米粒子, 发光优化, 生物医用","keywordCn":"稀土, 上转换, 纳米粒子, 发光优化, 生物医用","keywordCnList":["稀土"," 上转换"," 纳米粒子"," 发光优化"," 生物医用"],"keywordEn":"Rare earth, Upconversion, Nanoparticles, Luminescence optimization, Biomedical","keywordEnList":["Rare earth"," Upconversion"," Nanoparticles"," Luminescence optimization"," Biomedical"],"keywordList":["稀土"," 上转换"," 纳米粒子"," 发光优化"," 生物医用"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1071","oldUrl":"","pdfDownCount":6,"pdfSize":5847.52,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"优化稀土上转换纳米材料发光的方法","titleCn":"优化稀土上转换纳米材料发光的方法","titleEn":"Methods for Optimizing Luminescence of Rare Earth Upconversion Nanoparticles","viewCount":337,"volume":"81","year":2018},{"abstractInfo":"离子液体（ILs）具有不易挥发性、非易燃性、离子电导率高、物化性能稳定、电化学窗口宽、结构多样与可设计性等诸多优良特性，近年来已在电化学、生物、绿色化学等领域发挥着至关重要的作用。本文综述了ILs在生物检测方面的一些应用：作为理想的载体将目标基因或者药物运送到靶细胞中达到治疗的目的；探究ILs的毒性对生物体的影响从而达到杀灭癌细胞等特殊细胞或绿色降解的目的；利用其电催化活性好、灵敏度高等特性制成生物传感器用于电化学检测；将ILs作为核酸分离的载体，使得核酸的分离过程简化，效率提高。","abstractInfoCn":"离子液体（ILs）具有不易挥发性、非易燃性、离子电导率高、物化性能稳定、电化学窗口宽、结构多样与可设计性等诸多优良特性，近年来已在电化学、生物、绿色化学等领域发挥着至关重要的作用。本文综述了ILs在生物检测方面的一些应用：作为理想的载体将目标基因或者药物运送到靶细胞中达到治疗的目的；探究ILs的毒性对生物体的影响从而达到杀灭癌细胞等特殊细胞或绿色降解的目的；利用其电催化活性好、灵敏度高等特性制成生物传感器用于电化学检测；将ILs作为核酸分离的载体，使得核酸的分离过程简化，效率提高。","abstractInfoEn":"Ionic liquids (ILs) have many excellent properties such as non-volatility, nonflammability, high ionic conductivity, physicochemical stability, wide electrochemical window, structural diversity and designability. In recent years, they have played a vital role in electrochemistry, biology, green chemistry, etc. This article mainly reviews some applications of ILs in biology. Firstly, the target gene or drug is expected to be delivered by ILs as an ideal carrier to target cells for therapeutic purposes. Secondly, the toxicity effects of ILs on organisms have been explored on purpose for killing cancer cells and other special cells or green degradation. Thirdly, the good electrocatalytic activity and high sensitivity of ILs can lead to preparations of biosensors for electrochemical detections. Finally, ILs can be used as the carrier for separations of nucleic acids, simplifying the separation process and improving the efficiency.","articleNo":"","authorCnList":["洪伽金"," 刘勇"," 陈嘉亮"," 马科锋"],"authorEnList":["Hong Jiajin"," Liu Yong"," Chen Jialiang"," Ma Kefeng"],"authorList":["洪伽金"," 刘勇"," 陈嘉亮"," 马科锋"],"authors":"洪伽金, 刘勇, 陈嘉亮, 马科锋","authorsCn":"洪伽金, 刘勇, 陈嘉亮, 马科锋","authorsEn":"Hong Jiajin, Liu Yong, Chen Jialiang, Ma Kefeng","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"洪伽金, 刘勇, 陈嘉亮, 马科锋. 离子液体在生物工程方面的研究进展. 化学通报, 2018, 81(12): 1072-1077.","citationCn":"洪伽金, 刘勇, 陈嘉亮, 马科锋. 离子液体在生物工程方面的研究进展. 化学通报, 2018, 81(12): 1072-1077.","citationEn":"洪伽金, 刘勇, 陈嘉亮, 马科锋. Progress in Ionic Liquids of Biological Engineering. Chemistry, 2018, 81(12): 1072-1077.","doi":"","figContent":"hxtb-81-12-1072-1.jpg$$hxtb-81-12-1072-2.jpg$$hxtb-81-12-1072-3.jpg$$hxtb-81-12-1072-S1.jpg$$hxtb-81-12-1072-4.jpg","figList":["hxtb-81-12-1072-1.jpg","hxtb-81-12-1072-2.jpg","hxtb-81-12-1072-3.jpg","hxtb-81-12-1072-S1.jpg","hxtb-81-12-1072-4.jpg"],"firstFig":"hxtb-81-12-1072-1.jpg","fpage":"1072","highCitedState":"","htmlCount":6,"htmlFile":"","id":"31ba4520-cc25-4428-90fb-d7d695fc96b0","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"离子液体, 生物工程, 生物分离, 电化学, 生物毒性","keywordCn":"离子液体, 生物工程, 生物分离, 电化学, 生物毒性","keywordCnList":["离子液体"," 生物工程"," 生物分离"," 电化学"," 生物毒性"],"keywordEn":"Ionic liquids, Bioengineering, Bioseparation, Electrochemistry, Biotoxicity","keywordEnList":["Ionic liquids"," Bioengineering"," Bioseparation"," Electrochemistry"," Biotoxicity"],"keywordList":["离子液体"," 生物工程"," 生物分离"," 电化学"," 生物毒性"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1077","oldUrl":"","pdfDownCount":5,"pdfSize":4195.24,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"离子液体在生物工程方面的研究进展","titleCn":"离子液体在生物工程方面的研究进展","titleEn":"Progress in Ionic Liquids of Biological Engineering","viewCount":90,"volume":"81","year":2018},{"abstractInfo":"无患子是一种集工业、药用、观赏、生态于一体的多功能综合利用价值极高的经济树种，近年来，由于其具有较高的商业价值和药理活性，受到了广泛的重视。迄今文献中报道的无患子中分离鉴定的三萜皂苷类化合物有71种，具有抗菌、抗肿瘤、保护心脑血管、保护肝脏、抗生育、杀虫等多种生物活性和良好的非离子表面活性作用，在医药、食品保健、日化和农业等领域应用前景广阔。本文对其皂苷的种类、提取与分离及其应用进行了综述，以期为今后无患子的研究、开发与利用提供参考。","abstractInfoCn":"无患子是一种集工业、药用、观赏、生态于一体的多功能综合利用价值极高的经济树种，近年来，由于其具有较高的商业价值和药理活性，受到了广泛的重视。迄今文献中报道的无患子中分离鉴定的三萜皂苷类化合物有71种，具有抗菌、抗肿瘤、保护心脑血管、保护肝脏、抗生育、杀虫等多种生物活性和良好的非离子表面活性作用，在医药、食品保健、日化和农业等领域应用前景广阔。本文对其皂苷的种类、提取与分离及其应用进行了综述，以期为今后无患子的研究、开发与利用提供参考。","abstractInfoEn":"<i>Sapindus mukorossi<\/i> Gaertn., a kind of economic tree with high comprehensive utilization value, which integrates with industry, medicine, ornamental and ecology. In recent years, it has received extensive attention due to its high commercial value and pharmacological activity. To date, there were 71 kinds of triterpenoid saponins were isolated and identified from <i>Sapindus mukorossi<\/i> according to the reports from literatures, most of them have antibacterial, anti-tumor, protection of heart and brain blood vessels, protecting liver, anti fertility, insecticidal and other biological activities and good nonionic surface activity. So, they have a wide application in the fields of medicine, food health care, daily chemical and agricultural fields. In this paper, the types, extraction and separation of saponins and their application were summarized to provide reference for the future research, development and utilization of <i>Sapindus mukorossi.