Citation: Yan XU, Bin LIU, Jie LI, Li GAO. A Manganese(II) Coordination Polymer Constructed from Phosphonate Ligand: Synthesis, Crystal Structure and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 306-310. doi: 10.14102/j.cnki.0254–5861.2011–2852 shu

A Manganese(II) Coordination Polymer Constructed from Phosphonate Ligand: Synthesis, Crystal Structure and Magnetic Properties

Department of Materials Science and Engineering, Suqian College, Suqian 223800, China

Corresponding author: Yan XU, xuyan0511@126.com
Received Date: 20 April 2020
Accepted Date: 16 June 2020

Fund Project: Suqian Sci & Tech Program K201911

Figures(5)

A coordination polymer formulated as [Mn(5-pncH₂)₂H₂O] (1, 5-pncH₃ = 5-phosphono-1-naphthalenecarboxylic acid), was hydrothermally synthesized and magnetically characterized. Compound 1 features a three-dimensional structure in which the inorganic chains of [Mn(O-P-O)]_n are cross-linked by the organic groups of phosphonate ligands. Magnetic measurements of 1 indicate that dominant antiferromagnetic interactions are mediated between the Mn^II centers.
- manganese,
- phosphonate ligand,
- crystal structure,
- magnetic properties
1. [1]
  Kurmoo, M. Magnetic metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1353–1379. doi: 10.1039/b804757j
2. [2]
  Lee, J. Y.; Farha, O. K.; Roberts, J.; Scheidt, K. A.; Nguyen, S. T.; Hupp, J. T. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 2009, 38, 1450–1459. doi: 10.1039/b807080f
3. [3]
  Qin, L.; Hu, J. S.; Huang, L. F.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Syntheses, characterizations, and properties of six metal-organic complexes based on flexible ligand 5-(4-pyridyl)-methoxyl isophthalic acid. Cryst. Growth Des. 2010, 10, 4176–4183. doi: 10.1021/cg100870v
4. [4]
  Du, J. J.; Yuan, Y. P.; Sun, J. X.; Peng, F. M.; Jiang, X.; Qiu, L. G.; Xie, A. J.; Shen, Y. H.; Zhu, J. F. New photocatalysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye. J. Hazard. Mater. 2011, 190, 945–951. doi: 10.1016/j.jhazmat.2011.04.029
5. [5]
  Wen, L. L.; Zhou, L.; Zhang, B. G.; Meng, X. G.; Qu, H.; Li, D. F. Multifunctional amino-decorated metal-organic frameworks: nonlinear-optic, ferroelectric, fluorescence sensing and photocatalytic properties. Mater. Chem. 2012, 22, 22603–22609. doi: 10.1039/c2jm34349e
6. [6]
  Meek, S. T.; Greathouse, J. A.; Allendorf, M. D. Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials. Adv. Mater. 2011, 23, 249–267. doi: 10.1002/adma.201002854
7. [7]
  Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815–5840. doi: 10.1039/C4CS00010B
8. [8]
  Zhang, W.; Xiong, R. G. Ferroelectric metal-organic frameworks. Chem. Rev. 2012, 112, 1163–1195. doi: 10.1021/cr200174w
9. [9]
  Yu, J. J.; Li, X. M.; Liu, B.; Zhou, S. A new Mn(II) complex assembled by 2, 5-dihydroxy-1, 4-benzenedicarboxylic acid and 2, 2´-bipyridine: synthesis, structure and theoretical calculation. Chin. J. Struct. Chem. 2020, 39, 765-771.
10. [10]
  Li, Y.; Wu, J.; Gu, J. Z.; Qiu, W. D.; Feng, A. S. Temperature-dependent syntheses of two manganese(II) coordination compounds based on an ether-bridged tetracarbolylic acid. Chin. J. Struct. Chem. 2020, 39, 727-736.
11. [11]
  Liu, X. G.; Bao, S. S.; Huang, J.; Otsubo, K.; Feng, J. S.; Ren, M.; Hu, F. C.; Sun, Z.; Zheng, L. M.; Wei, S.; Kitagawa, H. Homochiral metal phosphonate nanotubes. Chem. Commun. 2015, 51, 15141–15144. doi: 10.1039/C5CC05647K
12. [12]
  Liu, M.; Feng, J. S.; Bao, S. S.; Zheng, L. M. Formation mechanism and reversible expansionand shrinkage of magnesium based homochiral metal-organic nanotubes. Chem. -Eur. J. 2017, 23, 1086–1092. doi: 10.1002/chem.201603776
