Citation: Liang LIN, Zan-Yong ZHUANG. A Self-growing Porous Calcium-based Adsorbent Derived from Biowaste for Efficient Wastewater Purification[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1328-1336. doi: 10.14102/j.cnki.0254–5861.2011–3173 shu

A Self-growing Porous Calcium-based Adsorbent Derived from Biowaste for Efficient Wastewater Purification

Liang LIN ^a ,
Zan-Yong ZHUANG ^{b, c,,}

a.
Fujian Chuanzheng Communications College, Fuzhou 350007, China
b.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
c.
Key Laboratory of Advanced Materials Technologies (Fuzhou University), Fujian Province University, Fuzhou 350108, China

Corresponding author: Zan-Yong ZHUANG, zyzhuang@fzu.edu.cn
Received Date: 11 March 2021
Accepted Date: 17 June 2021

Fund Project: the National Natural Science Foundation of China 51772053

Figures(10)

Traditional adsorbents are normally suffered from a low adsorption capacity that has a finite saturated adsorption capacity. We reported herein a hierarchical self-growing porous calcium silicate hydrate (CSH) that uses biowaste as the precursor and is highly efficient in wastewater purification. In the process of phosphorus removal, CSH can react with phosphorus in water and grow into the hydroxyapatite (HAP). The generation of HAP further increases the active sites while maintains the porous structure of pristine CSH. Subsequently, the HAP could conduct the efficient extraction of Pb²⁺ from wastewater based on the ion exchange between Ca²⁺ and Pb²⁺. Clearly, the CSH structure has self-growing structure using the pollutants as the building blocks, not only achieving high adsorption capacity for pollutants, but also maintaining the hierarchically porous structure that supports the high efficiency in the next cycling. We provide here an intriguing pathway to tackle bottleneck of the traditional adsorbents, i.e., a finite saturated adsorption capacity.
- self-growing model,
- high adsorption capacity,
- biowaste,
- porous materials,
- wastewater purifications
1. [1]
  Lin, L.; Yu, Y. Adsorption of Pb²⁺ and Cu²⁺ with unburned desulphurization slag modified nickel slag. Chin. J. Struct. Chem. 2017, 36, 491–502.
2. [2]
  Kong, F. L.; Xi, M.; Xu, L. H.; Li, Y.; Qin, P. R. Review of studies on the limitation of nutrients in the eutrophic water. J. Earth Environ. 2016, 7, 121–129.
3. [3]
  Lin, L.; Yu, Y. A study on the surface physicochemical properties of modified nickel slag adsorbent to remove Pb²⁺ and Cu²⁺ from aqueous solution. J. Fuzhou Univ. (Nat. Sci. Ed. ) 2016, 44, 119–123.
4. [4]
  Lin, L.; Yu, Y. Application of modified nickel slag adsorbent on the removal of Pb²⁺ and Cu²⁺ from aqueous solution. Chin. J. Struct. Chem. 2016, 35, 879–888.
5. [5]
  Ince, O. K.; Ince, M.; Yonten, V.; Goksu, A. A food waste utilization study for removing lead(II) from drinks. Food Chem. 2017, 214, 637–643. doi: 10.1016/j.foodchem.2016.07.117
6. [6]
  Lin, L. Preparation of wastewater phosphorus removal materials by dry FGD ash produced from iron industry. Chin. J. Struct. Chem. 2013, 32, 266–272.
7. [7]
  Yin, H. B.; Kong, M. Reduction of sediment internal P-loading from eutrophic lakes using thermally modified calcium-rich attapulgite-based thin-layer cap. J. Environ. Manage. 2015, 151, 178–185. doi: 10.1016/j.jenvman.2015.01.003
8. [8]
  Petrella, A.; Spasiano, D.; Acquafredda, P.; Vietro, N. D.; Ranieri, E.; Cosma P.; Rizzi, V.; Petruzzelli, V.; Petruzzelli, D. Heavy metals retention (Pb(II), Cd(II), Ni(II)) from single and multimetal solutions by natural biosorbents from the olive oil milling operations. Process Saf. Environ. Prot. 2018, 114, 79–90. doi: 10.1016/j.psep.2017.12.010
9. [9]
  Yan, Y. K.; Yuvaraja, G.; Liu, C. J.; Kong, L. J.; Guo, K.; Reddy, G. M.; Zyryanov, G. V. Removal of Pb(II) ions from aqueous media using epichlorohydrin crosslinked chitosan Schiff's base@Fe₃O₄(ECCSB@Fe₃O₄). Int. J. Biol. Macromol. 2018, 117, 1305–1313. doi: 10.1016/j.ijbiomac.2018.05.204
10. [10]
  Abdelrahman, E. A.; Hegazey, R. M. Utilization of waste aluminum cans in the fabrication of hydroxysodalite nanoparticles and their chitosan biopolymer composites for the removal of Ni(II) and Pb(II) ions from aqueous solutions: kinetic, equilibrium, and reusability studies. Microchem. J. 2019, 145, 18–25. doi: 10.1016/j.microc.2018.10.016
11. [11]
  Filote, C.; Volf, I.; Santos, S. C. R.; Botelho, C. M. S. Bioadsorptive removal of Pb(II) from aqueous solution by the biorefinery waste of Fucus spiralis. Sci. Total Environ. 2019, 648, 1201–1209. doi: 10.1016/j.scitotenv.2018.08.210
12. [12]
  Wang, H. Y.; Gao, B.; Wang, S. S.; Fang, J. Removal of Pb(II), Cu(II), and Cd(II) from aqueous solutions by biochar derived from KMnO₄ treated hickory wood. Bioresour. Technol. 2015, 197, 356–362. doi: 10.1016/j.biortech.2015.08.132
13. [13]
  Liu, L.; Li, C.; Bao, C. L.; Jia, Q.; Xiao, P.; Liu, X.; Zhang, Q. Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(III) and Pd(II). Talanta. 2012, 93, 350–357. doi: 10.1016/j.talanta.2012.02.051
14. [14]
  Deng, X. J.; Lü, L. L.; Li, H. W.; Luo, F. The adsorption properties of Pb(II) and Cd(II) on functionalized graphene prepared by electrolysis method. J. Hazard. Mater. 2010, 183, 923–930. doi: 10.1016/j.jhazmat.2010.07.117
15. [15]
  Kang, X. J.; Huang, S. S.; Yang, P. P.; Ma, P. A.; Yang, D. M.; Lin, J. Preparation of luminescent and mesoporous Eu³⁺/Tb³⁺ doped calcium silicate microspheres as drug carriers via a template route. Dalton Trans. 2011, 40, 1873–1879.
16. [16]
  Penn, R. L.; Banfield, J. F. Imperfect oriented attachment: dislocation generation in defect-free nanocrystals. Science 1998, 281, 969–971. doi: 10.1126/science.281.5379.969
17. [17]
  You, W. J.; Weng, Y. L.; Wang, X.; Zhuang, Z. Y.; Yu, Y. Synthesis and adsorption properties of hierarchically ordered nanostructures derived from porous CaO network. ACS Appl. Mater. Interfaces 2016, 8, 33656–33665.
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