Citation: Man WANG, Xiao-Yuan WU, Sa-Sa WANG, Can-Zhong LU. A Stable Polyoxometalate-based Coordination Polymer for Light Driven Degradation of Organic Dye Pollutant[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1449-1455. doi: 10.14102/j.cnki.0254–5861.2011–3156 shu

A Stable Polyoxometalate-based Coordination Polymer for Light Driven Degradation of Organic Dye Pollutant

Man WANG ^{a, b} ,
Xiao-Yuan WU ^b ,
Sa-Sa WANG ^b ,
Can-Zhong LU ^{b, c, d,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Xiamen Institute of Rare Earth Materials, Chinese Academy of Sciences, Xiamen 361021, China

Corresponding author: Can-Zhong LU, czlu@fjirsm.ac.cn
Received Date: 24 February 2021
Accepted Date: 29 March 2021

Fund Project: the Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH033the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21521061the National Natural Science Foundation of China 21773247the National Natural Science Foundation of China 21875252the National Natural Science Foundation of China 52073286

Figures(4)

A new POM-based coordination polymer, [Cl₂Cu₁₁^Ⅰ(trz)₈][H₃SiW₁₂O₄₀] (1), was successfully obtained under hydrothermal reaction. The compound was characterized by single-crystal X-ray diffraction, TG analyses, IR spectra and PXRD analysis. Compound 1 shows extreme stability and outstanding catalytic activity to the degradation of organic dye pollutant.
- polyoxometalate-based coordination polymer,
- photocatalysis,
- 1, 2, 4-triazole
1. [1]
  Ma, P. T.; Hu, F.; Wan, R.; Huo, Y.; Zhang, D. D.; Niu, J. Y.; Wang, J. P. Magnetic double-tartaric bridging mono-lanthanide substituted phosphotungstates with photochromic and switchable luminescence properties. J. Mater. Chem. C. 2016, 4, 5424–5433. doi: 10.1039/C6TC00960C
2. [2]
  Yamase, T. Photo- and electrochromism of polyoxometalates and related materials. Chem. Rev. 1998, 98, 307–325. doi: 10.1021/cr9604043
3. [3]
  Stracke, J. J.; Finke, R. G. Electrocatalytic water oxidation beginning with the cobalt polyoxometalate [Co₄(H₂O)₂(PW₉O₃₄)₂]^10-: identification of heterogeneous CoO_x as the dominant catalyst. J. Am. Chem. Soc. 2011, 133, 14872–14875. doi: 10.1021/ja205569j
4. [4]
  Ma, Y. Y.; Wu, C. X.; Feng, X. J.; Tan, H. Q.; Yan, L. K.; Liu, Y.; Kang, Z. H.; Wang, E. B.; Li, Y. G. Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C. Energ. Environ. Sci. 2017, 10, 788–798. doi: 10.1039/C6EE03768B
5. [5]
  Aldamen, M. A.; Clemente-Juan, J. M.; Coronado, E.; Marti-Gastaldo, C.; Gaita-Arino, A. Mononuclear lanthanide single-molecule magnets based on polyoxometalates. J. Am. Chem. Soc. 2008, 130, 8874–8875. doi: 10.1021/ja801659m
6. [6]
  Reinoso, S.; Vitoria, P.; San Felices, L.; Montero, A.; Lezama, L.; Gutierrez-Zorrilla, J. M. Tetrahydroxy-p-benzoquinone as a source of polydentate O-donor ligands. Synthesis, crystal structure, and magnetic properties of the [Cu(bpy)(dhmal)]₂ dimer and the two-dimensional [{SiW₁₂O₄₀}{Cu₂(bpy)₂(H₂O)(ox)}₂]·16H₂O inorganic-metalorganic hybrid. Inorg. Chem. 2007, 46, 1237–1249. doi: 10.1021/ic061671m
7. [7]
  Sato, R.; Suzuki, K.; Sugawa, M.; Mizuno, N. Heterodinuclear lanthanoid-containing polyoxometalates: stepwise synthesis and single-molecule magnet behavior. Chem. Eur. J. 2013, 19, 12982–12990. doi: 10.1002/chem.201302596
8. [8]
  Gao, N.; Sun, H.; Dong, K.; Ren, J.; Duan, T.; Xu, C.; Qu, X. Transition-metal-substituted polyoxometalate derivatives as functional anti-amyloid agents for Alzheimer's disease. Nat. Commun. 2014, 5, 3422. doi: 10.1038/ncomms4422
