Citation: Da-Yi CHEN, Yan LI, Yi-Heng WU, Zhi-Lin WANG, Shuai-Hua WANG, Qing SU, Bi-Sheng ZHANG, Qing-You ZENG, Shao-Fan WU. Scintillation Properties of Ce³⁺/Tb³⁺ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1337-1345. doi: 10.14102/j.cnki.0254–5861.2011–3146 shu

Scintillation Properties of Ce³⁺/Tb³⁺ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application

Da-Yi CHEN ^{a, b} ,
Yan LI ^{b, c} ,
Yi-Heng WU ^{a, b} ,
Zhi-Lin WANG ^{a, b} ,
Shuai-Hua WANG ^b,, ,
Qing SU ^d ,
Bi-Sheng ZHANG ^d ,
Qing-You ZENG ^d ,
Shao-Fan WU ^b,,

a.
University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100039, China
b.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Collaborative Innovation Center for Optoelectronic Semiconductors and Efficient Devices, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
d.
Fujian Luhai Engineering Investigation & Designing Company, Fuzhou 350007, China

Corresponding author: Shuai-Hua WANG, shwang@fjirsm.ac.cn Shao-Fan WU, sfwu@fjirsm.ac.cn
Received Date: 22 February 2021
Accepted Date: 15 April 2021

Fund Project: the National Natural Science Foundation of China 22075284the National Natural Science Foundation of China 51872287the National Natural Science Foundation of China U2030118Equipment Pre-research Foundation Project of China 61409220309the Financial Support of Fujian Province under 2018Y024the Financial Support of Fujian Province under 2019T3011

Figures(9)