<\/i>","articleNo":"","authorCnList":["徐圆圆"," 贾黎明"," 陈仲"," 高媛"],"authorEnList":["Xu Yuanyuan"," Jia Liming"," Chen Zhong"," Gao Yuan"],"authorList":["徐圆圆"," 贾黎明"," 陈仲"," 高媛"],"authors":"徐圆圆, 贾黎明, 陈仲, 高媛","authorsCn":"徐圆圆, 贾黎明, 陈仲, 高媛","authorsEn":"Xu Yuanyuan, Jia Liming, Chen Zhong, Gao Yuan","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"徐圆圆, 贾黎明, 陈仲, 高媛. 无患子三萜皂苷研究进展. 化学通报, 2018, 81(12): 1078-1088.","citationCn":"徐圆圆, 贾黎明, 陈仲, 高媛. 无患子三萜皂苷研究进展. 化学通报, 2018, 81(12): 1078-1088.","citationEn":"徐圆圆, 贾黎明, 陈仲, 高媛. Advances on Triterpenoid Saponin of <i>Sapindus mukorossi<\/i>. Chemistry, 2018, 81(12): 1078-1088.","doi":"","figContent":"hxtb-81-12-1078-S1.jpg$$hxtb-81-12-1078-S2.jpg$$hxtb-81-12-1078-S3.jpg$$hxtb-81-12-1078-S4.jpg$$hxtb-81-12-1078-S5.jpg","figList":["hxtb-81-12-1078-S1.jpg","hxtb-81-12-1078-S2.jpg","hxtb-81-12-1078-S3.jpg","hxtb-81-12-1078-S4.jpg","hxtb-81-12-1078-S5.jpg"],"firstFig":"hxtb-81-12-1078-S1.jpg","fpage":"1078","highCitedState":"","htmlCount":739,"htmlFile":"","id":"03f7591a-7f34-41d9-90e0-753fd810740b","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"无患子, 三萜皂苷, 生物活性, 应用","keywordCn":"无患子, 三萜皂苷, 生物活性, 应用","keywordCnList":["无患子"," 三萜皂苷"," 生物活性"," 应用"],"keywordEn":"<i>apindus mukorossi<\/i>, Triterpenoids saponins, Biological activity, Application","keywordEnList":["<i>apindus mukorossi<\/i>"," Triterpenoids saponins"," Biological activity"," Application"],"keywordList":["无患子"," 三萜皂苷"," 生物活性"," 应用"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1088","oldUrl":"","pdfDownCount":26,"pdfSize":1299.88,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"无患子三萜皂苷研究进展","titleCn":"无患子三萜皂苷研究进展","titleEn":"Advances on Triterpenoid Saponin of <i>Sapindus mukorossi<\/i>","viewCount":1913,"volume":"81","year":2018},{"abstractInfo":"膜污染是聚偏氟乙烯（PVDF）膜在污水处理工程应用中的主要障碍，膜亲水改性是改善膜污染的主要方法。本文根据改性方法的异同，按照表面涂覆、表面接枝、共混改性、共聚改性等方法进行了综述。通过分析不同改性方法对PVDF亲水效果、渗透能力、抗污能力及长期有效性等方面的影响，讨论了各种改性方法的优缺点，为PVDF膜处理的应用提供技术和理论支持。","abstractInfoCn":"膜污染是聚偏氟乙烯（PVDF）膜在污水处理工程应用中的主要障碍，膜亲水改性是改善膜污染的主要方法。本文根据改性方法的异同，按照表面涂覆、表面接枝、共混改性、共聚改性等方法进行了综述。通过分析不同改性方法对PVDF亲水效果、渗透能力、抗污能力及长期有效性等方面的影响，讨论了各种改性方法的优缺点，为PVDF膜处理的应用提供技术和理论支持。","abstractInfoEn":"Membrane fouling constitutes a bottleneck limiting the efficient and wide application of polyvinylidene fluoride (PVDF) membrane. One of the main way to improve the antifouling performance of PVDF membrane is surface hydrophilic modification. This paper reviews different modification methods including surface coating, surface grafting, blending modification and copolymerization modification. By analyzing the effects of different modification methods on hydrophilic effect, permeability, antifouling ability and long term effectiveness of PVDF, their advantages and disadvantages were discussed. It is hoped that this paper will provide some technical and theoretical support for the application of PVDF membrane treatment.","articleNo":"","authorCnList":["朱腾义"," 严和婷"," 李毛"],"authorEnList":["Zhu Tengyi"," Yan Heting"," Li Mao"],"authorList":["朱腾义"," 严和婷"," 李毛"],"authors":"朱腾义, 严和婷, 李毛","authorsCn":"朱腾义, 严和婷, 李毛","authorsEn":"Zhu Tengyi, Yan Heting, Li Mao","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"朱腾义, 严和婷, 李毛. 聚偏氟乙烯膜改性方法研究进展. 化学通报, 2018, 81(12): 1089-1095.","citationCn":"朱腾义, 严和婷, 李毛. 聚偏氟乙烯膜改性方法研究进展. 化学通报, 2018, 81(12): 1089-1095.","citationEn":"朱腾义, 严和婷, 李毛. Progress in Polyvinylidene Fluoride Membrane Modification Method. Chemistry, 2018, 81(12): 1089-1095.","doi":"","figContent":"hxtb-81-12-1089-1.jpg","figList":["hxtb-81-12-1089-1.jpg"],"firstFig":"hxtb-81-12-1089-1.jpg","fpage":"1089","highCitedState":"","htmlCount":4,"htmlFile":"","id":"76e3c35e-892d-4e14-b3a2-b6a2ea233d2f","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"聚偏氟乙烯, 膜污染, 亲水化改性, 渗透能力","keywordCn":"聚偏氟乙烯, 膜污染, 亲水化改性, 渗透能力","keywordCnList":["聚偏氟乙烯"," 膜污染"," 亲水化改性"," 渗透能力"],"keywordEn":"Polyvinylidene fluoride, Membrane fouling, Hydrophilic modification, Permeability","keywordEnList":["Polyvinylidene fluoride"," Membrane fouling"," Hydrophilic modification"," Permeability"],"keywordList":["聚偏氟乙烯"," 膜污染"," 亲水化改性"," 渗透能力"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1095","oldUrl":"","pdfDownCount":3,"pdfSize":1372.52,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"聚偏氟乙烯膜改性方法研究进展","titleCn":"聚偏氟乙烯膜改性方法研究进展","titleEn":"Progress in Polyvinylidene Fluoride Membrane Modification Method","viewCount":129,"volume":"81","year":2018},{"abstractInfo":"油品中的氮化物影响油品稳定性、储运安全及二次加工工艺等。近年来，油品脱氮成为解决环境污染和能源短缺的研究热点之一。现炼油厂脱氮技术虽成熟，但成本大、能耗高。光催化技术进行油品脱氮具有安全无毒、环境友好、高稳定性、高催化活性、低能耗等优点，备受人们的瞩目。本文介绍了催化技术在燃料油品脱氮领域的发展进程及研究现状，包括针对金属氧化物催化剂、分子筛催化剂体系进行载体优化和催化剂改性研究等，期望能对新型改性纳米光催化剂制备及其在油品深度脱氮领域高效率和高性能应用提供参考。","abstractInfoCn":"油品中的氮化物影响油品稳定性、储运安全及二次加工工艺等。近年来，油品脱氮成为解决环境污染和能源短缺的研究热点之一。现炼油厂脱氮技术虽成熟，但成本大、能耗高。光催化技术进行油品脱氮具有安全无毒、环境友好、高稳定性、高催化活性、低能耗等优点，备受人们的瞩目。