Citation: Cheng-Peng WANG, Chiranjeevulu KASHI, Xiao-Liang YE, Wen-Hua LI, Guan-E WANG, Gang XU. A Zinc Based Coordination Polymer: Multi-functional Material for Humidity Sensor and Fluorescence Applications[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1138-1144. doi: 10.14102/j.cnki.0254–5861.2011–3133 shu

A Zinc Based Coordination Polymer: Multi-functional Material for Humidity Sensor and Fluorescence Applications

Cheng-Peng WANG ^{a, b} ,
Chiranjeevulu KASHI ^b ,
Xiao-Liang YE ^b ,
Wen-Hua LI ^b ,
Guan-E WANG ^{b, e,,} ,
Gang XU ^{b, c, d}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
e.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle (Nanchang Hangkong University), Nanchang 330063, China

Corresponding author: Guan-E WANG, gewang@fjirsm.ac.cn
Received Date: 4 February 2021
Accepted Date: 9 March 2021

Fund Project: the National Natural Science Foundation of China 21822109the National Natural Science Foundation of China 2020000052the National Natural Science Foundation of China 21905280the National Natural Science Foundation of China 21975254the National Natural Science Foundation of China 21950410532the National Natural Science Foundation of China 24074283Key Research Program of Frontier Science, CAS QYZDB-SSW-SLH023International Partnership Program of CAS 121835KYSB201800the Natural Science Foundation of Fujian Province 2017J05094China Post-doctoral Science Foundation 2019M662254the Youth Innovation Promotion Association CAS 2018342Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund ES202080085

Figures(5)

Coordination polymers with structurally designable and energy, fluorescence, electrical etc. properties, are expected to become the next generation of multifunctional materials. A new compound, Zn(OAc)SPhNH (HSPhNH₂ = 4-aminophenol), was hydrothermally synthesized using 4-aminophenol as template and balance anion. The single-crystal X-ray diffraction showed a two-dimensional (2D) structure constructed of Zn(OAc)⁺ and SPhNH^-. This compound exhibited typical semiconductive behavior, whose conductivity increased with the raise of temperature. Moreover, the conductivity was positively correlated with humidity. The compound also showed blue light emission property, which indicates great potential applications in light-emitting diodes.
- coordination polymer,
- photoluminescence,
- semiconductor,
- humidity sensor,
- conductivity
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