Citation: Zhi-Qiang LU, Yan-Zhi LI, Chu HAO, Yi RU, Shu-Jian YANG, Ning-Dan ZHANG, Yu-Qin FU, Wei-Long WU, Yan ZHOU. Synthesis, Crystal Structure and Luminescent/magnetic Properties of Two Metal-organic Frameworks Based on Multi-N/O-donor Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1122-1130. doi: 10.14102/j.cnki.0254–5861.2011–3206 shu

Synthesis, Crystal Structure and Luminescent/magnetic Properties of Two Metal-organic Frameworks Based on Multi-N/O-donor Mixed Ligands

Zhi-Qiang LU ^{a, b,,} ,
Yan-Zhi LI ^{a, b} ,
Chu HAO ^b ,
Yi RU ^b ,
Shu-Jian YANG ^b ,
Ning-Dan ZHANG ^b ,
Yu-Qin FU ^b,, ,
Wei-Long WU ^b ,
Yan ZHOU ^b

a.
Hubei Key Laboratory of Natural Products Research and Development, Key Laboratory of Functional Yeast (China National Light Industry), College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, China
b.
Luoyang Key Laboratory of Organic Functional Molecules, School of Chemistry & Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: Zhi-Qiang LU, zqlu2000@163.com Yu-Qin FU, lyfuyuqin@126.com
Received Date: 6 April 2021
Accepted Date: 15 June 2021

Fund Project: the National Natural Science Foundation of China U1304206the National Natural Science Foundation of China 21801112Natural Science Foundation of Henan Province 212300410374Science and Technology Project of Hennan Province 212102210549the Key Scientific Research Project of Higher Education of Henan Province 13A150799

Figures(13)