本文介绍了催化技术在燃料油品脱氮领域的发展进程及研究现状，包括针对金属氧化物催化剂、分子筛催化剂体系进行载体优化和催化剂改性研究等，期望能对新型改性纳米光催化剂制备及其在油品深度脱氮领域高效率和高性能应用提供参考。","abstractInfoEn":"Nitrogen compounds in oils affect oil stability, storage and transportation safety and secondary processing. In recent years, the denitrification of oil has become one of the research hotspots to solve environmental pollution and energy shortage problems. Although the technology of denitrification is mature, its cost and energy consumption are high. Photocatalytic denitrification has many advantages, such as safety, environmental friendliness, high stability, high catalytic activity and low energy consumption. This paper introduces the development process and research status of photocatalytic technology in the field of fuel oil denitrification, including carrier optimization and catalyst modification for metal oxide catalysts and molecular sieve catalyst systems. It is expected to provide reference for the preparation of novel modified nanophotocatalysts and their applications in the deep denitrification of oil products.","articleNo":"","authorCnList":["陈颖"," 张会丽"," 梁宇宁"],"authorEnList":["Chen Ying"," Zhang Huilli"," Liang Yuning"],"authorList":["陈颖"," 张会丽"," 梁宇宁"],"authors":"陈颖, 张会丽, 梁宇宁","authorsCn":"陈颖, 张会丽, 梁宇宁","authorsEn":"Chen Ying, Zhang Huilli, Liang Yuning","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"陈颖, 张会丽, 梁宇宁. 油品光催化深度脱氮技术研究进展. 化学通报, 2018, 81(12): 1096-1103.","citationCn":"陈颖, 张会丽, 梁宇宁. 油品光催化深度脱氮技术研究进展. 化学通报, 2018, 81(12): 1096-1103.","citationEn":"陈颖, 张会丽, 梁宇宁. Research Progress in Photocatalytic Deep Denitrification Technology for Oil Products. Chemistry, 2018, 81(12): 1096-1103.","doi":"","figContent":"hxtb-81-12-1096-1.jpg$$hxtb-81-12-1096-2.jpg$$hxtb-81-12-1096-3.jpg$$hxtb-81-12-1096-4.jpg$$hxtb-81-12-1096-5.jpg$$hxtb-81-12-1096-6.jpg$$hxtb-81-12-1096-7.jpg$$hxtb-81-12-1096-8.jpg","figList":["hxtb-81-12-1096-1.jpg","hxtb-81-12-1096-2.jpg","hxtb-81-12-1096-3.jpg","hxtb-81-12-1096-4.jpg","hxtb-81-12-1096-5.jpg","hxtb-81-12-1096-6.jpg","hxtb-81-12-1096-7.jpg","hxtb-81-12-1096-8.jpg"],"firstFig":"hxtb-81-12-1096-1.jpg","fpage":"1096","highCitedState":"","htmlCount":5,"htmlFile":"","id":"4f23f2c4-5abd-4a68-95b0-1c62fb982c1d","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"油品脱氮, 光催化, 纳米改性","keywordCn":"油品脱氮, 光催化, 纳米改性","keywordCnList":["油品脱氮"," 光催化"," 纳米改性"],"keywordEn":"Nitrogen removal from oil, Photocatalysts, Nano-modification","keywordEnList":["Nitrogen removal from oil"," Photocatalysts"," Nano-modification"],"keywordList":["油品脱氮"," 光催化"," 纳米改性"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1103","oldUrl":"","pdfDownCount":5,"pdfSize":2675.85,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"油品光催化深度脱氮技术研究进展","titleCn":"油品光催化深度脱氮技术研究进展","titleEn":"Research Progress in Photocatalytic Deep Denitrification Technology for Oil Products","viewCount":131,"volume":"81","year":2018}],"研究论文":[{"abstractInfo":"金属离子的高效检测对于人类健康和环境保护极其重要。本文通过对甲基苯磺酸催化下3-脱氢莽草酸甲酯与若丹明6G乙二胺缩合的芳构化反应合成了一种检测Fe<sup>3+<\/sup>的荧光探针分子RhM606。该探针分子在乙醇溶液中特异性地与Fe<sup>3+<\/sup>络合，导致若丹明内酰胺开环，在553nm处出现强的荧光发射峰。该荧光探针对Fe<sup>3+<\/sup>具有良好的选择性，可定量检测水中的Fe<sup>3+<\/sup>，检测限为3.93μmol/L。","abstractInfoCn":"金属离子的高效检测对于人类健康和环境保护极其重要。本文通过对甲基苯磺酸催化下3-脱氢莽草酸甲酯与若丹明6G乙二胺缩合的芳构化反应合成了一种检测Fe<sup>3+<\/sup>的荧光探针分子RhM606。该探针分子在乙醇溶液中特异性地与Fe<sup>3+<\/sup>络合，导致若丹明内酰胺开环，在553nm处出现强的荧光发射峰。该荧光探针对Fe<sup>3+<\/sup>具有良好的选择性，可定量检测水中的Fe<sup>3+<\/sup>，检测限为3.93μmol/L。","abstractInfoEn":"The detection of metal ions is extremely important for human health and environmental protection. In this work, a fluorescent probe for the detection of Fe<sup>3+<\/sup> was synthesized based on aromatization reaction of methyl 3-dehydroshikimate (3-MDHS). The target probe RhM606 was synthesized by condensation reaction between rhodamine-6G ethylenediamine and 3-MDHS catalyzed by <i>p<\/i>-toluene sulfonic acid. The probe molecules have a specific coordination effect with Fe<sup>3+<\/sup> in ethanol solution, which induce the opening of the lactam ring and generate a strong fluorescence emission at 553 nm. The fluorescent probe has a good selectivity and can quantitatively determinate Fe<sup>3+<\/sup> in aqueous solution. The limit of detection is 3.93 μmol/L.","articleNo":"","authorCnList":["高楼军"," 白童鹿"," 张恩生"," 张玉琦"," 鞠萍"," 王记江"],"authorEnList":["Gao Loujun"," Bai Tonglu"," Zhang Ensheng"," Zhang Yuqi"," Ju Ping"," Wang Jijiang"],"authorList":["高楼军"," 白童鹿"," 张恩生"," 张玉琦"," 鞠萍"," 王记江"],"authors":"高楼军, 白童鹿, 张恩生, 张玉琦, 鞠萍, 王记江","authorsCn":"高楼军, 白童鹿, 张恩生, 张玉琦, 鞠萍, 王记江","authorsEn":"Gao Loujun, Bai Tonglu, Zhang Ensheng, Zhang Yuqi, Ju Ping, Wang Jijiang","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"高楼军, 白童鹿, 张恩生, 张玉琦, 鞠萍, 王记江. 一种Fe<sup>3+<\/sup>荧光探针的合成及其检测性能研究. 化学通报, 2018, 81(12): 1104-1109.","citationCn":"高楼军, 白童鹿, 张恩生, 张玉琦, 鞠萍, 王记江. 一种Fe<sup>3+<\/sup>荧光探针的合成及其检测性能研究. 