Citation: KONG Chun-Yan. Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a New Cd(Ⅱ) Coordination Polymer with Four-fold Interpenetrated dia Topology[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 267-271. doi: 10.14102/j.cnki.0254-5861.2011-0477 shu

Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a New Cd(Ⅱ) Coordination Polymer with Four-fold Interpenetrated dia Topology

KONG Chun-Yan ^,

1.
College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China

Corresponding author: KONG Chun-Yan,
Received Date: 2 August 2014
Available Online: 21 October 2014

A new Cd(Ⅱ) coordination polymer with 2-nitroterephthalic acid (H₂npa) and 1,4-bis(2-methyl-imidazol-1-yl) butane (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR and EA. Complex [Cd(npa)(bib)]_n (1) is of orthorhombic system, space group Pcca with a=16.1750(5), b=9.8764(5), c=15.5890(3)Å, V=2490.4(2)Å³, Z=4, M_r=539.82, D_c=1.440 g/cm³, F(000)=1088, μ=0.918 mm^-1, the final R=0.0320 and wR=0.0775 for 2253 reflections with I>2σ(I). X-ray diffraction analysis reveals that complex 1 displays a four-fold interpenetrated dia topology. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.
- Cd(Ⅱ),
- coordination polymer,
- luminescence
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