Citation: Juan-Zhi YAN, Dan ZHAO, Li-Ping LU. Comparison and Relation between Crystal Structures and Magnetic Properties of Two Manganese(Ⅱ) Coordination Polymers Based on (Triazol-1-yl)iso/terephthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1469-1474. doi: 10.14102/j.cnki.0254–5861.2011–3186 shu

Comparison and Relation between Crystal Structures and Magnetic Properties of Two Manganese(Ⅱ) Coordination Polymers Based on (Triazol-1-yl)iso/terephthalic Acid

a.
Taiyuan University, Taiyuan 030032, China
b.
Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: Li-Ping LU, luliping@sxu.edu.cn
Received Date: 19 March 2021
Accepted Date: 1 June 2021

Fund Project: NNSFC 21571118

Figures(6)

One new Mn(Ⅱ) coordination polymer, [Mn(Htia)₂(H₂O)₂]_n·2nH₂O (1, H₂tia = 4-(1, 2, 4-triazol-1-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions. Further characterizations including single-crystal XRD, elemental analysis, IR spectroscopy, thermogravimetric analysis and powder XRD were performed to verify the structure. Complex 1 displays a one-dimensional (1D) chain and is similar to a reported Mn(Ⅱ) complex 2 {[Mn(Htta)₂(H₂O)₂]·2H₂O}_n. It crystallizes in triclinic P\begin{document}$ \overline 1 $\end{document} space group, with a = 7.5557 (3), b = 7.5974 (3), c = 11.8448 (4) Å, α = 90.088(1)°, β = 95.863(1)°, γ = 113.668(1)°, V = 618.81(4) Å³, Z = 1, M_r = 591.36 g/mol, D_c = 1.587 mg/m³, μ = 0.609 mm^-1, F(000) = 303, GOOF = 1.062, the final R = 0.0359 and wR = 0.0818 for 4272 observed reflections with I > 2σ(I). Based on two similar structures, Hirshfeld surface analysis confirmed both structures are mainly stabilized by O···H/H···O and C···H/H···C hydrogen bonds. Further, weak ferromagnetic behaviors between adjacent Mn(Ⅱ) ions in 1D chain are obtained.
- manganese(Ⅱ) complexes,
- (triazol-1-yl)iso/terephthalic acid,
- crystal structure,
- Hirshfeld surface,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142