化学通报, 2018, 81(12): 1104-1109.","citationEn":"高楼军, 白童鹿, 张恩生, 张玉琦, 鞠萍, 王记江. Synthesis and Properties of a Fluorescence Probe for the Detection of Fe<sup>3+<\/sup> Ions. Chemistry, 2018, 81(12): 1104-1109.","doi":"","figContent":"hxtb-81-12-1104-S1.jpg$$hxtb-81-12-1104-1.jpg$$hxtb-81-12-1104-2.jpg$$hxtb-81-12-1104-3.jpg$$hxtb-81-12-1104-4.jpg$$hxtb-81-12-1104-5.jpg$$hxtb-81-12-1104-6.jpg$$hxtb-81-12-1104-7.jpg$$hxtb-81-12-1104-8.jpg","figList":["hxtb-81-12-1104-S1.jpg","hxtb-81-12-1104-1.jpg","hxtb-81-12-1104-2.jpg","hxtb-81-12-1104-3.jpg","hxtb-81-12-1104-4.jpg","hxtb-81-12-1104-5.jpg","hxtb-81-12-1104-6.jpg","hxtb-81-12-1104-7.jpg","hxtb-81-12-1104-8.jpg"],"firstFig":"hxtb-81-12-1104-S1.jpg","fpage":"1104","highCitedState":"","htmlCount":80,"htmlFile":"","id":"d0f3ad51-88a7-4217-9fd6-c7385a96c33f","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"Fe<sup>3+<\/sup>, 若丹明6G衍生物, 荧光探针, 金属离子检测","keywordCn":"Fe<sup>3+<\/sup>, 若丹明6G衍生物, 荧光探针, 金属离子检测","keywordCnList":["Fe<sup>3+<\/sup>"," 若丹明6G衍生物"," 荧光探针"," 金属离子检测"],"keywordEn":"Fe<sup>3+<\/sup>, Rhodamine-6G derivative, Fluorescent probe, Metal ion detection","keywordEnList":["Fe<sup>3+<\/sup>"," Rhodamine-6G derivative"," Fluorescent probe"," Metal ion detection"],"keywordList":["Fe<sup>3+<\/sup>"," 若丹明6G衍生物"," 荧光探针"," 金属离子检测"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1109","oldUrl":"","pdfDownCount":6,"pdfSize":7617.71,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"一种Fe<sup>3+<\/sup>荧光探针的合成及其检测性能研究","titleCn":"一种Fe<sup>3+<\/sup>荧光探针的合成及其检测性能研究","titleEn":"Synthesis and Properties of a Fluorescence Probe for the Detection of Fe<sup>3+<\/sup> Ions","viewCount":231,"volume":"81","year":2018},{"abstractInfo":"本文利用2-氨基吡啶与4-<i>N，N-<\/i>二乙氨基水杨醛反应合成了5-<i>N，N<\/i>-二乙胺基-2-（吡啶-2’-亚氨甲基）苯酚（探针<b>L<\/b>），并对其结构进行了表征。在DMSO/Tris（体积比6:4，pH=7.4）溶液中，探针<b>L<\/b>高选择性荧光“关-开”识别Zn<sup>2+<\/sup>，在365nm紫外灯照射下，由无荧光变成蓝色荧光。实验表明，探针<b>L<\/b>与Zn<sup>2+<\/sup>的结合比为1:1，结合常数为2.6×10<sup>3<\/sup>L/mol，检测限为9.39×10<sup>-7<\/sup>mol/L，pH适用范围为7~11，并可检测水样中的Zn<sup>2+<\/sup>。","abstractInfoCn":"本文利用2-氨基吡啶与4-<i>N，N-<\/i>二乙氨基水杨醛反应合成了5-<i>N，N<\/i>-二乙胺基-2-（吡啶-2’-亚氨甲基）苯酚（探针<b>L<\/b>），并对其结构进行了表征。在DMSO/Tris（体积比6:4，pH=7.4）溶液中，探针<b>L<\/b>高选择性荧光“关-开”识别Zn<sup>2+<\/sup>，在365nm紫外灯照射下，由无荧光变成蓝色荧光。实验表明，探针<b>L<\/b>与Zn<sup>2+<\/sup>的结合比为1:1，结合常数为2.6×10<sup>3<\/sup> L/mol，检测限为9.39×10<sup>-7<\/sup> mol/L，pH适用范围为7~11，并可检测水样中的Zn<sup>2+<\/sup>。","abstractInfoEn":"In this paper, the titled compound (probe <b>L<\/b>) was synthesized by using 2-aminopyridine and 4-<i>N, N<\/i>-diethylamino salicylaldehyde as starting materials, and its structure was characterized by NMR. In DMSO/Tris (6:4, <i>V/V,<\/i>  pH=7.4) solution, the probe <b>L<\/b> can selectively recognize Zn<sup>2+<\/sup> with fluorescence 'turn-on' responding, and fluorescence color of the system was changed from non-fluoresce to strong blue fluorescence under 365 nm UV lamp irradiation. The experimental results demonstrated that the binding ratio of <b>L<\/b> to Zn<sup>2+<\/sup> is 1:1, the binding constant is 2.60×10<sup>3<\/sup> L·mol<sup>-1<\/sup>, the detection limit is 9.39×10<sup>-7<\/sup>mol/L, and the proper pH range is 7~11. The probe <b>L<\/b> can also detect Zn<sup>2+<\/sup> in real water samples.","articleNo":"","authorCnList":["钟克利"," 邓隆隆"," 郭佳"," 张强"," 侯淑华"," 边延江"," 汤立军"],"authorEnList":["Zhong Keli"," Deng Longlong"," Guo Jia"," Zhang Qiang"," Hou Shuhua"," Bian Yanjiang"," Tang Lijun"],"authorList":["钟克利"," 邓隆隆"," 郭佳"," 张强"," 侯淑华"," 边延江"," 汤立军"],"authors":"钟克利, 邓隆隆, 郭佳, 张强, 侯淑华, 边延江, 汤立军","authorsCn":"钟克利, 邓隆隆, 郭佳, 张强, 侯淑华, 边延江, 汤立军","authorsEn":"Zhong Keli, Deng Longlong, Guo Jia, Zhang Qiang, Hou Shuhua, Bian Yanjiang, Tang Lijun","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"钟克利, 邓隆隆, 郭佳, 张强, 侯淑华, 边延江, 汤立军. 5-<i>N, N<\/i>-二乙氨基-2-(吡啶-2'-亚氨甲基)苯酚的合成及其对Zn<sup>2+<\/sup>的识别. 化学通报, 2018, 81(12): 1110-1114, 1120.","citationCn":"钟克利, 邓隆隆, 郭佳, 张强, 侯淑华, 边延江, 汤立军. 5-<i>N, N<\/i>-二乙氨基-2-(吡啶-2'-亚氨甲基)苯酚的合成及其对Zn<sup>2+<\/sup>的识别. 化学通报, 2018, 81(12): 1110-1114, 1120.","citationEn":"钟克利, 邓隆隆, 郭佳, 张强, 侯淑华, 边延江, 汤立军. Synthesis of 5-<i>N, N<\/i>-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn<sup>2+<\/sup>. Chemistry, 2018, 81(12): 1110-1114, 1120.","doi":"","figContent":"hxtb-81-12-1110-S1.jpg$$hxtb-81-12-1110-1.jpg$$hxtb-81-12-1110-2.jpg$$hxtb-81-12-1110-3.jpg$$hxtb-81-12-1110-4.jpg$$hxtb-81-12-1110-5.jpg$$hxtb-81-12-1110-6.jpg$$hxtb-81-12-1110-7.jpg$$hxtb-81-12-1110-8.jpg$$hxtb-81-12-1110-9.jpg$$hxtb-81-12-1110-10.jpg","figList":["hxtb-81-12-1110-S1.jpg","hxtb-81-12-1110-1.jpg","hxtb-81-12-1110-2.jpg","hxtb-81-12-1110-3.jpg","hxtb-81-12-1110-4.jpg","hxtb-81-12-1110-5.jpg","hxtb-81-12-1110-6.jpg","hxtb-81-12-1110-7.jpg","hxtb-81-12-1110-8.jpg","hxtb-81-12-1110-9.jpg","hxtb-81-12-1110-10.jpg"],"firstFig":"hxtb-81-12-1110-S1.jpg","fpage":"1110","highCitedState":"","htmlCount":31,"htmlFile":"","id":"f53b2163-c85a-4d2c-91bc-426acee3c4c7","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"4-<i>N, N<\/i>-二乙氨基水杨醛, 荧光探针, Zn<sup>2+<\/sup>, 识别","keywordCn":"4-<i>N, N<\/i>-二乙氨基水杨醛, 荧光探针, Zn<sup>2+<\/sup>, 识别","keywordCnList":["4-<i>N"," N<\/i>-二乙氨基水杨醛"," 荧光探针"," Zn<sup>2+<\/sup>"," 识别"],"keywordEn":"4-<i>N, N<\/i>-diethylamino salicylaldehyde, Fluorescent probe, Zn<sup>2+<\/sup>, Recognition","keywordEnList":["4-<i>N"," N<\/i>-diethylamino salicylaldehyde"," Fluorescent probe"," Zn<sup>2+<\/sup>"," Recognition"],"keywordList":["4-<i>N"," N<\/i>-二乙氨基水杨醛"," 荧光探针"," Zn<sup>2+<\/sup>"," 识别"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1114, 1120","oldUrl":"","pdfDownCount":4,"pdfSize":3898.38,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"5-<i>N, N<\/i>-二乙氨基-2-(吡啶-2'-亚氨甲基)苯酚的合成及其对Zn<sup>2+<\/sup>的识别","titleCn":"5-<i>N, N<\/i>-二乙氨基-2-(吡啶-2'-亚氨甲基)苯酚的合成及其对Zn<sup>2+<\/sup>的识别","titleEn":"Synthesis of 5-<i>N, N<\/i>-(diethylamino)-2-[(pyridin-2-ylimino)methyl] phenol and Its Recognition Characteristics for Zn<sup>2+<\/sup>","viewCount":218,"volume":"81","year":2018},{"abstractInfo":"以（<i>E<\/i>）-1-（2-对甲苯磺酰胺基）-3-芳基丙-2-烯-1-酮（<b>1<\/b>）为底物与<i>N<\/i>-硫代丁二酰亚胺（<b>2<\/b>）通过亲电环化反应合成了2-芳基-3-硫代-2，3-二氢喹啉-4（1<i>H<\/i>）-酮类化合物。