9. [9]
  Rhule, J. T.; Hill, C. L.; Judd, D. A.; Schinazi, R. F. Polyoxometalates in medicine. Chem. Rev. 1998, 98, 327–357. doi: 10.1021/cr960396q
10. [10]
  Han, X. B.; Li, Y. G.; Zhang, Z. M.; Tan, H. Q.; Lu, Y.; Wang, E. B. Polyoxometalate-based nickel clusters as visible light-driven water oxidation catalysts. J. Am. Chem. Soc. 2015, 137, 5486–5493. doi: 10.1021/jacs.5b01329
11. [11]
  Yu, L.; Du, X.; Ding, Y.; Chen, H.; Zhou, P. Efficient visible light-driven water oxidation catalyzed by an all-inorganic copper-containing polyoxometalate. Chem. Commun. 2015, 51, 17443–17446. doi: 10.1039/C5CC07119D
12. [12]
  Wang, S. S.; Yang, G. Y. Recent advances in polyoxometalate-catalyzed reactions. Chem. Rev. 2015, 115, 4893–4962. doi: 10.1021/cr500390v
13. [13]
  Du, D. Y.; Qin, J. S.; Li, S. L.; Su, Z. M.; Lan, Y. Q. Recent advances in porous polyoxometalate-based metal-organic framework materials. Chem. Soc. Rev. 2014, 43, 4615–4632. doi: 10.1039/C3CS60404G
14. [14]
  Sha, J. Q.; Yang, X. Y.; Zhu, P. P.; Lan, Y. Q.; Sheng, N. Two new silver triazole frameworks with polyoxometalate templates. RSC Adv. 2016, 6, 108328–108334. doi: 10.1039/C6RA23809B
15. [15]
  Zhu, P. P.; Sheng, N.; Li, M. T.; Li, J. S.; Liu, G. D.; Yang, X. Y.; Sha, J. Q.; Zhu, M. L.; Jiang, J. Z. Fabrication and electrochemical performance of unprecedented POM-based metal-carbene frameworks. J. Mater. Chem. A. 2017, 5, 17920–17925. doi: 10.1039/C7TA05254E
16. [16]
  Yang, X. Y.; Wei, T.; Li, J. S.; Sheng, N.; Zhu, P. P.; Sha, J. Q.; Wang, T.; Lan, Y. Q. Polyoxometalate-incorporated metallapillararene/metallacalixarene metal-organic frameworks as anode materials for lithium ion batteries. Inorg. Chem. 2017, 56, 8311–8318. doi: 10.1021/acs.inorgchem.7b00995
17. [17]
  Li, D.; Ma, X.; Wang, Q.; Ma, P.; Niu, J.; Wang, J. Copper-containing polyoxometalate-based metal-organic frameworks as highly efficient heterogeneous catalysts toward selective oxidation of alkylbenzenes. Inorg. Chem. 2019, 58, 15832–15840. doi: 10.1021/acs.inorgchem.9b02189
18. [18]
  Zhou, E. L.; Qin, C.; Huang, P.; Wang, X. L.; Chen, W. C.; Shao, K. Z.; Su, Z. M. A stable polyoxometalate-pillared metal-organic framework for proton-conducting and colorimetric biosensing. Chem. Eur. J. 2015, 21, 11894–11898. doi: 10.1002/chem.201501515
19. [19]
  Yang, X.; Zhu, P.; Ren, J.; Chen, Y.; Li, X.; Sha, J.; Jiang, J. Surfactant-assisted synthesis and electrochemical properties of an unprecedented polyoxometalate-based metal-organic nanocaged framework. Chem. Commun. 2019, 55, 1201–1204. doi: 10.1039/C8CC08559E
20. [20]
  Li, X.; Yang, X. Y.; Sha, J. Q.; Han, T.; Du, C. J.; Sun, Y. J.; Lan, Y. Q. POMOF/SWNT nanocomposites with prominent peroxidase-mimicking activity for l-cysteine "On-Off Switch" colorimetric biosensing. ACS Appl. Mater. Interfaces. 2019, 11, 16896–16904. doi: 10.1021/acsami.9b00872
21. [21]
  Brese, N. E.; O'keeffe, M. Bond-valence parameters for solids. Acta Crystallograp. Sect. B Struct. Sci. 1991, 47, 192–197. doi: 10.1107/S0108768190011041
22. [22]
  Wang, S. S.; Yang, W. B.; Yang, M.; Wu, X. Y.; Wu, W.; Wang, S. X.; Lin, L.; Lu, C. Z. A bi-polyoxometallate-based host-guest metal-organic framework. Chem. Commun. 2020, 56, 2503–2506. doi: 10.1039/C9CC09008H
23. [23]
  Chen, D. M.; Zheng, Y. P.; Shi, D. Y.; Fang, S M. An acid-base resistant polyoxometalate-based metal-organic framework constructed from {Cu₄Cl}⁷⁺ and {Cu₂(CO₂)₄} clusters for photocatalytic degradation of organic dye. J. Solid State Chem. 2020, 287, 121384. doi: 10.1016/j.jssc.2020.121384
