Citation: Zhong-Xuan XU, Bang-Ping HU, Li-Feng LI, Shi-Fei XU. Homochiral Coordination Polymers from Single Helices to Multiple Helices Controlled by Metal Ions[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1131-1137. doi: 10.14102/j.cnki.0254–5861.2011–3139 shu

Homochiral Coordination Polymers from Single Helices to Multiple Helices Controlled by Metal Ions

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi 563002, China

Corresponding author: Zhong-Xuan XU, xuzhongxuan4201@163.com
Received Date: 22 February 2021
Accepted Date: 21 May 2021

Fund Project: the National Natural Science Foundation of China 21761036

Figures(7)

Helix as essential molecular chiral phenomenon at supramolecular level offers an affective method to study chiral characteristic of homochiral coordination polymers (CPs). Herein, two homochiral CPs [Cd((R)-CBA)₂(3, 5-DIT)]_n ((R)-H₂CBA = (R)-4-(1-carboxyethoxy) benzoic acid, 3, 5-DIT = 3, 5-di(1H-imidazol-1-yl)toluene, 1-R) and [Zn((R)-CBA)(3, 5-DIT)]_n (2-R) were synthesized under hydrothermal conditions. In complex 1-R, only a helical chain was built by chiral ligands (R)-CBA^2-, ancillary ligands 3, 5-DIT and Cd(Ⅱ) ions. After Cd(Ⅱ) ions were replaced by Zn(Ⅱ) ions under similar reaction system, Zn(Ⅱ), (R)-CBA^2- and/or 3, 5-DIT formed six types of helices, resulting in complex 2-R. So, the metal ions played a key role in the construction of helical structures. Complexes 1-R and 2-R were also characterized by elemental analysis, PXRD, TGA, CD and UV-visible absorptions. In addition, complexes 1-R and 2-R exhibited different photoluminescence behaviors in solid sate compared to free ligand (R)-H₂CBA.
- homochiral coordination polymers,
- helical chain,
- metal ion effect,
- supramolecular framework
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