以三氟化硼乙醚（20（mol）%）为催化剂、1，2-二氯乙烷为溶剂、60℃下反应，可以60%~92%的收率得到一系列2-芳基-3-硫代-4（1<i>H<\/i>）-喹啉酮衍生物。化合物<b>3a~3l<\/b>未见文献报道，其结构均经<sup>1<\/sup>HNMR、<sup>13<\/sup>CNMR以及高分辨质谱进行确定。","abstractInfoCn":"以（<i>E<\/i>）-1-（2-对甲苯磺酰胺基）-3-芳基丙-2-烯-1-酮（<b>1<\/b>）为底物与<i>N<\/i>-硫代丁二酰亚胺（<b>2<\/b>）通过亲电环化反应合成了2-芳基-3-硫代-2，3-二氢喹啉-4（1<i>H<\/i>）-酮类化合物。以三氟化硼乙醚（20（mol）%）为催化剂、1，2-二氯乙烷为溶剂、60℃下反应，可以60%~92%的收率得到一系列2-芳基-3-硫代-4（1<i>H<\/i>）-喹啉酮衍生物。化合物<b>3a~3l<\/b>未见文献报道，其结构均经<sup>1<\/sup>H NMR、<sup>13<\/sup>C NMR以及高分辨质谱进行确定。","abstractInfoEn":"The syntheses of 2-aryl-3-sulfenyl-2, 3-dihydroquinolin-4(1<i>H<\/i>)-ones are realized using (<i>E<\/i>)-1-(2-tosylaminophenyl)-3-arylprop-2-en-1-ones (<b>1<\/b>) and <i>N<\/i>-sulfanylsuccinimides as substrates through electrophilic cyclization. With BF<sub>3<\/sub>·Et<sub>2<\/sub>O (20(mol)%) as the catalyst and 1, 2-dichloroethane as the solvent, the reaction can be performed well at 60℃ and give the desired 2-aryl-3-sulfenyl-4(1<i>H<\/i>)-quinolinones in a yield of 60%~92%. Compounds <b>3a-3l<\/b> have not been reported in the literature, and their structures are confirmed by <sup>1<\/sup>H NMR, <sup>13<\/sup>C NMR and HR-MS.","articleNo":"","authorCnList":["程宇飞"," 高文超"," 刘强"," 常宏宏"," 张建栋"," 魏文珑"],"authorEnList":["Cheng Yufei"," Gao Wenchao"," Liu Qiang"," Chang Honghong"," Zhang Jiandong"," Wei Wenlong"],"authorList":["程宇飞"," 高文超"," 刘强"," 常宏宏"," 张建栋"," 魏文珑"],"authors":"程宇飞, 高文超, 刘强, 常宏宏, 张建栋, 魏文珑","authorsCn":"程宇飞, 高文超, 刘强, 常宏宏, 张建栋, 魏文珑","authorsEn":"Cheng Yufei, Gao Wenchao, Liu Qiang, Chang Honghong, Zhang Jiandong, Wei Wenlong","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"程宇飞, 高文超, 刘强, 常宏宏, 张建栋, 魏文珑. 亲电硫试剂参与的2-芳基-3-硫代-2, 3-二氢喹啉-4(1<i>H<\/i>)-酮的合成. 化学通报, 2018, 81(12): 1121-1126.","citationCn":"程宇飞, 高文超, 刘强, 常宏宏, 张建栋, 魏文珑. 亲电硫试剂参与的2-芳基-3-硫代-2, 3-二氢喹啉-4(1<i>H<\/i>)-酮的合成. 化学通报, 2018, 81(12): 1121-1126.","citationEn":"程宇飞, 高文超, 刘强, 常宏宏, 张建栋, 魏文珑. Syntheses of 2-Aryl-3-sulfenyl-4(1<i>H<\/i>)-quinolinones Using Electrophilic Sulfur Reagents. Chemistry, 2018, 81(12): 1121-1126.","doi":"","figContent":"hxtb-81-12-1121-S1.jpg","figList":["hxtb-81-12-1121-S1.jpg"],"firstFig":"hxtb-81-12-1121-S1.jpg","fpage":"1121","highCitedState":"","htmlCount":5,"htmlFile":"","id":"48f36b9c-429d-4961-95b4-8f4297825962","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"<i>N<\/i>-硫代丁二酰亚胺, 2-芳基-3-硫代-4(1<i>H<\/i>)-喹啉酮, 亲电环化, 硫醚合成","keywordCn":"<i>N<\/i>-硫代丁二酰亚胺, 2-芳基-3-硫代-4(1<i>H<\/i>)-喹啉酮, 亲电环化, 硫醚合成","keywordCnList":["<i>N<\/i>-硫代丁二酰亚胺"," 2-芳基-3-硫代-4(1<i>H<\/i>)-喹啉酮"," 亲电环化"," 硫醚合成"],"keywordEn":"<i>N<\/i>-Sulfanylsuccinimides, 2-Aryl-3-sulfenyl-4(1<i>H<\/i>)-quinolinones, Electrophilic cyclization, Sulfide syntheses","keywordEnList":["<i>N<\/i>-Sulfanylsuccinimides"," 2-Aryl-3-sulfenyl-4(1<i>H<\/i>)-quinolinones"," Electrophilic cyclization"," Sulfide syntheses"],"keywordList":["<i>N<\/i>-硫代丁二酰亚胺"," 2-芳基-3-硫代-4(1<i>H<\/i>)-喹啉酮"," 亲电环化"," 硫醚合成"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1126","oldUrl":"","pdfDownCount":5,"pdfSize":1324.46,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"亲电硫试剂参与的2-芳基-3-硫代-2, 3-二氢喹啉-4(1<i>H<\/i>)-酮的合成","titleCn":"亲电硫试剂参与的2-芳基-3-硫代-2, 3-二氢喹啉-4(1<i>H<\/i>)-酮的合成","titleEn":"Syntheses of 2-Aryl-3-sulfenyl-4(1<i>H<\/i>)-quinolinones Using Electrophilic Sulfur Reagents","viewCount":136,"volume":"81","year":2018},{"abstractInfo":"发展了一种从3-（2-溴代苯甲酰基）-吲哚出发在无过渡金属参与下合成茚并吲哚酮类化合物的新方法。在甲苯/四氢呋喃（2:1）混合溶剂中，3-（2-溴代苯甲酰基）-吲哚、正丁基锂和碘化锌原位生成的2-吲哚锌在碘化锂辅助下与芳基溴化物发生分子内加成-环化反应，合成了一系列取代的茚并-[1，2-<i>b<\/i>]吲哚-10（5<i>H<\/i>）-酮类化合物，且均获得了较好的收率。考察了溶剂、卤化锌、添加剂对产率的影响。","abstractInfoCn":"发展了一种从3-（2-溴代苯甲酰基）-吲哚出发在无过渡金属参与下合成茚并吲哚酮类化合物的新方法。在甲苯/四氢呋喃（2:1）混合溶剂中，3-（2-溴代苯甲酰基）-吲哚、正丁基锂和碘化锌原位生成的2-吲哚锌在碘化锂辅助下与芳基溴化物发生分子内加成-环化反应，合成了一系列取代的茚并-[1，2-<i>b<\/i>]吲哚-10（5<i>H<\/i>）-酮类化合物，且均获得了较好的收率。考察了溶剂、卤化锌、添加剂对产率的影响。","abstractInfoEn":"A convenient method for the preparation of indenoindolones from 3-(2-bromobenzoyl)-indoles without the aid of transition-metal catalysis has been developed. 2-Zincioindole reagents, prepared in-situ from 3-(2-bromobenzoyl)-indoles, <i>n<\/i>-BuLi and ZnI<sub>2<\/sub>, were found to undergo intramolecular addition-cyclizing reactions with aryl bromides in the presence of LiI in a mixed solvent consisting of toluene and THF(2:1). Various substituted indeno[1, 2-b]indol-10(5<i>H<\/i>)-ones can be obtained in good yields. The effects of reaction parameters such as solvent, zinc halide and additive on the yield were investigated.","articleNo":"","authorCnList":["姬凌波"," 王丁众"," 柴国璧"," 崔凯"," 马骥"," 席辉"," 胡有持"," 宗永立"," 范武"," 刘俊辉"],"authorEnList":["Ji Lingbo"," Wang Dingzhong"," Chai Guobi"," Cui Kai"," Ma Ji"," Xi Hui"," Hu Youchi"," Zong Yongli"," Fan Wu"," Liu Junhui"],"authorList":["姬凌波"," 王丁众"," 柴国璧"," 崔凯"," 马骥"," 席辉"," 胡有持"," 宗永立"," 范武"," 刘俊辉"],"authors":"姬凌波, 王丁众, 柴国璧, 崔凯, 马骥, 席辉, 胡有持, 宗永立, 范武, 刘俊辉","authorsCn":"姬凌波, 王丁众, 柴国璧, 崔凯, 马骥, 席辉, 胡有持, 宗永立, 范武, 刘俊辉","authorsEn":"Ji Lingbo, Wang Dingzhong, Chai Guobi, Cui Kai, Ma Ji, Xi Hui, Hu Youchi, Zong Yongli, Fan Wu, Liu Junhui","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"姬凌波, 王丁众, 柴国璧, 崔凯, 马骥, 席辉, 胡有持, 宗永立, 范武, 刘俊辉. 