Citation: Wei-Hong YAN, Xian-Cai ZENG. Two New Copper Complexes by H₄AQTC (Anthraquinone-1, 4, 5, 8-tetracarboxylic Acid): Syntheses, Structures and Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 349-356. doi: 10.14102/j.cnki.0254–5861.2011–2923 shu

Two New Copper Complexes by H₄AQTC (Anthraquinone-1, 4, 5, 8-tetracarboxylic Acid): Syntheses, Structures and Properties

Wei-Hong YAN ^, ,
Xian-Cai ZENG

School of Biology and Chemical Engineering, Nanyang Institute of Technology; Henan Key Laboratory of Industrial Microbial Resources and Fermentation Technology, Nanyang 473004, China

Corresponding author: Wei-Hong YAN, yyu_yu@163.com
Received Date: 28 June 2020
Accepted Date: 24 July 2020

Figures(7)

Two new complexes [Cu(AQTC)_0.5(H₂O)₃]·3H₂O}_n (1, H₄AQTC = anthraquinone-1, 4, 5, 8-tetracarboxylic acid) and Cu[(Py)₂C(OH)₂]₂(H₂AQTC)·2H₂O (2, (Py)₂CO = di-2-pyridyl ketone) have been prepared and characterized by elemental analyses and IR spectroscopy. X-ray crystallographic studies show that complex 1 crystallizes in monoclinic space group C2/m and complex 2 in monoclinic space group P2₁/c. Complex 1 features a 1D chain structure by carboxyl oxygen atoms. Complex 2 displays a mononuclear structure and anions and cations are separated. What's interesting is that the ligand of H₄AQTC with eight carboxyl oxygen atoms and two quinone oxygen atoms does not directly coordinate with metals, and only exist as a counter-anion in complex 2. Three-dimensional structures of two complexes are formed by intermolecular interactions. The thermogravimetric analyses of two complexes are investigated. The luminescent properties of complex 1 are investigated as well.
- anthraquinone-1,
- 4, 5, 8-tetracarboxylic acid,
- di-2-pyridyl ketone,
- syntheses,
- crystal structure
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通讯作者: 陈斌, bchen63@163.com

Two New Copper Complexes by H₄AQTC (Anthraquinone-1, 4, 5, 8-tetracarboxylic Acid): Syntheses, Structures and Properties