Citation: PAN Jian-Ting, DING Ai-Xiang, YANG Jia-Xiang, HUANG Jian-Yan, KONG Lin. Pyridine-contained α-Cyanostilbenzene Schiff Base: Preparation, Crystal Structure and Photoluminescence[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 215-220. doi: 10.14102/j.cnki.0254-5861.2011-0463 shu

Pyridine-contained α-Cyanostilbenzene Schiff Base: Preparation, Crystal Structure and Photoluminescence

1.
Department of Chemistry, Anhui University, Hefei 230039, China

Received Date: 25 July 2014
Available Online: 5 December 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (21101001) (21101001)the Educational Commission of Anhui Province (KJ2014ZD02) (KJ2014ZD02)

A novel pyridine-contained α-cyanostilbenzene Schiff base, (Z)-3-(4-butoxyphenyl)-2-(4-((E)-pyridin-2-yl-methyleneamino)phenyl)acrylonitrile (L), has been synthesized and characterized by ¹H NMR, ¹³C NMR, FT-IR spectra and single-crystal X-ray diffraction. Single-crystal data show that compound L belongs to the triclinic system, space group P1, with a=8.759(4), b=10.779(4), c=12.594(5)Å, α=65.873(4), β=88.332(5), γ=73.800(5)°, M_r=381.46, V=1037.2(7)Å³, Z=2, D_c=1.221 g/cm^-3, μ=0.076 mm^-1, F(000)=404, R_int=0.0311, R (I>2σ(I))=0.0484, wR (I>2σ(I))=0.1544, R (all data)=0.0484, wR (all data)=0.1692, completeness to theta=25.000 being 99.0% and GOF=1.179. There are two kinds of intermolecular hydrogen bonds and one kind of C-H…π weak interaction between adjacent molecules. Compound L can be used as a candidate for desirable devices with high performance due to its good thermal stability and excellent optical performance.
- pyridine,
- Schiff base,
- single-crystal,
- intermolecular H-bond,
- optical performance
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