Citation: HUANG Nan-Nan, WANG Xiao-Dan, YU Ying-Hui, GAO Jin-Sheng, HOU Guang-Feng. A Three-dimensional Zn^Ⅱ Based Coordination Polymer with 2-Fold Interpenetrated Topology Displaying Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 292-298. doi: 10.14102/j.cnki.0254-5861.2011-0487 shu

A Three-dimensional Zn^Ⅱ Based Coordination Polymer with 2-Fold Interpenetrated Topology Displaying Luminescent Property

a.
a. Pharmaceutical College, Heilongjiang University of Traditional Chinese Medicine, Harbin 150040, China;
b.
b. Engineering Research Centre of Pesticide of Heilongjiang University, Heilongjiang University, Harbin 150080, China

Received Date: 29 August 2014
Available Online: 26 October 2014
Fund Project: Support by the National Natural Science Foundation of China (21371052) (21371052)

A new coordination polymer, [Zn₂(m-bix)(p-bdc)₂] (1), was synthesized under hydrothermal conditions by a reaction of 1,3-bis(imidazol-1-ylmethyl)benzene (m-bix), 1,3-benzenedicarboxylic acid (H₂p-bdc) and Zn(NO₃)₂. The colorless block crystals of complex 1 (C₃₀H₂₂N₄O₈Zn₂) belong to the triclinic system, space group P1 with a=10.213(2), b=12.052(2), c=12.392(3)Å, α=82.97(3), β=76.04(3), γ=78.02(3)°, V=1443.8(5)Å³, Z=2, D_c=1.604 g/cm^-3, M_r=697.26, F(000)=708, R=0.0403 and wR=0.0907 for 4886 observed reflections (I>2σ(I)). In 1, the tetrahedral Zn^Ⅱ cations are linked by [p-bdc]^2- anions into 2D sq1 networks, which are further connected by bix ligands forming an interesting 2-fold 4,4-connected mog-type 3D network with a point symbol of {4·6⁴·8}²{4²·6²·8²}. Complex 1 was characterized by elemental, IR spectroscopy, powder X-ray diffractions and thermalgravimetric analysis. In addition, complex 1 exhibits coordination induced photoluminescent property.
- coordination polymer,
- crystal structure; mog-type topology,
- photoluminescent
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