Citation: WANG Ji-Jiang, SU Yong-Chao, GAO Lou-Jun. Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Based on 1,3-Di(2,4-dicarboxyphenyl) Benzene and 1,3-Di(4-pyridyl)propane[J]. Chinese Journal of Structural Chemistry, ;2015, 34(2): 241-247. doi: 10.14102/j.cnki.0254-5861.2011-0416 shu

Syntheses, Structures, and Photoluminescent Properties of Two 2D Coordination Polymers Based on 1,3-Di(2,4-dicarboxyphenyl) Benzene and 1,3-Di(4-pyridyl)propane

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: GAO Lou-Jun,
Received Date: 16 June 2014
Available Online: 12 November 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21373178) (No. 21373178) and the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124) (338080043)

Two new 2D coordination polymers, [Zn(HL)(Hbpp)]_n (1) and [Cd(HL)(Hbpp)(H₂O)]_n (2) (H₄L=1,3-di(2,4-dicarboxyphenyl) benzene, bpp=1,3-di(4-pyridyl)propane), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis, TGA and IR spectroscopy. Complex 1 crystallizes in monoclinic, space group P2₁/n, with a=13.1031(6), b=14.7315(7), c=15.0041(7)Å, β=91.202(1)°, V=2895.6(2)Å³, D_c=1.532 g/cm³, M_r=667.97, F(000)=1376.0, μ=0.909 mm^-1, Z=4, the final R=0.0481 and wR=0.1304 for 7027 observed reflections with I>2σ(I). Complex 2 also belongs to the monoclinic space group P2₁/n, with a=13.6326(4), b=14.6432(4), c=14.9395(5)Å, β=93.132(1)°, V=2977.84(16)Å³, D_c=1.613 g/cm³, M_r=1445.98, F(000)=733.0, μ=0.794 mm^-1, Z=2, the final R=0.0283 and wR=0.0784 for 7230 observed reflections with I>2σ(I). Both complexes 1 and 2 form 2D net structures, which are further linked to form 3D supramolecular net structures via intermolecular hydrogen bonds and aromatic π-π stacking interactions.
- 1,3-di(2,4-dicarboxyphenyl) benzene,
- Zn(Ⅱ),
- Cd(Ⅱ),
- photoluminescent properties
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