Citation: Hua ZHANG, Liu-Qing JI, Yu-Zhu SONG, Zhi-Guo KONG, Cong LI, Xiu-Yan WANG. Syntheses, Crystal Structures and Properties of Mn(II) and Co(II) Coordination Complexes Based on 1, 10-Phenanthroline Derivative[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 336-342. doi: 10.14102/j.cnki.0254–5861.2011–2901 shu

Syntheses, Crystal Structures and Properties of Mn(II) and Co(II) Coordination Complexes Based on 1, 10-Phenanthroline Derivative

Hua ZHANG ^{a, b, c} ,
Liu-Qing JI ^c ,
Yu-Zhu SONG ^c ,
Zhi-Guo KONG ^{a, b, c} ,
Cong LI ^{a, b, c} ,
Xiu-Yan WANG ^{a, b, c,,}

a.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Changchun 130103, China
b.
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Ministry of Education, Changchun 130103, China
c.
Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: Xiu-Yan WANG, wangxiuyanjlnu2004@163.com
Received Date: 10 June 2020
Accepted Date: 7 August 2020

Fund Project: the National Natural Science Foundation of China 21805110

Figures(8)

Two new coordination complexes [Mn(L)₂(DNSA)] (1) and [Co(L)(1, 4-bdc)]_n (2) have been achieved under hydrothermal conditions (H₂DNSA = 3, 5-dinitro-salicylic acid, 1, 4-bdc = 1, 4-benzenedicarboxylic acid and L = 2-(2-fluoro-6-fluorophenyl)-1H-imidazo[4, 5-f][1, 10]phenanthroline). 1 crystallizes in monoclinic, space group P2₁/c with a = 15.871(3), b = 17.274(4), c = 16.078(3) Å, β = 113.03(3)^o, V = 4056.6(16) Å³, Z = 4, C₄₅H₂₂Cl₂F₂MnN₁₀O₇, M_r = 978.57, D_c = 1.602 g/cm³, F(000) = 1980, μ(MoKa) = 0.536 mm^–1, R = 0.0437 and wR = 0.1065. 2 belongs to the monoclinic system, space group C2/c with a = 14.665(2), b = 30.856(4), c = 11.237(2) Å, β = 111.166(2)^o, V = 4742.0(12) Å³, Z = 8, C₂₇H₁₄ClCoFN₄O₄, M_r = 517.80, D_c = 1.602 g/cm³, F(000) = 2312, μ(MoKa) = 0.889 mm^–1, R = 0.0364 and wR = 0.0862. The central Mn(II) ion in 1 is six-coordinated by four nitrogen atoms from two L ligands and two oxygen atoms from one DNSA anion. In 2, the two kinds of 1, 4-bdc ligands link neighboring Co(II) atoms to yield a two-dimensional layer structure. The luminescence of 1 has been studied in detail. Moreover, thermal behaviors of 1 and 2 are also investigated.
- crystal structure,
- coordination complex,
- 1, 10-phenanthroline derivative,
- thermal behavior
1. [1]
  Eddaoudi, M.; Moler, D. B.; Li, H.; Chen, B.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Acc. Chem. Res. 2001, 34, 319–330. doi: 10.1021/ar000034b
2. [2]
  Yoshii, Y.; Sakai, K.; Hoshino, N.; Takeda, T.; Noro, S.; Nakamura, T.; Akutagawa, T. Crystal-to-crystal structural transformation of hydrogen-bonding molecular crystals of (imidazolium)(3-hydroxy-2-quinoxalinecarboxylate) through H₂O adsorption-desorption. CrystEngComm. 2015, 17, 5962–5969. doi: 10.1039/C4CE02519A
3. [3]
  Kong, Z. G.; Guo, S. N.; Zhao, X. Y.; An, X. An unusual 2D → 3D polythreading framework based on (4)-c sql networks with arms: synthesis, structure and luminescence. Mendeleev Commun. 2016, 26, 52−53. doi: 10.1016/j.mencom.2016.01.020
4. [4]
  Zheng, B. S.; Luo, X.; Wang, Z. X.; Zhang, S. W.; Yun, R. R.; Huang, L.; Zeng, W. J.; Liu, W. L. An unprecedented water stable acylamide-functionalized metal-organic framework for highly efficient CH₄/CO₂ gas storage/separation and acid-base cooperative catalytic activity. Inorg. Chem. Front. 2018, 5, 2355–2363. doi: 10.1039/C8QI00662H
