Citation: Cheng-Peng WANG, Chiranjeevulu KASHI, Xiao-Liang YE, Wen-Hua LI, Guan-E WANG, Gang XU. A Zinc Based Coordination Polymer: Multi-functional Material for Humidity Sensor and Fluorescence Applications[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1138-1144. doi: 10.14102/j.cnki.0254–5861.2011–3133 shu

A Zinc Based Coordination Polymer: Multi-functional Material for Humidity Sensor and Fluorescence Applications

Cheng-Peng WANG ^{a, b} ,
Chiranjeevulu KASHI ^b ,
Xiao-Liang YE ^b ,
Wen-Hua LI ^b ,
Guan-E WANG ^{b, e,,} ,
Gang XU ^{b, c, d}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
e.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle (Nanchang Hangkong University), Nanchang 330063, China

Corresponding author: Guan-E WANG, gewang@fjirsm.ac.cn
Received Date: 4 February 2021
Accepted Date: 9 March 2021

Fund Project: the National Natural Science Foundation of China 21822109the National Natural Science Foundation of China 2020000052the National Natural Science Foundation of China 21905280the National Natural Science Foundation of China 21975254the National Natural Science Foundation of China 21950410532the National Natural Science Foundation of China 24074283Key Research Program of Frontier Science, CAS QYZDB-SSW-SLH023International Partnership Program of CAS 121835KYSB201800the Natural Science Foundation of Fujian Province 2017J05094China Post-doctoral Science Foundation 2019M662254the Youth Innovation Promotion Association CAS 2018342Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund ES202080085

Figures(5)

