Citation: Long ZHAO, Guan-Fan CHEN, Yi-Hang WEN, Xun-Wen XIAO. Halogen-bonded Cocrystal Based on Tetrathiafulvalene Derivatives[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1277-1283. doi: 10.14102/j.cnki.0254–5861.2011–3150 shu

Halogen-bonded Cocrystal Based on Tetrathiafulvalene Derivatives

Long ZHAO ^{a, c} ,
Guan-Fan CHEN ^a,, ,
Yi-Hang WEN ^b,, ,
Xun-Wen XIAO ^c

a.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
b.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, China
c.
School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China

Corresponding author: Guan-Fan CHEN, chenguanfan@126.com Yi-Hang WEN, wyh@zjnu.edu.cn
Received Date: 2 February 2021
Accepted Date: 24 May 2021

Fund Project: Natural Science Foundation of Zhejiang Province LYY20B020032Ningbo Science and Technology Innovation 2025 2018B10033

Figures(6)

In this paper, two cocrystals 1 and 2 with the same chemical composition [L1.L2] (L1 = bis(4΄-pyridyl)-TTF, L2 = 4, 4΄-diiodophenyl) were synthesized by slow diffusion with different solvent systems. Cocrystals 1 and 2 were characterized by single-crystal X-ray and the purity of these two cocrystals was confirmed by PXRD data. The photocurrent responses of these two cocrystals were also tested. Only cocrystal 1 could generate photocurrent signal when exposed to light. From the crystal structure analysis, the possible reason may come from the different biphenyl conformations in L2.
- tetrathiafulvalene,
- crystal structure,
- halogen bonding,
- photocurrent responses
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