Citation: Yu-Lin WU, Ning XIE, Xiao-Fang LI, Zhao-Ming FU, Xin-Tao WU, Qi-Long ZHU. MOF-derived Hierarchical Hollow NiRu-C Nanohybrid for Efficient Hydrogen Evolution Reaction[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1346-1356. doi: 10.14102/j.cnki.0254–5861.2011–3153 shu

MOF-derived Hierarchical Hollow NiRu-C Nanohybrid for Efficient Hydrogen Evolution Reaction

Yu-Lin WU ^{a, b} ,
Ning XIE ^{a, b} ,
Xiao-Fang LI ^b,, ,
Zhao-Ming FU ^e,, ,
Xin-Tao WU ^{b, c, d} ,
Qi-Long ZHU ^{b, c, d,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
d.
University of Chinese Academy of Sciences, Beijing 100049, China
e.
Physics and Electronic Information College, Yunnan Normal University, Kunming 650500, China

Corresponding author: Xiao-Fang LI, lixiaofang@fjirsm.ac.cn Zhao-Ming FU, fuzhm1979@163.com Qi-Long ZHU, qlzhu@fjirsm.ac.cn
Received Date: 2 February 2021
Accepted Date: 31 March 2021

Fund Project: the National Natural Science Foundation of China (NSFC) 21901246the National Natural Science Foundation of China (NSFC) 21905279the Natural Science Foundation of Fujian Province 2020J01116the Natural Science Foundation of Fujian Province 2019J05158

Figures(11)

Designing efficient electrocatalysts for efficient hydrogen evolution is extremely desired but challenging. Herein, we report a facile MOF-assisted strategy to synthesize the hierarchical hollow spherical NiRu-C nanohybrid with closely packed rod-like bulges on the surface. Benefited from the more exposed active sites of NiRu-C nanohybrid and the efficient electron/mass transport in its unique hierarchical hollow spherical nanostructure, the optimized nanohybrid showed excellent performance for alkaline hydrogen evolution with ultralow overpotentials, which are much superior to those of Pt/C and the overwhelming majority of reported electrocatalysts. The interpretation of the reaction mechanism was further discussed with DFT calculations. Our research may provide a guidance for the development of advanced electrocatalysts with controlled morphology and excellent performance for future energy applications.
- hydrogen evolution reaction,
- NiRu,
- hollow spherical nanostructure,
- electrocatalysis
1. [1]
  Yang, Y.; Zhang, K.; Lin, H.; Li, X.; Chan, H. C.; Yang, L.; Gao, Q. MoS₂-Ni₃S₂ heteronanorods as efficient and stable bifunctional electrocatalysts for overall water splitting. ACS Catal. 2017, 7, 2357−2366. doi: 10.1021/acscatal.6b03192
2. [2]
  Du, N.; Wang, C.; Wang, X.; Lin, Y.; Jiang, J.; Xiong, Y. Trimetallic tristar nanostructures: tuning electronic and surface structures for enhanced electrocatalytic hydrogen evolution. Adv. Mater. 2016, 28, 2077–84. doi: 10.1002/adma.201504785
3. [3]
  Ito, Y.; Cong, W.; Fujita, T.; Tang, Z.; Chen, M. High catalytic activity of nitrogen and sulfur co-doped nanoporous graphene in the hydrogen evolution reaction. Angew. Chem. Int. Ed. 2015, 54, 2131–6. doi: 10.1002/anie.201410050
4. [4]
  He, L.; Zhou, D.; Lin, Y.; Ge, R.; Hou, X.; Sun, X.; Zheng, C. Ultrarapid in situ synthesis of Cu₂S nanosheet arrays on copper foam with room-temperature-active iodine plasma for efficient and cost-effective oxygen evolution. ACS Catal. 2018, 8, 3859–3864. doi: 10.1021/acscatal.8b00032
