Citation: Xin-Hong CHANG, Xiao-Gang YANG, Zhi-Min ZHAI, Jia-Yi CHEN, Fei-Fei LI. Synthesis, Structure and Highly Enhanced Phosphorescence of a Cadmium(Ⅱ) Coordination Polymer Assembled with 1, 4-Naphthalenedicarboxylic Acid and 2-Propylimidazole[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 187-192. doi: 10.14102/j.cnki.0254–5861.2011–2793 shu

Synthesis, Structure and Highly Enhanced Phosphorescence of a Cadmium(Ⅱ) Coordination Polymer Assembled with 1, 4-Naphthalenedicarboxylic Acid and 2-Propylimidazole

a.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China
b.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

Corresponding author: Xin-Hong CHANG, 12133033@qq.com
Received Date: 2 March 2020
Accepted Date: 15 June 2020

Fund Project: the National Natural Science Foundation of China 21971100the National Natural Science Foundation of China 21771097Key Scientific Research Projects of Higher Education of Henan Province 20A150005Henan Province Natural Science Foundation 182300410166

Figures(5)

One cadmium(Ⅱ) coordination polymer [Cd(1, 4-NDC)(PPIM)₂]_n (1, 1, 4-H₂NDC = 1, 4-naphthalenedicarboxylic acid, PPIM = 2-propylimidazole), has been synthesized under hydrothermal conditions and structurally characterized by elemental analysis, TGA and X-ray single-crystal diffraction. Complex 1 crystallizes in monoclinic with space group P2₁/n, a = 8.8292(2), b = 16.6936(4), c = 16.7869(4) Å, β = 99.701(2)°, V = 2438.86(10) Å³, Z = 4, D_c = 1.489 Mg/m³, F(000) = 1112, μ = 0.932 mm^–1, S = 1.076, the final R = 0.0360 and wR = 0.0850. In 1, the 1, 4-NDC ligand bridges the Cd(Ⅱ) to form a 1D infinite chain, which are connected through N–H···O hydrogen bond to form a 2D layer then to an overall 3D supramolecular structure. The time-resolved measurements indicate that 1 shows highly prolonged phosphorescent lifetime about 452 times in comparison with that of pristine PPIM ligand. Single-crystal analysis and theory calculations indicate that strong coordination bonds and complete separation of HOMOs and LUMOs in the rigid matrix of 1 promote the long-last phosphorescence emission.
- coordination polymer,
- crystal structure,
- room temperature phosphorescence,
- theory calculations
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