Citation: OUYANG Miao, LI Jia-Ming, JIANG Yi-Min, LIU Xu-Hui, ZHANG Hui-Ying, LIAO Bei-Ling. Synthesis and Crystal Structure of a New 2D O-bridged Copper(Ⅱ) Coordination Polymer Constructed from Sulfonate-derived Schiff Base[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 299-305. doi: 10.14102/j.cnki.0254-5861.2011-0493 shu

Synthesis and Crystal Structure of a New 2D O-bridged Copper(Ⅱ) Coordination Polymer Constructed from Sulfonate-derived Schiff Base

a.
a. School of Chemistry and Bioengineering, Hechi University, Yizhou 546300, China;
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b. College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, China;
c.
c. College of Chemistry and Chemical Engineering, Qinzhou University, Qinzhou 535000, China

Received Date: 2 September 2014
Available Online: 11 November 2014
Fund Project: Supported by Guangxi Provincial Department of Education (No. YB2014333) (No. YB2014333) the Project of Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University) (No. 20110330)Key Subjects of Universities in Guangxi Province Applied Chemistry (2007<20>) (Guangxi Normal University)

A new chain-like coordination polymer, namely, [CuL]_n (1, Na₂L=2-[(2-hydroxybenzylidene)-amino]-benzenesulfonic acid sodium salt), has been synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Complex 1 crystallizes in monoclinic system, space group P2₁/c with a=9.2296(16), b=10.4754(18), c=12.200(2)Å, β=102.392(2)°, V=1152.0(3)Å³, C₁₃H₉CuNO₄S, M_r=338.83, D_c=1.953 g/cm³, Z=4, F(000)=684, μ=2.089 mm^-1, the final R=0.0376 and wR=0.0956. X-ray diffraction analyses indicate that 1 displays a square-pyramidal metal center with NO₄ donor sets. The sulfonate-derived Schiff base serves as a common N,O,O'-tridentate and a unique O-bridged ligand connecting the metals. Dinuclear copper complexes serve as secondary building blocks (SBUs) to construct an unusual 2D coordination network. In the crystal, the components form a stable 3D supramolecular architecture by C-H…O interactions and π-stacking.
- sulfonate-derived Schiff base,
- copper(Ⅱ) complex,
- synthesis,
- crystal structure
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