Coordination polymers with structurally designable and energy, fluorescence, electrical etc. properties, are expected to become the next generation of multifunctional materials. A new compound, Zn(OAc)SPhNH (HSPhNH₂ = 4-aminophenol), was hydrothermally synthesized using 4-aminophenol as template and balance anion. The single-crystal X-ray diffraction showed a two-dimensional (2D) structure constructed of Zn(OAc)⁺ and SPhNH^-. This compound exhibited typical semiconductive behavior, whose conductivity increased with the raise of temperature. Moreover, the conductivity was positively correlated with humidity. The compound also showed blue light emission property, which indicates great potential applications in light-emitting diodes.
- coordination polymer,
- photoluminescence,
- semiconductor,
- humidity sensor,
- conductivity
1. [1]
  Molina-Jorda, J. M. Highly adsorptive and magneto-inductive guefoams (multifunctional guest-containing foams) for enhanced energy-efficient preconcentration and management of VOCs. ACS Appl. Mater. Interfaces 2020, 12, 11702−11712. doi: 10.1021/acsami.9b22858
2. [2]
  Guo, Z. G.; Cao, R.; Wang, X.; Li, H. F.; Yuan, W. B.; Wang, G. J.; Wu, H. H.; Li, J. A multifunctional 3D ferroelectric and NLO-active porous metal-organic framework. J. Am. Chem. Soc. 2009, 131, 6894−6895. doi: 10.1021/ja9000129
3. [3]
  Lee, E. Y.; Jang, S. Y.; Suh, M. P. Multifunctionality and crystal dynamics of a highly stable, porous metal-organic framework [Zn₄O(NTB)₂]. J. Am. Chem. Soc. 2005, 127, 6374−6381. doi: 10.1021/ja043756x
4. [4]
  Salonitis, K.; Pandremenos, J.; Paralikas, J.; Chryssolouris, G. Multifunctional materials: engineering applications and processing challenges. Int. J. Adv. Manuf. Tech. 2009, 49, 803−826.
5. [5]
  Xi, X.; Fang, Y.; Dong, T.; Cui, Y. Bottom-up assembly from a helicate to homochiral micro- and mesoporous metal-organic frameworks. Angew. Chem. Int. Ed. 2011, 50, 1154−1158. doi: 10.1002/anie.201004885
6. [6]
  Jiao, L.; Wang, Y.; Jiang, H. L.; Xu, Q. Metal-organic frameworks as platforms for catalytic applications. Adv. Mater. 2018, 30, 1703663−23. doi: 10.1002/adma.201703663
7. [7]
  Kongpatpanich, K.; Horike, S.; Sugimoto, M.; Kitao, S.; Seto, M.; Kitagawa, S. A porous coordination polymer with a reactive diiron paddlewheel unit. Chem. Commun. 2014, 50, 2292−2294. doi: 10.1039/c3cc47954d
8. [8]
  Lin, W.; Rieter, W. J.; Taylor, K. M. Modular synthesis of functional nanoscale coordination polymers. Angew. Chem. Int. Ed. 2009, 48, 650−658. doi: 10.1002/anie.200803387
9. [9]
  Mo, K.; Yang, Y.; Cui, Y. A homochiral metal-organic framework as an effective asymmetric catalyst for cyanohydrin synthesis. J. Am. Chem. Soc. 2014, 136, 1746−1749. doi: 10.1021/ja411887c
10. [10]
  Liang, L. F.; Jiang, F. L.; Chen, Q. H.; Yuan, D. Q.; Hong, M. C. Ultra-microporous metal-organic framework with high concentration of free carboxyl groups and Lewis basic sites for CO₂ capture at ambient conditions. Chin. J. Struct. Chem. 2019, 38, 559−565.
11. [11]
  Li, J. R.; Sculley, J.; Zhou, H. C. Metal-organic frameworks for separations. Chem. Rev. 2012, 112, 869−932. doi: 10.1021/cr200190s
12. [12]
  Dinca, M.; Long, J. R. Hydrogen storage in microporous metal-organic frameworks with exposed metal sites. Angew. Chem. Int. Ed. 2008, 47, 6766−6779. doi: 10.1002/anie.200801163
13. [13]
  Tang, J.; Salunkhe, R. R.; Liu, J.; Torad, N. L.; Imura, M.; Furukawa, S.; Yamauchi, Y. Thermal conversion of core-shell metal-organic frameworks: a new method for selectively functionalized nanoporous hybrid carbon. J. Am. Chem. Soc. 2015, 137, 1572−1580. doi: 10.1021/ja511539a
14. [14]
  Xia, W.; Mahmood, A.; Zou, R.; Xu, Q. Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion. Energy Environ. Sci. 2015, 8, 1837−1866. doi: 10.1039/C5EE00762C
15. [15]
  Huang, J.; He, Y.; Yao, M. S.; He, J.; Xu, G.; Zeller, M.; Xu, Z. A semiconducting gyroidal metal-sulfur framework for chemiresistive sensing. J. Mater. Chem. A 2017, 5, 16139−16143. doi: 10.1039/C7TA02069D
16. [16]
  Sun, L.; Campbell, M. G.; Dinca, M. Electrically conductive porous metal-organic frameworks. Angew. Chem. Int. Ed. 2016, 55, 3566−3579. doi: 10.1002/anie.201506219
17. [17]
  Yao, M. S.; Tang, W. X.; Wang, G. E.; Nath, B.; Xu, G. MOF thin film-coated metal oxide nanowire array: significantly improved chemiresistor sensor performance. Adv. Mater. 2016, 28, 522−5234.