Two new complexes, namely [Cd₂(L)(pycy)(Cl)]·2H₂O (1) and [Cu(HL)(H₂btac)]·2H₂O, have been synthesized by the reaction of the corresponding metal salts with mixed ligands including 1-(1H-imidazol-4-yl)-4-(4H-tetrazol-5-yl)benzene (HL), 2, 6-pyridinedicarboxylic acid (H₂pycy) and 1, 2, 4, 5-benzenetetracarboxylic acid (H₄btac), and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and powder X-ray diffraction (PXRD). Complex 1 crystallizes in triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 9.8938(7), b = 10.1662(7), c = 12.4520(8) Å, α = 92.7070(10), β = 108.1310(10), γ = 105.3230(10)°, V = 1136.44(13) Å³, Z = 2, C₁₇H₁₂N₇O₆ClCd₂, M_r = 670.59, D_c = 1.960 g/cm³, μ = 2.037 mm^-1, S = 1.062, F(000) = 648, the final R = 0.0532 and wR = 0.1651 for 12156 observed reflections (I > 2σ(I)). Complex 2 crystallizes in triclinic, space group P\begin{document}$ \overline 1 $\end{document} with a = 7.3058(8), b = 7.4890(8), c = 10.8937(12) Å, α = 71.3810(10), β = 84.134(2), γ = 65.745(2)°, V = 514.68(10) Å³, Z = 1, C₂₀H₁₆CuN₆O₁₀, M_r = 563.94, D_c = 1.819 g/cm³, μ = 1.139 mm^-1, S = 1.187, F(000) = 287, the final R = 0.0314 and wR = 0.0807 for 3564 observed reflections (I > 2σ(I)). Single-crystal X-ray structural analysis reveals that complex 1 features a trinodal (3, 3, 4)-connected two-dimensional (2D) net layer with Schläfli symbol (4·6·8)(4·6²·8³)(6²·8) while 2 has a 2D network with 4⁴ sql topology. Moreover, the photoluminescent property of 1 and magnetic property of 2 were also discussed.
- synthesis,
- complex,
- luminescence,
- magnetic property
1. [1]
  Zhang, Y. M.; Yuan, S.; Day, G.; Wang, X.; Yang, X. Y.; Zhou, H. C. Luminescent sensors based on metal-organic frameworks. Coord. Chem. Rev. 2018, 354, 28–45. doi: 10.1016/j.ccr.2017.06.007
2. [2]
  Li, B.; Zang, S. Q.; Wang, L. Y.; Mak, T. C. W. Halogen bonding: a powerful, emerging tool for constructing high-dimensional metal-containing supramolecular networks. Coordin. Chem. Rev. 2016, 308, 1–21. doi: 10.1016/j.ccr.2015.09.005
3. [3]
  Zhao, J. P.; Han, S. D.; Jiang, X.; Xu, J.; Chang, Z.; Bu, X. H. A three dimensional magnetically frustrated metal-organic framework via the vertices augmentation of underlying net. Chem. Commun. 2015, 51, 4627−4630. doi: 10.1039/C4CC09547B
4. [4]
  Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815–5840. doi: 10.1039/C4CS00010B
5. [5]
  Lustig, W. P.; Mukherjee, S.; Mukherjee, N. D.; Rudd, A. V.; Desai, J.; Li, S. K. Ghosh, metal-organic frameworks: functional luminescent and photonic materials for sensing applications. Chem. Soc. Rev. 2017, 46, 3242–3285. doi: 10.1039/C6CS00930A
6. [6]
  Chen, S. S. The roles of imidazole ligands in coordination supramolecular systems. CrystEngComm. 2016, 18, 6543–6565. doi: 10.1039/C6CE01258B
7. [7]
  Dong, X. Y.; Zhang, M.; Pei, R. B.; Wang, Q.; Wei, D. H.; Zang, S. Q.; Fan, Y. T.; Mak, T. C. W. A crystalline copper(II) coordination polymer for the efficient visible-light-driven generation of hydrogen. Angew. Chem. Int. Ed. 2016, 55, 2073–2077. doi: 10.1002/anie.201509744
8. [8]
  Hall, G. S.; Angeles, M. J.; Hicks, J.; Turner, D. R. Centric and acentric networks using low symmetry heterotopic carboxylate/pyridyl ligands. CrystEngComm. 2016, 18, 6614–6623. doi: 10.1039/C6CE01000H
9. [9]
  Wang, F.; Fu, H. R.; Kang, Y.; Zhang, J. A new approach towards zeolitic tetrazolate-imidazolate frameworks (ZTIFs) with uncoordinated N-heteroatom sites for high CO₂ uptake. Chem. Commun. 2014, 50, 2065–12068. doi: 10.1039/c4cc90030h
10. [10]
  Mei, Y. X.; Xu, F.; Wei, Z. H.; Cai, H. pH dependent supramolecules based on co-crystallization of pyrazine-2, 3, 5, 6-tetracarboxylic acid with 4, 4΄-bipyridine through intermolecular hydrogen bonds. Chin. J. Struct. Chem. 2016, 35, 1031–1037.
11. [11]
  Li, X. M.; Sun, M.; Pan, Y. R. Synthesis, crystal structure and theoretical calculations of a nickel(II) coordination polymer assembled by 4, 4΄-oxydibenzoicacid and 1, 3-bis(imidazol-1-ylmethyl)-benzene ligands. Chin. J. Struct. Chem. 2015, 34, 710–718.
12. [12]