无过渡金属参与下茚并-[1, 2-<i>b<\/i>]吲哚-10(5<i>H<\/i>)-酮的合成. 化学通报, 2018, 81(12): 1127-1131.","citationCn":"姬凌波, 王丁众, 柴国璧, 崔凯, 马骥, 席辉, 胡有持, 宗永立, 范武, 刘俊辉. 无过渡金属参与下茚并-[1, 2-<i>b<\/i>]吲哚-10(5<i>H<\/i>)-酮的合成. 化学通报, 2018, 81(12): 1127-1131.","citationEn":"姬凌波, 王丁众, 柴国璧, 崔凯, 马骥, 席辉, 胡有持, 宗永立, 范武, 刘俊辉. Tansition-Metal-Free Syntheses of Indeno[1, 2-<i>b<\/i>]-indol-10(5<i>H<\/i>)-one Derivatives. Chemistry, 2018, 81(12): 1127-1131.","doi":"","figContent":"hxtb-81-12-1127-S1.jpg","figList":["hxtb-81-12-1127-S1.jpg"],"firstFig":"hxtb-81-12-1127-S1.jpg","fpage":"1127","highCitedState":"","htmlCount":8,"htmlFile":"","id":"45a399d1-f27a-4d33-9c6a-cdfe52859b61","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"碘化锂, 2-吲哚锌, 加成-环化, 芳基溴","keywordCn":"碘化锂, 2-吲哚锌, 加成-环化, 芳基溴","keywordCnList":["碘化锂"," 2-吲哚锌"," 加成-环化"," 芳基溴"],"keywordEn":"Lithium iodide 2-zincioindole, addition-cyclizing, aryl bromides","keywordEnList":["Lithium iodide 2-zincioindole"," addition-cyclizing"," aryl bromides"],"keywordList":["碘化锂"," 2-吲哚锌"," 加成-环化"," 芳基溴"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1131","oldUrl":"","pdfDownCount":4,"pdfSize":1319.54,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"无过渡金属参与下茚并-[1, 2-<i>b<\/i>]吲哚-10(5<i>H<\/i>)-酮的合成","titleCn":"无过渡金属参与下茚并-[1, 2-<i>b<\/i>]吲哚-10(5<i>H<\/i>)-酮的合成","titleEn":"Tansition-Metal-Free Syntheses of Indeno[1, 2-<i>b<\/i>]-indol-10(5<i>H<\/i>)-one Derivatives","viewCount":162,"volume":"81","year":2018},{"abstractInfo":"为提高环氧氯丙烷胺类絮凝剂的絮凝性能，选用六次甲基四胺为交联剂，以环氧氯丙烷、二甲胺为主要原料，合成了环氧氯丙烷-二甲胺-六次甲基四胺（HMTA）季铵盐阳离子改性絮凝剂，其在辽河油田废水处理中表现出优异的絮凝性能，并研究了絮凝剂用量和温度对HMTA絮凝剂絮凝性能的影响。结果表明，使用HMTA絮凝剂的合适温度为45℃，最佳用量为20mg/L，除浊率可达98.1%，除油率达到35.1%。红外光谱和核磁共振谱的表征结果证实六次甲基四胺在聚合物中发挥了交联剂的作用，有效提高了环氧氯丙烷胺类絮凝剂的絮凝性能。","abstractInfoCn":"为提高环氧氯丙烷胺类絮凝剂的絮凝性能，选用六次甲基四胺为交联剂，以环氧氯丙烷、二甲胺为主要原料，合成了环氧氯丙烷-二甲胺-六次甲基四胺（HMTA）季铵盐阳离子改性絮凝剂，其在辽河油田废水处理中表现出优异的絮凝性能，并研究了絮凝剂用量和温度对HMTA絮凝剂絮凝性能的影响。结果表明，使用HMTA絮凝剂的合适温度为45℃，最佳用量为20mg/L，除浊率可达98.1%，除油率达到35.1%。红外光谱和核磁共振谱的表征结果证实六次甲基四胺在聚合物中发挥了交联剂的作用，有效提高了环氧氯丙烷胺类絮凝剂的絮凝性能。","abstractInfoEn":"To improve the flocculability of the epichlorohydrin and polyamine flocculants, a novel epichlorohydrin-dimethylamine-methenamine quaternary ammonium salt cationic modified flocculant (HMTA) was synthesized by using epichlorohydrin and dimethylamine as main raw materials and methenamine as the crosslinking agent. The HMTA flocculant showed better performance in the treatment of the Liaohe oilfield wastewater. Influences of the flocculant dosage and temperature on the flocculation performance of the flocculant (HMTA) were investigated. Under the optimum temperature of 45℃ and the optimum dosage of flocculant of 20mg/L, turbidity removal rate of 98.1% and oil removal rate of 35.1% are achieved. The IR and NMR results illustrated that the methenamine acted as the crosslinking agent in the polymer and improved the flocculation performance of the epichlorohydrin and polyamine flocculant.","articleNo":"","authorCnList":["王浩"," 郭帅"," 曹月坤"," 吕雪川"," 李国轲"," 高肖汉"],"authorEnList":["Wang Hao"," Guo Shuai"," Cao Yuekun"," Lv Xuechuan"," Li Guoke"," Gao Xiaohan"],"authorList":["王浩"," 郭帅"," 曹月坤"," 吕雪川"," 李国轲"," 高肖汉"],"authors":"王浩, 郭帅, 曹月坤, 吕雪川, 李国轲, 高肖汉","authorsCn":"王浩, 郭帅, 曹月坤, 吕雪川, 李国轲, 高肖汉","authorsEn":"Wang Hao, Guo Shuai, Cao Yuekun, Lv Xuechuan, Li Guoke, Gao Xiaohan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"王浩, 郭帅, 曹月坤, 吕雪川, 李国轲, 高肖汉. 环氧氯丙烷类阳离子改性絮凝剂的合成及性能研究. 化学通报, 2018, 81(12): 1132-1137.","citationCn":"王浩, 郭帅, 曹月坤, 吕雪川, 李国轲, 高肖汉. 环氧氯丙烷类阳离子改性絮凝剂的合成及性能研究. 化学通报, 2018, 81(12): 1132-1137.","citationEn":"王浩, 郭帅, 曹月坤, 吕雪川, 李国轲, 高肖汉. Synthesis and Properties of the Epichlorohydrin Cationic Modified Flocculants. Chemistry, 2018, 81(12): 1132-1137.","doi":"","figContent":"hxtb-81-12-1132-S1.jpg$$hxtb-81-12-1132-1.jpg$$hxtb-81-12-1132-2.jpg$$hxtb-81-12-1132-3.jpg$$hxtb-81-12-1132-4.jpg$$hxtb-81-12-1132-5.jpg$$hxtb-81-12-1132-6.jpg$$hxtb-81-12-1132-7.jpg$$hxtb-81-12-1132-8.jpg$$hxtb-81-12-1132-9.jpg","figList":["hxtb-81-12-1132-S1.jpg","hxtb-81-12-1132-1.jpg","hxtb-81-12-1132-2.jpg","hxtb-81-12-1132-3.jpg","hxtb-81-12-1132-4.jpg","hxtb-81-12-1132-5.jpg","hxtb-81-12-1132-6.jpg","hxtb-81-12-1132-7.jpg","hxtb-81-12-1132-8.jpg","hxtb-81-12-1132-9.jpg"],"firstFig":"hxtb-81-12-1132-S1.jpg","fpage":"1132","highCitedState":"","htmlCount":47,"htmlFile":"","id":"b1631524-f81d-4812-9a75-cecc6ad24972","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"环氧氯丙烷, 六次甲基四胺, 阳离子絮凝剂, 油田废水, 沉降","keywordCn":"环氧氯丙烷, 六次甲基四胺, 阳离子絮凝剂, 油田废水, 沉降","keywordCnList":["环氧氯丙烷"," 六次甲基四胺"," 阳离子絮凝剂"," 油田废水"," 沉降"],"keywordEn":"Epichlorohydrin, Methenamine, Cationic flocculant, Oilfield wastewater, Sedimentation","keywordEnList":["Epichlorohydrin"," Methenamine"," Cationic flocculant"," Oilfield wastewater"," Sedimentation"],"keywordList":["环氧氯丙烷"," 六次甲基四胺"," 阳离子絮凝剂"," 油田废水"," 沉降"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1137","oldUrl":"","pdfDownCount":4,"pdfSize":1395.02,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"环氧氯丙烷类阳离子改性絮凝剂的合成及性能研究","titleCn":"环氧氯丙烷类阳离子改性絮凝剂的合成及性能研究","titleEn":"Synthesis and Properties of the Epichlorohydrin Cationic Modified Flocculants","viewCount":384,"volume":"81","year":2018},{"abstractInfo":"为了了解某市电子废物拆解区二噁英及其类似物污染情况，于2017年9月至2017年10月期间，从电子废物拆解区内的村落居民家中，随机采集了鸡、鸭、鹅、鸽及鹌鹑各2批次成年放养家禽样本，研究其肉质中17种二噁英（PCDD/F<sub>S<\/sub>）及12种二噁英类多氯联苯（DL-PCBs）的污染水平。