Citation: Deepanjali Pandey, Shahid S. Narvi, Gopal K. Mehrotra, Raymond J. Butcher. Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] Complex Showing Spin Canted Anti-ferromagnetic Character[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 777-785. doi: 10.14102/j.cnki.0254-5861.2011-0259 shu

Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] Complex Showing Spin Canted Anti-ferromagnetic Character

1.
a Department of Chemistry, Motilal Nehru National Institute of Technology Allahabad-211004, India;
b Department of Chemistry, Howard University, 2400 Sixth Street, N.
b Department of Chemistry, Howard University, 2400 Sixth Street, N.W, Washington, DC 20059, USA)

Corresponding author: Deepanjali Pandey,
Received Date: 3 March 2014
Available Online: 12 March 2015

A new three-dimensional nickel (II) hydrogen-bonded molecular self assembly containing [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] complex has been synthesized and characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermal analysis and magnetic measurements. Structural analysis reveals that the complex crystallizes in triclinic space group P1 (crystal data a=7.5574, b=8.2683, c=9.0056 Å, α=73.010, β=69.698, γ=66.51°) and exhibits a distorted octahedral coordination sphere. Most interesting point in its structure is the involvement of sulphur atom of thiocyanate moiety in the trifurcated hydrogen bonding to build up the hydrogen-bonded self assembly. The magnetic behavior as determined by squid magnetometer (2~300 K temp. range) reveals dominating antiferromagnetic interaction followed by spin canting behavior below 20 K.
- hydrogen bonded 3D structure,
- intermolecular magnetic interaction,
- spin canting
1. [1]
  Saisai Yuan , Yiming Chen , Xijuan Wang , Degui Zhao , Tengyang Gao , Caiyun Wei , Chuanxiang Chen , Yang Yang , Wenjing Hong . Decouple the intermolecular interaction by encapsulating an insulating sheath. Chinese Chemical Letters, 2025, 36(6): 110816-. doi: 10.1016/j.cclet.2025.110816
2. [2]
  Jinjin Yang , Chuanhui Zhu , Shuang Zhao , Tao Xia , Pengfei Tan , Yutian Zhang , Mei-Huan Zhao , Yijie Zeng , Man-Rong Li . Spin-orbit-controlled metal-insulator transition in metastable SrIrO₃ stabilized by physical and chemical pressures. Chinese Chemical Letters, 2025, 36(6): 109891-. doi: 10.1016/j.cclet.2024.109891
3. [3]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
4. [4]
  Chong-Yang Shi , Jian-Xing Gong , Zhen Li , Chao Shu , Long-Wu Ye , Qing Sun , Bo Zhou , Xin-Qi Zhu . Gold-catalyzed intermolecular amination of allyl azides with ynamides: Efficient construction of 3-azabicyclo[3.1.0] scaffold. Chinese Chemical Letters, 2025, 36(2): 109895-. doi: 10.1016/j.cclet.2024.109895
5. [5]
  Songtao Cai , Liuying Wu , Yuan Li , Soham Samanta , Jinying Wang , Bing Liu , Feihu Wu , Kaitao Lai , Yingchao Liu , Junle Qu , Zhigang Yang . Intermolecular hydrogen-bonding as a robust tool toward significantly improving the photothermal conversion efficiency of a NIR-II squaraine dye. Chinese Chemical Letters, 2024, 35(4): 108599-. doi: 10.1016/j.cclet.2023.108599
6. [6]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
7. [7]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
8. [8]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
9. [9]
  Chengmin Hu , Pingxuan Liu , Ziyang Song , Yaokang Lv , Hui Duan , Li Xie , Ling Miao , Mingxian Liu , Lihua Gan . Tailor-made overstable 3D carbon superstructures towards efficient zinc-ion storage. Chinese Chemical Letters, 2025, 36(4): 110381-. doi: 10.1016/j.cclet.2024.110381
10. [10]
  Run Chai , Qiujie Wu , Yongchao Liu , Xiaohui Song , Xuyong Feng , Yi Sun , Hongfa Xiang . A 3D dual layer host with enhanced sodiophilicity as stable anode for high-energy sodium metal batteries. Chinese Chemical Letters, 2025, 36(6): 110007-. doi: 10.1016/j.cclet.2024.110007
11. [11]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
12. [12]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
13. [13]
  Yi Zhu , Jingyan Zhang , Yuchao Zhang , Ying Chen , Guanghui An , Ren Liu . Designing unimolecular photoinitiator by installing NHPI esters along the TX backbone for acrylate photopolymerization and their applications in coatings and 3D printing. Chinese Chemical Letters, 2024, 35(7): 109573-. doi: 10.1016/j.cclet.2024.109573
14. [14]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234
15. [15]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
16. [16]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
17. [17]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
18. [18]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
19. [19]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
20. [20]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353