Scintillator is a material that converts high-energy rays into visible light, and has great applications in high-energy physics, medical imaging, and security inspections. As a type of scintillator, scintillation glass has the advantages of low cost, high stability, controllable shape, and ability to be prepared on a large scale. In this paper, a traditional fusion quenching method was used to prepare a cerium-terbium co-doped glass. The green characteristic light of Tb ion was observed at 543 nm. Moreover, through the doping sensitization of Ce ions, the luminescence of Tb was successfully enhanced. The material has high X-ray response sensitivity, complete stability and strong X-ray emission intensity. We use a simple X-ray imaging platform for imaging, and the results show that our glass has a spatial resolution of 7.0 lp/mm.
- scintillators,
- light yield,
- glass,
- X-ray imaging,
- luminescence
1. [1]
  Zanella, G.; Zannoni, R.; Dalligna, R. Nuclear instruments and methods in physics research section a: accelerators, spectrometers, detectors and associated equipment. Nucl. Instr. Meth. A 1994, 345, 198–201. doi: 10.1016/0168-9002(94)90987-3
2. [2]
  Anderson, D. F. Properties of the high-density scintillator cerium fluoride. IEEE T. Nucl. Sci. 1989, 36, 137–140. doi: 10.1109/23.34420
3. [3]
  Blasse, G. Scintillator materials. Chem. Mater. 1994, 6, 1465–1475. doi: 10.1021/cm00045a002
4. [4]
  Murray, R. B.; Meyer, A. Scintillation response of activated inorganic crystals to various charged particles. Phys. Rev. 1961, 122, 815–826. doi: 10.1103/PhysRev.122.815
5. [5]
  Liu, S.; Zheng, S. P.; Tang, C. M. Photoluminescence and radio luminescence properties of Yb³⁺-doped silica glass. Mater. Lett. 2015, 144, 43–45. doi: 10.1016/j.matlet.2015.01.005
6. [6]
  Nguyen, L. Q.; Gabella, G.; Goldblum, B. L.; Laplace, T. A.; Carlson, J. S.; Brubaker, E.; Feng, P. L. Boron-loaded organic glass scintillators. Nucl. Instrum. Meth. A 2021, 988, 164898–7. doi: 10.1016/j.nima.2020.164898
7. [7]
  Ortega-Alfaro, M. C.; Hernández, N.; Cerna, I.; López-Cortés, J. G.; Gómez, E.; Toscano, R. A.; Alvarez-Toledano, C. Novel dinuclear iron (0) complexes from α, β-unsaturated ketones β-positioned with sulfide and sulfoxide groups. J. Organomet. Chem. 2004, 689, 885‒893. doi: 10.1016/j.jorganchem.2003.12.015
8. [8]
  Lecoq, P. On the stabilization of Ce, Tb, and Eu ions with different oxidation states in silica based glasses. J. Alloy. Compd. 2016, 809, 130–139.
9. [9]
  Ronda, C.; Wieczorek, H.; Khanin, V.; Rodnyi, P. Review—scintillators for medical imaging: a tutorial overview. Ecs. J. Solid. State. Sc. 2016, 5, 3121–3125. doi: 10.1149/2.0131601jss
10. [10]
  Wantana, N.; Kaewnuam, E.; Kim, H. J. X-ray/proton and photoluminescence behaviors of Sm³⁺ doped high density tungsten gadolinium borate scintillating glass. J. Alloy. Compd. 2020, 849, 156574–8. doi: 10.1016/j.jallcom.2020.156574
11. [11]
  Lecoq, P. Development of new scintillators for medical applications. Nucl. Instrum. Meth. A 2016, 809, 130–139. doi: 10.1016/j.nima.2015.08.041
12. [12]
  Lecoq, P.; Gektin, A.; Korzhik, M. Inorganic Scintillators for Detecting Systems. Springer International Publishing, Switzerland, 2017, p1–408.
13. [13]
  Kawano, N.; Kawaguchi, N.; Okada, G. Scintillation and dosimetric properties of Ce-doped strontium aluminoborate glasses. J. Non-Cryst. Solids 2017, 030, 0022–3093.
14. [14]
  Saidi, K.; Dammak, M. Crystal structure, optical spectroscopy and energy transfer properties in NaZnPO₄: Ce³⁺, Tb³⁺ phosphors for UV-based LEDs. RSC Adv. 2020, 37, 21867–21875.
15. [15]
  Yi, Z.; Lu, W.; Qian, C.; Zeng, T.; Yin, L. Urchin-like Ce/Tb co-doped GdPO₄ hollow spheres for in vivo luminescence/X-ray bioimaging and drug delivery. Biomater. Sci. 2014, 10, 1404–1411.
16. [16]
  Zhang, W.; Hua, R.; Qi, X.; Zhao, J.; Qin, L.; Liu, T. Photoluminescence properties and energy transfer of Ce³⁺–Tb³⁺ co-doped SrAlF₅ nanorods by a hydrothermal method. CrystEngComm. 2017, 19, 5214–5222. doi: 10.1039/C7CE01054K
17. [17]
  Liang, C.; Gong, X. H.; Huang, J. H. Preparation and spectroscopic properties of Pr³⁺-doped transparent glass-ceramic containing LiYF₄ nanocrystals. Chin. J. Struct. Chem. 2017, 36, 614–620.
18. [18]
  Zhang, H. D.; Wang, S. H.; Wu, S. F. A new copper coordination polymer with magnetic property based on 3-(1, 2, 4-traiazol-1-1-yl) benzoic acid. Chin. J. Struct. Chem. 2017, 036, 2011–1615.
19. [19]
  Chen, J.; Wang, S. H.; Zhang, H. D. Crystal structure and luminescence with relative principles calculation of a new one-dimensional Zn(II) coordination polymer. Chin. J. Struct. Chem. 2017, 36, 711–715.