利用高分辨气相色谱/高分辨双聚焦磁式质谱联用（HRGC/HRMS）对采集的10批次家禽样本进行分析。结果发现，参照欧盟现行《2014/663/EU》行动标准及《（EU）No1259/2011》最大限量标准，6批次样本超过了二噁英毒性当量行动标准（1.25pg/gfat），其中3批次样本（2.40pg/gfat、2.56pg/gfat、1.94pg/gfat）超过最大限量标准（1.75pg/gfat）；2批次样本（0.930pg/gfat、2.14pg/gfat）超过了DL-PCBs当量行动标准限量（0.75pg/gfat）；1批次样本（3.33pg/gfat）超过二噁英和DL-PCBs毒性当量总量最大限量标准（3.0pg/gfat）。证实该地区存在一定程度的二噁英和DL-PCBs污染。","abstractInfoCn":"为了了解某市电子废物拆解区二噁英及其类似物污染情况，于2017年9月至2017年10月期间，从电子废物拆解区内的村落居民家中，随机采集了鸡、鸭、鹅、鸽及鹌鹑各2批次成年放养家禽样本，研究其肉质中17种二噁英（PCDD/F<sub>S<\/sub>）及12种二噁英类多氯联苯（DL-PCBs）的污染水平。利用高分辨气相色谱/高分辨双聚焦磁式质谱联用（HRGC/HRMS）对采集的10批次家禽样本进行分析。结果发现，参照欧盟现行《2014/663/EU》行动标准及《（EU）No 1259/2011》最大限量标准，6批次样本超过了二噁英毒性当量行动标准（1.25pg/g fat），其中3批次样本（2.40pg/g fat、2.56pg/g fat、1.94pg/g fat）超过最大限量标准（1.75pg/g fat）；2批次样本（0.930pg/g fat、2.14pg/g fat）超过了DL-PCBs当量行动标准限量（0.75pg/g fat）；1批次样本（3.33pg/g fat）超过二噁英和DL-PCBs毒性当量总量最大限量标准（3.0pg/g fat）。证实该地区存在一定程度的二噁英和DL-PCBs污染。","abstractInfoEn":"In order to understand the pollution of dioxins and their analogues in the e-waste dismantling area of certain city, Guangdong Province, two batches of adult free-range poultry samples of chickens, ducks, geese, pigeons and quail were randomly collected from the homes of village residents in the e-waste dismantling area to study the levels of 17 dioxins (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (DL-PCBs) in the meat from September 2017 to October 2017. The collected 10 batches of poultry samples were analyzed by high resolution gas chromatography/high resolution double focused magnetic mass spectrometry (HRGC/HRMS). As a result, referring to the EU current \"2014/663/EU\" action standard and \"(EU) No 1259/2011\" maximum limit standard, it was found that 6 batches of samples exceeded the dioxin equivalence action standard (1.25pg/g fat), of which 3 batches of samples (2.40pg/g fat, 2.56pg/g fat, 1.94pg/g fat) exceeded the maximum limit standard (1.75pg/g fat); two batches of samples (0.930pg/g fat, 2.14 pg/g fat) exceeded the dioxin-like polyphenylene equivalent standard of action (0.75pg/g fat); one batch of sample (3.33pg/g fat) exceeded the toxicity of dioxins and dioxin-like polychlorinated biphenyls equivalent total limit standard (3.0pg/g fat). It was confirmed that there is a certain degree of dioxin and dioxin-like PCB contamination in the area.","articleNo":"","authorCnList":["唐穗平"," 陈满英"," 邱启东"," 綦艳"," 陈洁"],"authorEnList":["Tang Suiping"," Chen Manying"," Qiu Qidong"," Qi Yan"," Chen Jie"],"authorList":["唐穗平"," 陈满英"," 邱启东"," 綦艳"," 陈洁"],"authors":"唐穗平, 陈满英, 邱启东, 綦艳, 陈洁","authorsCn":"唐穗平, 陈满英, 邱启东, 綦艳, 陈洁","authorsEn":"Tang Suiping, Chen Manying, Qiu Qidong, Qi Yan, Chen Jie","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"唐穗平, 陈满英, 邱启东, 綦艳, 陈洁. 电子废物拆解区禽肉中二噁英及其类似物污染分析. 化学通报, 2018, 81(12): 1138-1142.","citationCn":"唐穗平, 陈满英, 邱启东, 綦艳, 陈洁. 电子废物拆解区禽肉中二噁英及其类似物污染分析. 化学通报, 2018, 81(12): 1138-1142.","citationEn":"唐穗平, 陈满英, 邱启东, 綦艳, 陈洁. Study on the Pollution Level of Dioxins and Their Analogues of Poultry in an E-waste Dismantling Area. Chemistry, 2018, 81(12): 1138-1142.","doi":"","figContent":"hxtb-81-12-1138-1.jpg$$hxtb-81-12-1138-2.jpg","figList":["hxtb-81-12-1138-1.jpg","hxtb-81-12-1138-2.jpg"],"firstFig":"hxtb-81-12-1138-1.jpg","fpage":"1138","highCitedState":"","htmlCount":82,"htmlFile":"","id":"21db4633-4a06-43d7-ab94-5f808709f380","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"二噁英, 二噁英类多氯联苯, 家禽肉, 电子废物","keywordCn":"二噁英, 二噁英类多氯联苯, 家禽肉, 电子废物","keywordCnList":["二噁英"," 二噁英类多氯联苯"," 家禽肉"," 电子废物"],"keywordEn":"Dioxins, Dioxin-like PCBs, Poultry, E-waste","keywordEnList":["Dioxins"," Dioxin-like PCBs"," Poultry"," E-waste"],"keywordList":["二噁英"," 二噁英类多氯联苯"," 家禽肉"," 电子废物"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1142","oldUrl":"","pdfDownCount":4,"pdfSize":1406.67,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"电子废物拆解区禽肉中二噁英及其类似物污染分析","titleCn":"电子废物拆解区禽肉中二噁英及其类似物污染分析","titleEn":"Study on the Pollution Level of Dioxins and Their Analogues of Poultry in an E-waste Dismantling Area","viewCount":643,"volume":"81","year":2018}],"其他":[{"abstractInfo":"AfacileprocedureforthecatalyticadditionofarylboronicacidstoaromaticaldehydeswasdevelopedusingasimpleNiCl<sub>2<\/sub>(PPh<sub>3<\/sub>)<sub>2<\/sub>/IPr·HClsystemundermildconditions,providingdiarylmethanolsinhighyields.Thismethodissimpleandeasytohandle,whichisanimportantsupplementtothepreparationofdiarylmethanols.","abstractInfoCn":"发展了一种基于NiCl<sub>2<\/sub>（PPh<sub>3<\/sub>）<sub>2<\/sub>/IPr·HCl催化体系的芳基硼酸和芳香醛进行加成反应制备二芳基甲醇类化合物的新方法，并取得了较好的催化效果。