  Guo, X. Z.; Chen, S. S.; Li, W. D.; Han, S. S.; Deng, F.; Qiao, R.; Zhao, Y. Series of cadmium(II) coordination polymers based on a versatile multi-N-donor tecton or mixed carboxylate ligands: synthesis, structure, and selectively sensing property. ACS Omega 2019, 4, 11540−11553. doi: 10.1021/acsomega.9b01108
13. [13]
  Hua, J. A.; Zhao, Y.; Kang, Y. S.; Lu, Y.; Sun, W. Y. Solvent dependent zinc(II) coordination polymers with mixed ligands: selective sorption and fluorescence sensing. Dalton Trans. 2015, 44, 11524−11532. doi: 10.1039/C5DT01386K
14. [14]
  Zhang, C.; Liu, Z. Y.; Liu, N.; Zhao, H.; Yang, E. C.; Zhao, X. J. Different magnetic responses observed in Co₄^II, Co₃^II and Co₁^II based MOFs. Dalton Trans. 2016, 45, 11864−11875. doi: 10.1039/C6DT01587E
15. [15]
  Wang, W.; Wang, R.; Liu, L.; Wu, B. Coordination frameworks containing magnetic single chain of imidazoledicarboxylate-bridged cobalt(II)/nickel(II): syntheses, structures, and magnetic properties. Cryst. Growth Des. 2018, 18, 3449−3457. doi: 10.1021/acs.cgd.8b00174
16. [16]
  Hao, X. N.; Zheng, B. H.; Hu, T. P. Syntheses and characterizations of Cd(II) and Pr(III) complexes based on 5-(tetrazol-5-yl) isophthalic acid. Chin. J. Struct. Chem. 2016, 35, 1186–1194.
17. [17]
  Yang, Y.; Jiang, F.; Liu, C.; Chen, L.; Gai, Y.; Pang, J.; Su, K.; Wan, X.; Hong, M. Self-assembly syntheses, structural characterization, and luminescent properties of lanthanide coordination polymers constructed by three triazole-carboxylate ligands. Cryst. Growth Des. 2016, 16, 2266−2276. doi: 10.1021/acs.cgd.6b00060
18. [18]
  Chen, S. S.; Sheng, L. Q.; Zhao, Y.; Liu, Z. D.; Qiao, R.; Yang, S. Syntheses, structures, and properties of a series of polyazaheteroaromatic core-based Zn(II) coordination polymers together with carboxylate auxiliary ligands. Cryst. Growth Des. 2016, 16, 229–241. doi: 10.1021/acs.cgd.5b01133
19. [19]
  Chen, S. S.; Qiao, R.; Sheng, L. Q.; Zhao, Y.; Yang, S.; Chen, M. M.; Liu, Z. D.; Wang, D. H. Cadmium(II) and zinc(II) complexes with rigid 1-(1H-imidazol-4-yl)-3-(4H-tetrazol-5-yl)benzene and varied carboxylate ligands. CrystEngComm. 2013, 15, 5713–5725. doi: 10.1039/c3ce40150b
20. [20]
  Sheldrick, G. M. SHELXS-97, Programm for the Solution of Crystal Structure. University of Göttingen 1997.
21. [21]
  Sheldrick, G. M. SHELXL-97, Programm for the Refinement of Crystal Structure. University of Göttingen 1997.
22. [22]
  Liang, X. Q.; Wu, T.; Fan, Z. L. An 8-connected chiral lanthanide metal-organic framework constructed from naturally camphoric acid: crystal structure, vibrational circular dichroism spectroscopy and second-order nonlinear optical effect. Chin. J. Struct. Chem. 2016, 35, 1736–1744.
23. [23]
  Wang, D. Z.; Fan, J. Z.; Jia, D.; Du, C. C. Zinc and cadmium complexes based on bis-(1H-tetrazol-5-ylmethyl/ylethyl)-amine ligands: structures and photoluminescence properties. CrystEngComm. 2016, 18, 6708–6723. doi: 10.1039/C6CE01311B
24. [24]
  Chen, S. S.; Qiao, R.; Sheng, L. Q.; Yang, S.; Liu, Z. D. Four complexes with the rigid ligand 1, 4-bis(1H-imidazol-4-yl)benzene and varied carboxylate ligands. Z. Anorg. Allg. Chem. 2013, 639, 1808–1814. doi: 10.1002/zaac.201300189
25. [25]
  Liu, K.; Ma, B. H.; Guo, X. L.; Ma, D. X.; Meng, L. K.; Zeng, G.; Yang, F.; Li, G. H.; Shi, Z.; Feng, S. H. Syntheses, structures, luminescence and magnetic properties of eleven coordination polymers constructed by a N, N΄-sulfuryldiimidazole ligand. CrystEngComm. 2015, 17, 5054. doi: 10.1039/C5CE00807G
26. [26]
  Cui, Y. J.; Yue, Y. F.; Qian, G. D.; Chen, B. L. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 1126–1162.
27. [27]
  Zhang, K. Y.; Yu, Q.; Wei, H. J.; Liu, S. J.; Zhao, Q.; Huang, W. Long-lived emissive probes for time-resolved photoluminescence bioimaging and biosensing. Chem. Rev. 2018, 118, 1770–1839. doi: 10.1021/acs.chemrev.7b00425
28. [28]
  Yang, L.; Li, X.; Qin, C.; Zhao, L.; Shao, K. Z.; Su, Z. M. Metal-organic frameworks constructed from tib and carboxylate acid ligands: selective sensing of nitro explosives and magnetic properties. Dalton Trans. 2017, 46, 7567–7576.
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