Citation: Dong-Xiao WANG, Peng WANG, Jun-Yan CHENG. One Novel Ag(I) Compound Generated from Double Schiff-base Ligand with Quinoxaline-N-oxide as Terminal Binding Sites[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 301-305. doi: 10.14102/j.cnki.0254–5861.2011–2843 shu

One Novel Ag(I) Compound Generated from Double Schiff-base Ligand with Quinoxaline-N-oxide as Terminal Binding Sites

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan 250014, China
b.
College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China

Corresponding author: Peng WANG, pengwang@sdust.edu.cn Jun-Yan CHENG, chengjunyan@sdnu.edu.cn
Received Date: 9 April 2020
Accepted Date: 18 June 2020

Fund Project: NSFC 21671122NSFC 21475078

Figures(5)

One novel discrete coordination molecule with Ag^I centers, namely [Ag₃(L)₃(ClO₄)₃]∙3CH₂Cl₂∙ 6CH₃OH∙1.5H₂O (1), has been synthesized based on the double Schiff-base ligand, 3, 6-bis[2-(4-oxidequinoxaline)-yl]-4, 5-diaza-3, 5-octadiene (L) and AgClO₄. The obtained Ag(I) compound was fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. 1 is of trigonal system space group P-31c with a = 16.320(2), b = 16.320(2), c = 20.108(6) Å, T = 173(2) K, V = 4638.2(16) Å³, D_c = 1.645 g/cm³, M_r = 2297.33, Z = 2, F(000) = 2334, μ = 0.970 mm^–1, Goodness-of-fit = 1.109, the final R = 0.0776, wR = 0.1813, R indices (all data) = 0.1196, wR = 0.2011. The compound exhibits a triple-helical [Ag₃L₃]³⁺ crown-like trimer, in which three Ag(I) atoms form an equilateral triangle with the Ag···Ag distance of 4.7 Å. Uncoordinated counterions ClO₄^– and solvent molecules methanol generate the hydrogen-bonded frameworks based on discrete molecular complex building blocks.
- crystal structure,
- double Schiff-base ligand,
- discrete coordination compound,
- hydrogen bond
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