20. [20]
  Liang, J. X.; Xin, S. L.; Qing, Q. H. Highly efficient eco-friendly X-ray scintillators based on an organic manganese halide. Nat. Commun. 2020, 11, 4329–7. doi: 10.1038/s41467-020-18119-y
21. [21]
  Zhang, Y. H.; Sun, R. J.; Ou, X Y. Metal halide perovskite nanosheet for X-ray high-resolution scintillation-imaging screens. ACS Nano. 2019, 13, 2520–2525. doi: 10.1021/acsnano.8b09484
22. [22]
  Cao, J. T.; Guo, Z.; Zhu, S. Preparation of lead-free two-dimensional-layered (C₈H₁₇NH₃)₂SnBr₄ perovskite scintillators and their application in X-ray imaging. ACS Appl. Mater. Inter. 2020, 12, 19797–19804. doi: 10.1021/acsami.0c02116
23. [23]
  Qiu, Z. H.; Wang, S. H.; Wang, W. Q. Polymer composites entrapped Ce-doped LiYF₄ microcrystals for high-sensitivity X-ray scintillation and imaging. ACS. Appl. Mater. Inter. 2020, 12, 29835–29843.
24. [24]
  Jin, H. H.; Dong, H. S. High-performance next-generation perovskite nanocrystal scintillator for nondestructive X-ray imaging. Adv. Mater. 2018, 1801743–6.
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
3. [3]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
4. [4]
  Jingqi Ma , Huangjie Lu , Junpu Yang , Liangwei Yang , Jian-Qiang Wang , Xianlong Du , Jian Lin . Rational design and synthesis of a uranyl-organic hybrid for X-ray scintillation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100275-100275. doi: 10.1016/j.cjsc.2024.100275
5. [5]
  Xin Dong , Jing Liang , Zhijin Xu , Huajie Wu , Lei Wang , Shihai You , Junhua Luo , Lina Li . Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection. Chinese Chemical Letters, 2024, 35(6): 108708-. doi: 10.1016/j.cclet.2023.108708
6. [6]
  Xiuwen Xu , Quan Zhou , Yacong Wang , Yunjie He , Qiang Wang , Yuan Wang , Bing Chen . Expanding the toolbox of metal-free organic halide perovskite for X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109272-. doi: 10.1016/j.cclet.2023.109272
7. [7]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
8. [8]
  Hong-Jin Liao , Zhu Zhuo , Qing Li , Yoshihito Shiota , Jonathan P. Hill , Katsuhiko Ariga , Zi-Xiu Lu , Lu-Yao Liu , Zi-Ang Nan , Wei Wang , You-Gui Huang . A new class of crystalline X-ray induced photochromic materials assembled from anion-directed folding of a flexible cation. Chinese Chemical Letters, 2024, 35(8): 109052-. doi: 10.1016/j.cclet.2023.109052
9. [9]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
10. [10]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
11. [11]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
12. [12]
  Hui-Juan Wang , Wen-Wen Xing , Zhen-Hai Yu , Yong-Xue Li , Heng-Yi Zhang , Qilin Yu , Hongjie Zhu , Yao-Yao Wang , Yu Liu . Cucurbit[7]uril confined phenothiazine bridged bis(bromophenyl pyridine) activated NIR luminescence for lysosome imaging. Chinese Chemical Letters, 2024, 35(6): 109183-. doi: 10.1016/j.cclet.2023.109183
13. [13]
  Yu Pang , Min Wang , Ning-Hua Yang , Min Xue , Yong Yang . One-pot synthesis of a giant twisted double-layer chiral macrocycle via [4 + 8] imine condensation and its X-ray structure. Chinese Chemical Letters, 2024, 35(10): 109575-. doi: 10.1016/j.cclet.2024.109575
14. [14]
  Leichen Wang , Anqing Mei , Na Li , Xiaohong Ruan , Xu Sun , Yu Cai , Jinjun Shao , Xiaochen Dong . Aza-BODIPY dye with unexpected bromination and high singlet oxygen quantum yield for photoacoustic imaging-guided synergetic photodynamic/photothermal therapy. Chinese Chemical Letters, 2024, 35(6): 108974-. doi: 10.1016/j.cclet.2023.108974
15. [15]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
16. [16]
  Chaohui Zheng , Jing Xi , Shiyi Long , Tianpei He , Rui Zhao , Xinyuan Luo , Na Chen , Quan Yuan . Persistent luminescence encoding for rapid and accurate oral-derived bacteria identification. Chinese Chemical Letters, 2025, 36(1): 110223-. doi: 10.1016/j.cclet.2024.110223
17. [17]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
18. [18]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
19. [19]
  Zhao-Xia Lian , Xue-Zhi Wang , Chuang-Wei Zhou , Jiayu Li , Ming-De Li , Xiao-Ping Zhou , Dan Li . Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules. Chinese Chemical Letters, 2024, 35(8): 109063-. doi: 10.1016/j.cclet.2023.109063
20. [20]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(376)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Scintillation Properties of Ce3+/Tb3+ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application

Metrics

通讯作者: 陈斌, bchen63@163.com

Scintillation Properties of Ce³⁺/Tb³⁺ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application