Citation: CHEN Yong-Qiang, TIAN Yuan. A Zinc(Ⅱ) Coordination Framework Based on Terpyridine and 5-Nitroisophthalic Acid Mixed Ligands: Synthesis, Crystal Structure and Fluorescence Property[J]. Chinese Journal of Structural Chemistry, ;2014, 33(11): 1587-1592. doi: 10.14102/j.cnki.0254-5861.2011-0282 shu

A Zinc(Ⅱ) Coordination Framework Based on Terpyridine and 5-Nitroisophthalic Acid Mixed Ligands: Synthesis, Crystal Structure and Fluorescence Property

1.
College of Chemistry and Chemical Engineering, Jinzhong University, Yuci, Shanxi 030600, China

Received Date: 7 May 2014
Available Online: 21 September 2014
Fund Project:

A new coordination framework, {[Zn(L1)(5-nipc)]·H₂O}_n (1, L1=4'-(4-pyridyl)-4,2':6',4"-terpyridine, 5-nipc=5-nitroisophthalic acid), has been prepared under hydrothermal conditions, and determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, IR and powder X-ray diffraction. Complex 1 crystallizes in monoclinic, space group C2/c with a=29.983(9), b=13.709(3), c=14.391(3)Å, β=114.93(4)°, V=5364(2)Å³, D_c=1.493 g/cm³, C₂₈H₁₉N₅O₇Zn, M_r=602.85, F(000)=2464, μ(MoKα)=0.972 mm^-1, Z=8, R=0.0935 and wR=0.1509 for 4724 observed reflections (I>2σ(I)). The structure of 1 exhibits a three-dimensional (3D) network with a layer-pillar structure. The fluorescence property of 1 is also investigated.
- coordination framework,
- mixed-ligand approach,
- crystal structure,
- property
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