Citation: Zi-Bin CHEN, Bing-Ben CHEN, Jian-Wen CHENG. Luminescent Lanthanide-titanium-organic Compound Constructed by Tetra-nuclear Ln-Ti Building Units and Diphenylglycolic Acid[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 182-186. doi: 10.14102/j.cnki.0254–5861.2011–2805 shu

Luminescent Lanthanide-titanium-organic Compound Constructed by Tetra-nuclear Ln-Ti Building Units and Diphenylglycolic Acid

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: Jian-Wen CHENG, jwcheng@zjnu.cn
Received Date: 16 March 2020
Accepted Date: 18 May 2020

Fund Project: the NNSF of China 21975224

Figures(2)

Under solvothermal conditions with the mixed solvents of C₂H₅OH and H₂O, a new heterometallic lanthanide-titanium-organic compound, [TbTi(μ₃-O)(L₃)(H₂O)₄]·H₃O (1, H₂L = diphenylglycolic acid), has been synthesized. Compound 1 exhibits a 3D supramolecular framework by incorporating the tetra-nuclear [Tb₂Ti₂(μ₃-O)₂] unit and L^2- ligand. Compound 1 shows intense green luminescence. Furthermore, the PXRD, TGA and IR spectra were also studied.
- lanthanide,
- titanium,
- cluster,
- luminescence
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