Citation: Hua ZHANG, Liu-Qing JI, Yu-Zhu SONG, Zhi-Guo KONG, Cong LI, Xiu-Yan WANG. Syntheses, Crystal Structures and Properties of Mn(II) and Co(II) Coordination Complexes Based on 1, 10-Phenanthroline Derivative[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 336-342. doi: 10.14102/j.cnki.0254–5861.2011–2901 shu

Syntheses, Crystal Structures and Properties of Mn(II) and Co(II) Coordination Complexes Based on 1, 10-Phenanthroline Derivative

Hua ZHANG ^{a, b, c} ,
Liu-Qing JI ^c ,
Yu-Zhu SONG ^c ,
Zhi-Guo KONG ^{a, b, c} ,
Cong LI ^{a, b, c} ,
Xiu-Yan WANG ^{a, b, c,,}

a.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Changchun 130103, China
b.
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Ministry of Education, Changchun 130103, China
c.
Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: Xiu-Yan WANG, wangxiuyanjlnu2004@163.com
Received Date: 10 June 2020
Accepted Date: 7 August 2020

Fund Project: the National Natural Science Foundation of China 21805110

Figures(8)

Two new coordination complexes [Mn(L)₂(DNSA)] (1) and [Co(L)(1, 4-bdc)]_n (2) have been achieved under hydrothermal conditions (H₂DNSA = 3, 5-dinitro-salicylic acid, 1, 4-bdc = 1, 4-benzenedicarboxylic acid and L = 2-(2-fluoro-6-fluorophenyl)-1H-imidazo[4, 5-f][1, 10]phenanthroline). 1 crystallizes in monoclinic, space group P2₁/c with a = 15.871(3), b = 17.274(4), c = 16.078(3) Å, β = 113.03(3)^o, V = 4056.6(16) Å³, Z = 4, C₄₅H₂₂Cl₂F₂MnN₁₀O₇, M_r = 978.57, D_c = 1.602 g/cm³, F(000) = 1980, μ(MoKa) = 0.536 mm^–1, R = 0.0437 and wR = 0.1065. 2 belongs to the monoclinic system, space group C2/c with a = 14.665(2), b = 30.856(4), c = 11.237(2) Å, β = 111.166(2)^o, V = 4742.0(12) Å³, Z = 8, C₂₇H₁₄ClCoFN₄O₄, M_r = 517.80, D_c = 1.602 g/cm³, F(000) = 2312, μ(MoKa) = 0.889 mm^–1, R = 0.0364 and wR = 0.0862. The central Mn(II) ion in 1 is six-coordinated by four nitrogen atoms from two L ligands and two oxygen atoms from one DNSA anion. In 2, the two kinds of 1, 4-bdc ligands link neighboring Co(II) atoms to yield a two-dimensional layer structure. The luminescence of 1 has been studied in detail. Moreover, thermal behaviors of 1 and 2 are also investigated.
- crystal structure,
- coordination complex,
- 1, 10-phenanthroline derivative,
- thermal behavior
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