13. [13]
  Liu, X. G.; Zhou, K.; Dong, J.; Zhu, C. J.; Bao, S. S.; Zheng, L. M. Homochiral lanthanide phosphonates with brick-wall-shaped layer structures showing chiroptical and catalytical properties. Inorg. Chem. 2009, 48, 1901–1905. doi: 10.1021/ic801689r
14. [14]
  Liu, X. G.; Bao, S. S.; Zheng, L. M.; Li, Y. Z. Polymorphism in homochiral zinc phosphonates. Inorg. Chem. 2008, 47, 5525–5527. doi: 10.1021/ic800663t
15. [15]
  Huang, J.; Ding, H. M.; Xu, Y.; Zeng, D.; Zhu, H.; Zang, D. M.; Bao, S. S.; Ma, Y. Q.; Zheng, L. M. Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers. Nat. Commun. 2017, 8, 2131–2142. doi: 10.1038/s41467-017-02260-2
16. [16]
  Liu, B.; Liu, J. C.; Shen, Y.; Feng, J. S.; Bao, S. S.; Zheng, L. M. Polymorphic layered copper phosphonates: exfoliation and proton conductivity studies. Dalton Trans. 2019, 48, 6539–6545. doi: 10.1039/C9DT00970A
17. [17]
  Jia, J. G.; Feng, J. S.; Huang, X. D.; Bao, S. S.; Zheng, L. M. Homochiral iron(II)-based metal-organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel. Chem. Commun. 2019, 55, 2825–2828. doi: 10.1039/C9CC00506D
18. [18]
  Tian, C. B.; He, Z. Z.; Li, Z. H.; Lin, P.; Du, S. W. Two new ferrimagnetic Mn(II)-carboxylate coordination polymers constructed from 5-tert-butyl isophthalic acid with (5/2, 15/2) and (5/2, 10/2) spin topologies. CrystEngComm. 2011, 13, 3080–3086. doi: 10.1039/c0ce00864h
19. [19]
  Escriche-Tur, L.; Font-Bardia, M.; Belén Albela, B.; Corbella, M. Determination of ZFS parameters from the EPR spectra of mono-, di- and trinuclear Mn(II) complexes: impact of magnetic coupling. Dalton Trans. 2017, 46, 2699–2714. doi: 10.1039/C6DT04012H
20. [20]
  Chandrasekhar, V.; Goura, J.; Sañudo, E. C. Carboxylate-free manganese(II) phosphonate assemblies: synthesis, structure, and magnetism. Inorg. Chem. 2012, 51, 8479–8487. doi: 10.1021/ic301060j
21. [21]
  SAINT. Program for Data Extraction and Reduction. Siemens Analytical X-ray Instruments, Madison, WI 1994–1996.
22. [22]
  SHELXTL (Version 5.0), Reference Manual; Siemens Industrial Automation. Analytical Instruments: Madison, WI 1995.
23. [23]
  Liu, B.; Liu, J. C.; Shen, Y.; Feng, J. S.; Bao, S. S.; Zheng, L. M. Polymorphic layered copper phosphonates: exfoliation and proton conductivity studies. Dalton Trans. 2019, 48, 6539–6545. doi: 10.1039/C9DT00970A
24. [24]
  Liu, B.; Xu, Y.; Bao, S. S.; Huang, X. D.; Liu, M.; Zheng, L. M. Enantioenriched cobalt phosphonate containing Δ-type chains and showing slow magnetization relaxation. Inorg. Chem. 2016, 55, 9521‒9523. doi: 10.1021/acs.inorgchem.6b01854
25. [25]
  Pait, M.; Michael Shatruk, M.; Ray, D. Anion coordination selective [Mn₃] and [Mn₄] assemblies: synthesis, structural diversity, magnetic properties and catechol oxidase activity. Dalton Trans. 2015, 44, 11741–11754. doi: 10.1039/C5DT01157D
1. [1]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
6. [6]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
7. [7]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
8. [8]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
9. [9]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
10. [10]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
11. [11]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
12. [12]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
18. [18]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(317)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142