该方法具有简便、易操作等优点，是过渡金属催化制备二芳基甲醇类化合物的一个重要补充。","abstractInfoEn":"A facile procedure for the catalytic addition of arylboronic acids to aromatic aldehydes was developed using a simple NiCl<sub>2<\/sub>(PPh<sub>3<\/sub>)<sub>2<\/sub>/IPr·HCl system under mild conditions, providing diarylmethanols in high yields. This method is simple and easy to handle, which is an important supplement to the preparation of diaryl methanols.","articleNo":"","authorCnList":["陈强"," 樊新衡"," 张立鹏"," 杨联明"],"authorEnList":["Chen Qiang"," Fan Xinheng"," Zhang Lipeng"," Yang Lianming"],"authorList":["Chen Qiang"," Fan Xinheng"," Zhang Lipeng"," Yang Lianming"],"authors":"Chen Qiang, Fan Xinheng, Zhang Lipeng, Yang Lianming","authorsCn":"陈强, 樊新衡, 张立鹏, 杨联明","authorsEn":"Chen Qiang, Fan Xinheng, Zhang Lipeng, Yang Lianming","categoryName":" ","categoryNameCn":"研究论文","categoryNameEn":" ","citation":"Chen Qiang, Fan Xinheng, Zhang Lipeng, Yang Lianming. A Simple Nickel(Ⅱ) Catalyst System for the Addition of Arylboronic Acids to Arylaldehydes. Chemistry, 2018, 81(12): 1115-1120.","citationCn":"Chen Qiang, Fan Xinheng, Zhang Lipeng, Yang Lianming. 镍催化芳基硼酸与芳基醛的加成反应. 化学通报, 2018, 81(12): 1115-1120.","citationEn":"Chen Qiang, Fan Xinheng, Zhang Lipeng, Yang Lianming. A Simple Nickel(Ⅱ) Catalyst System for the Addition of Arylboronic Acids to Arylaldehydes. Chemistry, 2018, 81(12): 1115-1120.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"1115","highCitedState":"","htmlCount":33,"htmlFile":"","id":"0fb57d77-f1ba-4d2a-a8f2-e95aa7de1ce9","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"Nickel(Ⅱ), Catalytic reaction, Diaryl methanol","keywordCn":"二价镍, 催化反应, 二芳基甲醇","keywordCnList":["二价镍"," 催化反应"," 二芳基甲醇"],"keywordEn":"Nickel(Ⅱ), Catalytic reaction, Diaryl methanol","keywordEnList":["Nickel(Ⅱ)"," Catalytic reaction"," Diaryl methanol"],"keywordList":["Nickel(Ⅱ)"," Catalytic reaction"," Diaryl methanol"],"language":"en","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1120","oldUrl":"","pdfDownCount":3,"pdfSize":1257.08,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"A Simple Nickel(Ⅱ) Catalyst System for the Addition of Arylboronic Acids to Arylaldehydes","titleCn":"镍催化芳基硼酸与芳基醛的加成反应","titleEn":"A Simple Nickel(Ⅱ) Catalyst System for the Addition of Arylboronic Acids to Arylaldehydes","viewCount":260,"volume":"81","year":2018}],"研究简报":[{"abstractInfo":"以椴木为前驱体、二氧化碳为活化剂，制备出具有一定强度、无需粘结剂的电极材料，同时可用作集流体。通过扫描电镜、X射线衍射、拉曼光谱和孔径分析等对材料的形貌和孔结构进行了分析，并使用电吸附脱盐装置测试了其电吸附脱盐性能。结果表明，该材料有大量的微孔结构，比表面积为1440m<sup>2<\/sup>/g，其电吸附脱盐能力随着溶液浓度的提高而升高，在溶液浓度为200、500、1000和2000mg/L时，吸附量分别为2.02、3.76、6.21和12.42mg/g。","abstractInfoCn":"以椴木为前驱体、二氧化碳为活化剂，制备出具有一定强度、无需粘结剂的电极材料，同时可用作集流体。通过扫描电镜、X射线衍射、拉曼光谱和孔径分析等对材料的形貌和孔结构进行了分析，并使用电吸附脱盐装置测试了其电吸附脱盐性能。结果表明，该材料有大量的微孔结构，比表面积为1440m<sup>2<\/sup>/g，其电吸附脱盐能力随着溶液浓度的提高而升高，在溶液浓度为200、500、1000和2000 mg/L时，吸附量分别为2.02、3.76、6.21和12.42 mg/g。","abstractInfoEn":"In this work a novel binder-free electrode material is prepared through carbon dioxide activation by using basswood as a precursor, and it is also used as current collector. The morphology, structure, and pore properties are revealed by a variety of characterization methods, such as SEM, X-ray diffraction, Raman spectroscopy, nitrogen adsorption-desorption measurement. The capacitive desalination performance of the material was tested by capacitive desalination device. The results showed that the material has a large number of microporous structure with a specific surface area of 1440m<sup>2<\/sup>/g. At the solution solubility of 200, 500, 1000 and 2000 mg/L, the adsorption capacities were 2.02, 3.76, 6.21 and 12.42 mg/g, respectively.","articleNo":"","authorCnList":["董世知"," 王恩杰"," 马壮"],"authorEnList":["Dong Shizhi"," Wang Enjie"," Ma Zhuang"],"authorList":["董世知"," 王恩杰"," 马壮"],"authors":"董世知, 王恩杰, 马壮","authorsCn":"董世知, 王恩杰, 马壮","authorsEn":"Dong Shizhi, Wang Enjie, Ma Zhuang","categoryName":"研究简报","categoryNameCn":"研究简报","categoryNameEn":"","citation":"董世知, 王恩杰, 马壮. 一种新型无粘结剂电极的制备及电吸附脱盐性能研究. 化学通报, 2018, 81(12): 1143-1146.","citationCn":"董世知, 王恩杰, 马壮. 一种新型无粘结剂电极的制备及电吸附脱盐性能研究. 化学通报, 2018, 81(12): 1143-1146.","citationEn":"董世知, 王恩杰, 马壮. Study on Synthesis and Capacitive Deionization Performance of a Novel Binder-Free Electrodes. Chemistry, 2018, 81(12): 1143-1146.","doi":"","figContent":"hxtb-81-12-1143-1.jpg$$hxtb-81-12-1143-2.jpg$$hxtb-81-12-1143-3.jpg$$hxtb-81-12-1143-4.jpg$$hxtb-81-12-1143-5.jpg$$hxtb-81-12-1143-6.jpg","figList":["hxtb-81-12-1143-1.jpg","hxtb-81-12-1143-2.jpg","hxtb-81-12-1143-3.jpg","hxtb-81-12-1143-4.jpg","hxtb-81-12-1143-5.jpg","hxtb-81-12-1143-6.jpg"],"firstFig":"hxtb-81-12-1143-1.jpg","fpage":"1143","highCitedState":"","htmlCount":8,"htmlFile":"","id":"56a37c01-3053-4a52-a7e7-f638d9ca55d5","issnPpub":"0441-3776","issue":"12","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"电吸附脱盐, 无粘结剂, 二氧化碳活化","keywordCn":"电吸附脱盐, 无粘结剂, 二氧化碳活化","keywordCnList":["电吸附脱盐"," 无粘结剂"," 二氧化碳活化"],"keywordEn":"Capacitive deionization, Binder-free, Carbon dioxide activation","keywordEnList":["Capacitive deionization"," Binder-free"," Carbon dioxide activation"],"keywordList":["电吸附脱盐"," 无粘结剂"," 二氧化碳活化"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"1146","oldUrl":"","pdfDownCount":5,"pdfSize":1948.22,"pubDate":"2018-12-18","recommendState":"","releaseState":"1","secCount":0,"title":"一种新型无粘结剂电极的制备及电吸附脱盐性能研究","titleCn":"一种新型无粘结剂电极的制备及电吸附脱盐性能研究","titleEn":"Study on Synthesis and Capacitive Deionization Performance of a Novel Binder-Free Electrodes","viewCount":134,"volume":"81","year":2018}]}