Citation: Zhi-Zhuan ZHANG, Jian-Ce JIN, Liao-Kuo GONG, Ke-Zhao DU, Xiao-Ying HUANG. Two New Antimony(III) Chloride Hybrids Composed of Mononuclear [SbCl₆]^3- Unit and Ionic Liquid Cations with Different Length of Alkyl Chain[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1183-1193. doi: 10.14102/j.cnki.0254–5861.2011–3099 shu

Two New Antimony(III) Chloride Hybrids Composed of Mononuclear [SbCl₆]^3- Unit and Ionic Liquid Cations with Different Length of Alkyl Chain

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Liao-Kuo GONG, lkgong@fjirsm.ac.cn Xiao-Ying HUANG, xyhuang@fjirsm.ac.cn
Received Date: 17 January 2021
Accepted Date: 28 January 2021

Fund Project: the National Natural Science Foundation of China 21671187the Natural Science Foundation of Fujian Province 2020J01118

Figures(5)

Two new hybrid chloroantimonates, namely, [Prmim]₃SbCl₆ (1, Prmim = 1-propyl-3-methylimi-dazolium) and [Hmim]₃SbCl₆ (2, Hmim = 1-hexyl-3-methylimidazolium), were synthesized in ionic liquids (ILs) with the yields of 97% and 72%, respectively. Single-crystal X-ray diffraction (SCXRD) study reveals that 1 crystallizes in monoclinic, space group Pn with a = 15.2988(12), b = 13.6388(10), c = 15.6761(13) Å, β = 98.677(7)°, V = 3233.5(4) Å³, Z = 4, D_c = 1.459 g·cm^-3, F(000) = 1440, μ = 1.370 mm^-1, R = 0.0589 and wR = 0.1366 (I > 2σ(I)); 2 crystallizes in the hexagonal space group of P6₃ with a = 27.7471(6), b = 27.7471(6), c = 8.9811(2) Å, V = 5988.2(3) Å³, Z = 6, D_c = 1.391 g·cm^-3, F(000) = 2592, μ = 1.121 mm^-1, R = 0.0420 and wR = 0.0726 (I > 2σ(I)). The photophysical properties of the title compounds were studied by solid-state optical absorption, photoluminescent excitation/emission (PLE/PL), PL decay spectra and photoluminescent quantum yield (PLQY). 1 and 2 exhibit PL peaks at 627 and 607 nm, Stokes shifts of 257 and 242 nm, and PLQY of 32.5% and 49.2%, respectively. The distinct photo physical characteristics of 1 and 2 are highly related to the distortion extent of the [SbCl₆]^3- unit.
- antimony(III) chloride,
- ionic liquid,
- luminescence,
- distortion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Two New Antimony(III) Chloride Hybrids Composed of Mononuclear [SbCl6]3- Unit and Ionic Liquid Cations with Different Length of Alkyl Chain

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通讯作者: 陈斌, bchen63@163.com

Two New Antimony(III) Chloride Hybrids Composed of Mononuclear [SbCl₆]^3- Unit and Ionic Liquid Cations with Different Length of Alkyl Chain