5. [5]
  Wan, C.; Regmi, Y. N.; Leonard, B. M. Multiple phases of molybdenum carbide as electrocatalysts for the hydrogen evolution reaction. Angew. Chem. Int. Ed. 2014, 126, 6525–8. doi: 10.1002/ange.201402998
6. [6]
  Tian, J.; Liu, Q.; Cheng, N.; Asiri, A. M.; Sun, X. Self-supported Cu₃P nanowire arrays as an integrated high-performance three-dimensional cathode for generating hydrogen from water. Angew. Chem. Int. Ed. 2014, 53, 9577–81. doi: 10.1002/anie.201403842
7. [7]
  Zheng, Y.; Jiao, Y.; Zhu, Y.; Li, L. H.; Han, Y.; Chen, Y.; Du, A.; Jaroniec, M.; Qiao, S. Z. Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 2014, 5, 3783. doi: 10.1038/ncomms4783
8. [8]
  Li, L.; Wang, B.; Zhang, G.; Yang, G.; Yang, T.; Yang, S.; Yang, S. Electrochemically modifying the electronic structure of IrO₂ nanoparticles for overall electrochemical water splitting with extensive adaptability. Adv. Energy Mater. 2020, 10, 2001600–9. doi: 10.1002/aenm.202001600
9. [9]
  Zheng, T.; Shang, C.; He, Z.; Wang, X.; Cao, C.; Li, H.; Si, R.; Pan, B.; Zhou, S.; Zeng, J. Intercalated iridium diselenide electrocatalysts for efficient pH-universal water splitting. Angew. Chem. Int. Ed. 2019, 58, 14764–14769. doi: 10.1002/anie.201909369
10. [10]
  Qin, F.; Zhao, Z.; Alam, M. K.; Ni, Y.; Robles-Hernandez, F.; Yu, L.; Chen, S.; Ren, Z.; Wang, Z.; Bao, J. Trimetallic NiFeMo for overall electrochemical water splitting with a low cell voltage. ACS Energy Lett. 2018, 3, 546–554. doi: 10.1021/acsenergylett.7b01335
11. [11]
  Gupta, S.; Patel, M. K.; Miotello, A.; Patel, N. Metal boride-based catalysts for electrochemical water-splitting: a review. Adv. Funct. Mater. 2020, 30, 1906481–28. doi: 10.1002/adfm.201906481
12. [12]
  Zhang, J.; Zhang, Q.; Feng, X. Support and interface effects in water-splitting electrocatalysts. Adv. Mater. 2019, 31, 1808167–19. doi: 10.1002/adma.201808167
13. [13]
  Han, X.; Tong, X.; Liu, X.; Chen, A.; Wen, X.; Yang, N.; Guo, X. Y. Hydrogen evolution reaction on hybrid catalysts of vertical MoS₂ nanosheets and hydrogenated graphene. ACS Catal. 2018, 8, 1828–1836. doi: 10.1021/acscatal.7b03316
14. [14]
  Tang, Q.; Jiang, D. E. Mechanism of hydrogen evolution reaction on 1T-MoS₂ from first principles. ACS Catal. 2016, 6, 4953–4961. doi: 10.1021/acscatal.6b01211
15. [15]
  Bhalothia, D.; Huang, T. H.; Chang, C. W.; Lin, T. H.; Wu, S. C.; Wang, K. W.; Chen, T. Y. High-performance and stable hydrogen evolution reaction achieved by Pt trimer decoration on ultralow-metal loading bimetallic PtPd nanocatalysts. ACS Appl. Energy Mater. 2020, 3, 11142–11152. doi: 10.1021/acsaem.0c02084
16. [16]
  Zou, X.; Zhang, Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev. 2015, 44, 5148–80. doi: 10.1039/C4CS00448E
17. [17]
  Tao, Z.; Wang, T.; Wang, X.; Zheng, J.; Li, X. MOF-derived noble metal free catalysts for electrochemical water splitting. ACS Appl. Mater. Interfaces 2016, 8, 35390–35397. doi: 10.1021/acsami.6b13411
18. [18]
