Citation: Zhi-Guo ZHONG, Jing LI, Yu-Quan FENG. A New Tetra-nuclear Nd(III) Coordination Polymer Based on Linear Azide and Isonicotinate Anions: Synthesis, Thermal Stability and Near-infrared Luminescent Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2046-2052. doi: 10.14102/j.cnki.0254–5861.2011–2847 shu

A New Tetra-nuclear Nd(III) Coordination Polymer Based on Linear Azide and Isonicotinate Anions: Synthesis, Thermal Stability and Near-infrared Luminescent Properties

College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China

Corresponding author: Yu-Quan FENG, yqfeng2008@126.com
Received Date: 13 April 2020
Accepted Date: 29 May 2020

Fund Project: the National Natural Science Foundation of China 21601095

Figures(6)

A novel tetra-nuclear Nd(III) coordination polymer, Nd₄(µ₃-OH)₄(µ₂-H₂O)₂(C₆H₄NO₂)₆(N₃)₂(H₂O)₂ (1, C₆H₄N zide anion), was successfully prepared under hydrothermal conditions and fully characterized by C, H and N elemental analysis, IR spectrum, thermal stability and single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P\begin{document}$ \overline 1 $\end{document}, with Z = 1, a = 8.188(3), b = 12.516(5), c = 12.573(5) Å, α = 107.887(1)°, β = 104.681(2)°, γ = 98.086(6)°, V = 1152.2(8) Å³, M_r = 1533.73, D_c = 2.210 g/cm³, λ = 0.71073 Å, μ = 4.524 mm^–1, F(000) = 736, R = 0.0332 and wR = 0.0901 for 3954 observed reflections with I > 2σ(I) and S = 1.071. The molecular structure of polymer 1 is constructed by four Nd³⁺ cations, four bridging µ₃-OH^– anions, two bridging µ₂-H₂O, six C₆H₄NO₂^– anions, two linear azide anions and two coordinated water molecules. The structure of polymer 1 can be viewed as a 3-D supra-molecular network constructed by O–H···O and O–H···N hydrogen bonds between the adjacent chains. Moreover, its near-infrared luminescence and luminescence quenching for Cu²⁺ cation have also been investigated in detail.
- tetra-nuclear Nd(III) polymer,
- linear azide anion,
- thermal stability,
- near-infrared fluorescent properties
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