Citation: Yu-Hua GUO, You-Zhu YU, Yong-Sheng NIU, Zhen WANG, Wei-Yun SHI, Xian-Li WU. Solvothermal Synthesis, Crystal Structure and Photocurrent Property of a Ti₆-Core-based Titanium Oxo Cluster[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 357-362. doi: 10.14102/j.cnki.0254–5861.2011–2921 shu

Solvothermal Synthesis, Crystal Structure and Photocurrent Property of a Ti₆-Core-based Titanium Oxo Cluster

a.
Henan Joint International Research Laboratory of Nanocomposite Sensing Materials, School of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: You-Zhu YU, 119yyz@163.com
Received Date: 28 June 2020
Accepted Date: 11 August 2020

Fund Project: the National Natural Science Foundation of China 21702005the Foundation of the Henan Joint International Research Laboratory of Nanocomposite Sensing Materials and the Foundation of Anyang Institute of Technology YPY2019003

Figures(7)

A Ti₆-core-based titanium oxo cluster (TOC) [Ti₆(μ₂-O)₂(μ₃-O)₂(Bpo)₂(PhCOO)₈(OiPr)₄] assembled by 2, 2΄-biphenol (H₂Bpo) and benzoic acid has been synthesized and characterized by IR, elemental analyses, thermogravimetric analysis and X-ray diffraction technique. Single-crystal X-ray diffraction analysis revealed that the complex crystallizes in monoclinic system, space group P2₁/n. The structure contains two Ti₃(μ₃-O) units featuring a flat mode as building blocks. Solid-state UV/Vis absorption spectrum reveals that complex 1 shows a wide range from 240 to 650 nm. Moreover, the optical band gap of 1 is estimated to be 2.35 eV. Additionally, the Ti₆-TOC exhibits good photocurrent response.
- titanium oxo cluster,
- crystal structure,
- band gap,
- photocurrent response
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Solvothermal Synthesis, Crystal Structure and Photocurrent Property of a Ti6-Core-based Titanium Oxo Cluster

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通讯作者: 陈斌, bchen63@163.com

Solvothermal Synthesis, Crystal Structure and Photocurrent Property of a Ti₆-Core-based Titanium Oxo Cluster