  Tang, Y. J.; Wang, Y.; Wang, X. L.; Li, S. L.; Huang, W.; Dong, L. Z.; Liu, C. H.; Li, Y. F.; Lan, Y. Q. Molybdenum disulfide/nitrogen-doped reduced graphene oxide nanocomposite with enlarged interlayer spacing for electrocatalytic hydrogen evolution. Adv. Energy Mater. 2016, 6, 1600116–7. doi: 10.1002/aenm.201600116
19. [19]
  Marques Mota, F.; Choi, C. H.; Boppella, R.; Lee, J. E.; Kim, D. H. Arising synergetic and antagonistic effects in the design of Ni- and Ru-based water splitting electrocatalysts. J. Mater. Chem. A 2019, 7, 639–646. doi: 10.1039/C8TA08535H
20. [20]
  Zhang, J. Y.; Tian, X.; He, T.; Zaman, S.; Miao, M.; Yan, Y.; Qi, K.; Dong, Z.; Liu, H.; Xia, B. Y. In situ formation of Ni₃Se₄ nanorod arrays as versatile electrocatalysts for electrochemical oxidation reactions in hybrid water electrolysis. J. Mater. Chem. A 2018, 6, 15653–15658. doi: 10.1039/C8TA06361C
21. [21]
  Li, C.; Liu, Y.; Zhuo, Z.; Ju, H.; Li, D.; Guo, Y.; Wu, X.; Li, H.; Zhai, T. Local charge distribution engineered by Schottky heterojunctions toward urea electrolysis. Adv. Energy Mater. 2018, 8, 1801775–8. doi: 10.1002/aenm.201801775
22. [22]
  Chen, S.; Duan, J.; Vasileff, A.; Qiao, S. Z. Size fractionation of two-dimensional sub-nanometer thin manganese dioxide crystals towards superior urea electrocatalytic conversion. Angew. Chem. Int. Ed. 2016, 55, 3804–8. doi: 10.1002/anie.201600387
23. [23]
  Yuan, S.; Feng, L.; Wang, K.; Pang, J.; Bosch, M.; Lollar, C.; Sun, Y.; Qin, J.; Yang, X.; Zhang, P.; Wang, Q.; Zou, L.; Zhang, Y.; Zhang, L.; Fang, Y.; Li, J.; Zhou, H. C. Stable metal-organic frameworks: design, synthesis, and applications. Adv. Mater. 2018, 30, 1704303–35. doi: 10.1002/adma.201704303
24. [24]
  Cao, C.; Ma, D. D.; Xu, Q.; Wu, X. T.; Zhu, Q. L. Semisacrificial template growth of self-supporting MOF nanocomposite electrode for efficient electrocatalytic water oxidation. Adv. Funct. Mater. 2018, 29, 1807418–8.
25. [25]
  Li, X.; Zhao, S.; Zhang, W.; Liu, Y.; Li, R. Ru nanoparticles supported on nitrogen-doped porous carbon derived from ZIF-8 as an efficient catalyst for the selective hydrogenation of p-chloronitrobenzene and p-bromonitrobenzene. Dalton Trans. 2016, 45, 15595–15602. doi: 10.1039/C6DT02678H
26. [26]
  Yang, X.; Zhao, Z.; Yu, X.; Feng, L. Electrochemical hydrogen evolution reaction boosted by constructing Ru nanoparticles assembled as a shell over semimetal Te nanorod surfaces in acid electrolyte. Chem. Commun. 2019, 55, 1490–1493. doi: 10.1039/C8CC09993F
27. [27]
  Li, W.; Liu, Y.; Wu, M.; Feng, X.; Redfern, S. A. T.; Shang, Y.; Yong, X.; Feng, T.; Wu, K.; Liu, Z.; Li, B.; Chen, Z.; Tse, J. S.; Lu, S.; Yang, B. Carbon-quantum-dots-loaded ruthenium nanoparticles as an efficient electrocatalyst for hydrogen production in alkaline media. Adv. Mater. 2018, 30, 1800676–8. doi: 10.1002/adma.201800676
28. [28]
  Kresse, G.; Hafner, J. Ab initio molecular dynamics for liquid metals. Phys. Rev. B 1993, 47, 558–561. doi: 10.1103/PhysRevB.47.558
29. [29]
  Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 1996, 6, 15–50. doi: 10.1016/0927-0256(96)00008-0
30. [30]
  Blochl, P. E. Projector augmented-wave method. Phys. Rev. B 1994, 50, 17953–17979. doi: 10.1103/PhysRevB.50.17953