18. [18]
  Wang, W.; Wen, W. F.; Liu, C. S.; He, L. F.; Zhang, Y.; Yang, S. L.; Chen, W. T. Syntheses, structures, solid-state photoluminescence and optical band gaps of two novel heterometallic lanthanide/mercury compounds. J. Solid State Chem. 2020, 291, 121623−7. doi: 10.1016/j.jssc.2020.121623
19. [19]
  Chen, L. Z.; Ji, Q.; Dan, Y. Y. Synthesis, structure, and luminescent and dielectric properties of two novel 1D chains based on a t-shaped tripodal ligand 4-(4, 5-dicarboxy-1H-imidazol-2-yl)pyridineloxide. Chin. J. Struct. Chem. 2016, 35, 1728−1735.
20. [20]
  Chen, W. T. Synthesis, structure and photophysical properties of a new zinc compound. Inorg. Nano. Met. Chem. 2020, 50, 1295−1301. doi: 10.1080/24701556.2020.1745840
21. [21]
  Gu, X. Y.; Jin, C. C.; Cheng, J. W. A series of lanthanide-organic frameworks constructed by Ln₄(OH)₄ clusters and mixed ligands. Chin. J. Struct. Chem. 2019, 38, 103−108.
22. [22]
  Liu, G. N.; Zhu, W. J.; Zhang, M. J.; Xu, B.; Liu, Q. S.; Zhang, Z. W.; Li, C. C. Syntheses, crystal and band structures, and optical properties of a selenidoantimonate and an iron polyselenide. J. Solid State. Chem. 2014, 218, 109−115. doi: 10.1016/j.jssc.2014.06.012
23. [23]
  Lustig, W. P.; Li, J. Luminescent metal-organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices. Coor. Chem. Rev. 2018, 373, 116−147. doi: 10.1016/j.ccr.2017.09.017
24. [24]
  Wu, Q. Q.; Wen, Y. H. Hydrothermal syntheses, crystal structures and luminescence properties of Zn(II) and Cu(II) complexes based on 2, 2΄-((sulfonylbis(4, 1-phenylene))bis(oxy))diacetic acid. Chin. J. Struct. Chem. 2019, 39, 294−300.
25. [25]
  Wei, X. J.; Li, Y. H.; Qin, Z. B.; Cui, G. H. Two zinc(II) coordination polymers for selective luminescence sensing of iron(III) ions and photocatalytic degradation of methylene blue. J. Mol. Struct. 2019, 1175, 253−260. doi: 10.1016/j.molstruc.2018.08.001
26. [26]
  Liu, R. S.; Drozd, V.; Bagkar, N.; Shen, C. C.; Baginskiy, I.; Chen, C. H.; Tan, C. H. Direct white light phosphor based on metallorganic coordination extended networks for UV-light-emitting diodes. J. Electrochem. Soc. 2008, 155, 71−73.
27. [27]
  Cai, M. L.; Wang, G. E.; Yao, M. S.; Wu, G. D.; Li, Y. Z.; Xu, G. Semiconductive 1D nanobelt iodoplumbate hybrid with high humidity response. Inorg. Chem. Commun. 2018, 93, 42−46. doi: 10.1016/j.inoche.2018.05.002
28. [28]
  Lv, X. J.; Yao, M. S.; Wang, G. E.; Li, Y. Z.; Xu, G. A new 3D cupric coordination polymer as chemiresistor humidity sensor: narrow hysteresis, high sensitivity, fast response and recovery. Sci. China Chem. 2017, 60, 1197−1204.
29. [29]
  Chen, Z.; Luo, D.; Kang, M.; Lin, Z. New semiconducting coordination polymers from zinc sulfide clusters and chains. Inorg. Chem. 2011, 50, 4674−4676. doi: 10.1021/ic2004003
30. [30]
  Sampanthar, J. T.; Vittal, J. J. Syntheses and crystal structures of the dimer [{Zn(SPh)₂(bpy)}₂(mu-bpy)] and two forms of the zigzag coordination polymer [{Zn(SPh)₂ (mu-bpy)}_n], (bpy = 4, 4΄-bipyridyl). J. Chem. Soc. Dalton. 1999, 1993−1997.
31. [31]
  Tian, M.; Fu, Z. H.; Nath, B.; Yao, M. S. Synthesis of large and uniform Cu₃TCPP truncated quadrilateral nano-flake and its humidity sensing properties. RSC. Adv. 2016, 6, 88991−88995. doi: 10.1039/C6RA19403F
32. [32]
  Xie, W.; Liu, B.; Xiao, S.; Li, H.; Wang, Y.; Cai, D.; Wang, D.; Wang, L.; Liu, Y.; Li, Q.; Wang, T. High performance humidity sensors based on CeO₂ nanoparticles. Sens. Actuat. B. Chem. 2015, 215, 125−132. doi: 10.1016/j.snb.2015.03.051
33. [33]
  Wang, L.; He, Y.; Hu, J.; Qi, Q.; Zhang, T. DC humidity sensing properties of BaTiO₃ nanofiber sensors with different electrode materials. Sens. Actuat. B Chem. 2011, 153, 460−464. doi: 10.1016/j.snb.2010.11.016
34. [34]
  Ahmadipour, M.; Ain, M. F.; Ahmad, Z. A. Fabrication of resistance type humidity sensor based on CaCu₃Ti₄O₁₂ thick film. Measurement 2016, 94, 902−908. doi: 10.1016/j.measurement.2016.09.030
35. [35]
  Bi, H. C.; Yin, K. B.; Xie, X.; Ji, J.; Wan, S.; Sun, L. T.; Terrones, M.; Dresselhaus, M. S. Ultrahigh humidity sensitivity of graphene oxide. Sci. Rep. 2013, 3, 2714−7.
36. [36]
  Zhu, Y. C.; Bando, Y.; Xue, D. F.; Golberg, D. Oriented assemblies of ZnS one-dimensional nanostructures. Adv. Mater. 2004, 16, 831−834.
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