Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Syntheses, Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 227-234. doi: 10.14102/j.cnki.0254-5861.2011-0455 shu

Syntheses, Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid

a.
a. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;
b.
b. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GAO Zhu-Qing,
Received Date: 18 July 2014
Available Online: 23 December 2014
Fund Project: This project was supported by the Natural Science Foundation of Shanxi Province (No. 2013011011-6) (No. 2013011011-6)

Two coordination compounds, namely [Ce(3,5-Br₂BC)₃(3,5-HBr₂BC)]_n (1) and [Zn(3,5-Br₂BC)₂(phen)] (2, 3,5-HBr₂BC=3,5-dibromobenzoic acid, phen=1,10-phenanthroline), were assembled. Single-crystal X-ray diffraction studies show that compound 1 possesses a 1D chain coordination network, which is further extended into a 3D supramolecular architecture via Br…Br and Br…O halogen bonding. Compound 2 consists of a mononuclear molecule, which is assembled to a 3D supramolecular framework through C-H…O hydrogen bond, π-π stacking interactions and Br…π halogen bonding. Luminescent and magnetic properties of both compounds have also been studied.
- coordination compound,
- 3,5-dibromobenzoic acid,
- luminescent properties,
- magnetic properties
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