31. [31]
  Perdew, J. P.; Burke K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868. doi: 10.1103/PhysRevLett.77.3865
32. [32]
  Bi, R.; Zeng, C.; Huang, H.; Wang, X.; Zhang, L. Metal-organic frameworks derived hollow NiS₂ spheres encased in graphene layers for enhanced sodium-ion storage. J. Mater. Chem. A 2018, 6, 14077–14082. doi: 10.1039/C8TA05554H
33. [33]
  Xu, Y.; Yin, S.; Li, C.; Deng, K.; Xue, H.; Li, X.; Wang, H.; Wang, L. Low-ruthenium-content NiRu nanoalloys encapsulated in nitrogen-doped carbon as highly efficient and pH-universal electrocatalysts for the hydrogen evolution reaction. J. Mater. Chem. A 2018, 6, 1376–1381. doi: 10.1039/C7TA09939H
34. [34]
  Liu, Y.; Li, X.; Zhang, Q.; Li, W.; Xie, Y.; Liu, H.; Shang, L.; Liu, Z.; Chen, Z.; Gu, L.; Tang, Z.; Zhang, T.; Lu, S. A general route to fabricate low-ruthenium-based bimetals electrocatalysts for pH-universal hydrogen evolution reaction via carbon quantum dots. Angew. Chem. Int. Ed. 2019, 132, 1735–1743.
35. [35]
  Wang, J.; Wei, Z.; Mao, S.; Li, H.; Wang, Y. Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction. Energy & Environ. Sci. 2018, 11, 800–806.
36. [36]
  Liu, J.; Ding, G.; Yu, J.; Liu, X.; Zhang, X.; Guo, J.; Zhang, J.; Ren, W.; Che, R. Visualizing spatial potential and charge distribution in Ru/N-doped carbon electrocatalysts for superior hydrogen evolution reaction. J. Mater. Chem. A 2019, 7, 18072–18080. doi: 10.1039/C9TA06206H
37. [37]
  Lu, B.; Guo, L.; Wu, F.; Peng, Y.; Lu, J. E.; Smart, T. J.; Wang, N.; Finfrock, Y. Z.; Morris, D.; Zhang, P.; Li, N.; Gao, P.; Ping, Y.; Chen, S. Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media. Nat. Commun. 2019, 10, 631–11. doi: 10.1038/s41467-019-08419-3
38. [38]
  Jiang, P.; Yang, Y.; Shi, R.; Xia, G.; Chen, J.; Su, J.; Chen, Q. Pt-like electrocatalytic behavior of Ru-MoO₂ nanocomposites for the hydrogen evolution reaction. J. Mater. Chem. A 2017, 5, 5475–5485. doi: 10.1039/C6TA09994G
39. [39]
  Li, F.; Han, G. F.; Noh, H. J.; Ahmad, I.; Jeon, I. Y.; Baek, J. B. Mechanochemically assisted synthesis of a Ru catalyst for hydrogen evolution with performance superior to Pt in both acidic and alkaline media. Adv. Mater. 2018, 30, 1803676–7. doi: 10.1002/adma.201803676
40. [40]
  Chen, G.; Wang, T.; Zhang, J.; Liu, P.; Sun, H.; Zhuang, X.; Chen, M.; Feng, X. Accelerated hydrogen evolution kinetics on NiFe-layered double hydroxide electrocatalysts by tailoring water dissociation active sites. Adv. Mater. 2018, 30, 1706279–7. doi: 10.1002/adma.201706279
41. [41]
  Pu, Z.; Amiinu, I. S.; Kou, Z.; Li, W.; Mu, S. RuP₂-based catalysts with platinum-like activity and higher durability for the hydrogen evolution reaction at all pH values. Angew. Chem. Int. Ed. 2017, 129, 11717–11722. doi: 10.1002/ange.201704911
42. [42]
  Mahmood, J.; Li, F.; Jung, S. M.; Okyay, M. S.; Ahmad, I.; Kim, S. J.; Park, N.; Jeong, H. Y.; Baek, J. B. An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction. Nat. Nanotechnol. 2017, 12, 441–446. doi: 10.1038/nnano.2016.304
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