24. [24]
  Yang, Y.; Wu, Q.; Guo, Y.; Hu, C.; Wang, E. Efficient degradation of dye pollutants on nanoporous polyoxotungstate-anatase composite under visible-light irradiation. J. Mol. Catal. A-Chem. 2005, 225, 203–212. doi: 10.1016/j.molcata.2004.08.031
25. [25]
  Wang, X.; Li, Y. H.; Zhang, T.; Ma, S. J.; Wang, X. L. Three polyoxometalate-tuned copper complexes based on in situ ligand transformation: syntheses, structures, and properties. J. Coord. Chem. 2020, 73, 2533–2545. doi: 10.1080/00958972.2020.1825698
26. [26]
  Jiao, Y. Q.; Qin, C.; Zang, H. Y.; Chen, W. C.; Wang, C. G.; Zheng, T. T.; Shao, K. Z.; Su, Z. M. Assembly of organic-inorganic hybrid materials constructed from polyoxometalate and metal-1, 2, 4-triazole units: synthesis, structures, magnetic, electrochemical and photocatalytic properties. CrystEngComm. 2015, 17, 2176–2189. doi: 10.1039/C4CE02007C
27. [27]
  Cong, B. W.; Su, Z. H.; Zhao, Z. F.; Yu, B. Y.; Zhao, W. Q.; Xia, L.; Ma, X. J.; Zhou, B. B. Assembly of six [HxAs₂Mo₆O₂₆]^(6−x)− cluster-based hybrid materials from 1D chains to 3D framework with multiple Cu–N complexes. CrystEngComm. 2017, 19, 2739–2749. doi: 10.1039/C7CE00319F
28. [28]
  Yang, H.; Liu, T.; Cao, M.; Li, H.; Gao, S.; Cao, R. A water-insoluble and visible light induced polyoxometalate-based photocatalyst. Chem. Commun. 2010, 46, 2429–31. doi: 10.1039/b919868g
29. [29]
  Hao, H. F.; Zhou, W. Z.; Zang, H. Y.; Tan, H. Q.; Qi, Y. F.; Wang, Y. H.; Li, Y. G. Keggin-type polyoxometalate-based metal-organic networks for photocatalytic dye degradation. Chem. Asian J. 2015, 10, 1676–83. doi: 10.1002/asia.201500424
1. [1]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
2. [2]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
3. [3]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
4. [4]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
6. [6]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
7. [7]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Shiqi Xu , Zi Ye , Shuang Shang , Fengge Wang , Huan Zhang , Lianguo Chen , Hao Lin , Chen Chen , Fang Hua , Chong-Jing Zhang . Pairs of thiol-substituted 1,2,4-triazole-based isomeric covalent inhibitors with tunable reactivity and selectivity. Chinese Chemical Letters, 2024, 35(7): 109034-. doi: 10.1016/j.cclet.2023.109034
10. [10]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
11. [11]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
12. [12]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
13. [13]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
14. [14]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
15. [15]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
16. [16]
  Jia-Cheng Hou , Wei Cai , Hong-Tao Ji , Li-Juan Ou , Wei-Min He . Recent advances in semi-heterogenous photocatalysis in organic synthesis. Chinese Chemical Letters, 2025, 36(2): 110469-. doi: 10.1016/j.cclet.2024.110469
17. [17]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
18. [18]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
19. [19]
  Xin He , Feng Liu , Tao Tu . Double redox-mediated intrinsic semiconductor photocatalysis: Practical semi-heterogeneous synthesis. Chinese Chemical Letters, 2025, 36(3): 110621-. doi: 10.1016/j.cclet.2024.110621
20. [20]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(322)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142