5. [5]
  Sebastian, H.; Andreas, S.; Shobhna, K.; Roland, W.; Roland, A. F. Zinc-1, 4-benzenedicarboxylate-bipyridineframeworks-linker functionalization impacts network topology during solvothermal synthesis. J. Mater. Chem. 2012, 22, 909–918. doi: 10.1039/C1JM14791A
6. [6]
  Han, X.; Xu, Y. X.; Yang, J.; Xu, X.; Li, C. P.; Ma, J. F. Metal-assembled, resorcin[4]arene-based molecular trimer for efficient removal of toxic dichromate pollutants and knoevenagel condensation Reaction. ACS Appl. Mater. Inter. 2019, 11, 15591–15597. doi: 10.1021/acsami.9b02068
7. [7]
  Rubio-Martinez, M.; Avci-Camur, C.; Thornton, A. W.; Imaz, I.; Maspoch, D.; Hill, M. R. New synthetic routes towards MOF production at scale. Chem. Soc. Rev. 2017, 46, 3453–3480. doi: 10.1039/C7CS00109F
8. [8]
  Martin, B. D.; Suzanne, M. N.; Stuart, R. B. Variable length ligands: a new class of bridging ligands for supramolecular chemistry and crystal engineering. Chem. Commun. 2009, 37, 5579–5581.
9. [9]
  Wang, X. Y.; Li, G. T.; Wang, H.; Song, Y.; Liu, D. X; Xu, Z. L. Crystal structure, thermal behavior and luminescence of a new copper coordination polymer constructed with 4-(carboxymethoxy)-benzoic acid. Chin. J. Struct. Chem. 2019, 38, 629–634.
10. [10]
  Mala, N.; Pramendra, K. S. Chemistry and applications of organotin(IV) complexes of Schiff bases. Dalton Trans. 2011, 40, 7077–7121. doi: 10.1039/c0dt01426e
11. [11]
  Lin, Z. J.; Lü, J.; Hong, M. C.; Cao, R. Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications. Chem. Soc. Rev. 2014, 43, 5867–5895. doi: 10.1039/C3CS60483G
12. [12]
  Ferey, G. Microporous solids: from organically templated inorganic skeletons to hybrid frameworks∙∙∙ecumenism in chemistry. Chem. Mater. 2001, 13, 3084–3098. doi: 10.1021/cm011070n
13. [13]
  Wang, X. Y.; He, Y.; Zhao, L. N.; Kong, Z. G. An unusual 2D → 3D polythreading framework based on a long 1, 10-phenanthroline derivative ligand. Inorg. Chem. Commun. 2011, 14, 1186–1189. doi: 10.1016/j.inoche.2011.04.024
14. [14]
  Kong, Z. G.; Han, Q.; Zhang, L.; Liu, D. X.; Hu, B.; Wang, X. Y. A new Cd(II) coordination polymer constructed by 1, 10-phenanthroline derivative: syntheses, structure, physical properties and theoretical calculation. Chin. J. Struct. Chem. 2019, 38, 2141–2147.
15. [15]
  Burla, M. C.; Caliandro, R.; Carrozzini, B.; Cascarano, G. L.; Cuocci, C.; Giacovazzo, C.; Mallamo, M.; Mazzone, A.; Polidori, G. Crystal structure determination and refinement via SIR2014. J. Appl. Cryst. 2015, 48, 306–309. doi: 10.1107/S1600576715001132
16. [16]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. 2015, C71, 3–8.
17. [17]
  Chen, X. M.; Liu, G. F. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions. Chem. Eur. J. 2002, 8, 4811–4817. doi: 10.1002/1521-3765(20021018)8:20<4811::AID-CHEM4811>3.0.CO;2-R
18. [18]
  Zhang, S. H.; Feng, C. Microwave-assisted synthesis, crystal structure and fluorescence of novel coordination complexes with Schiff base ligands. J. Mol. Struct. 2010, 997, 62–66.
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