Citation: Ya-Xin XIE, Wan-Wan ZHANG, Zhi-Ying ZHAO, Zhang-Zhen HE. Synthesis, Structure and Properties of a New Molybdate-tellurite Compound with 2D Triangular Lattice[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 96-102. doi: 10.14102/j.cnki.0254–5861.2011–2778 shu

Synthesis, Structure and Properties of a New Molybdate-tellurite Compound with 2D Triangular Lattice

Ya-Xin XIE ^{a, b} ,
Wan-Wan ZHANG ^{a, b} ,
Zhi-Ying ZHAO ^a ,
Zhang-Zhen HE ^a,,

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhang-Zhen HE, hezz@fjirsm.ac.cn; hcz1988@hotmail.com
Received Date: 22 February 2020
Accepted Date: 14 April 2020

Fund Project: the National Natural Science Foundation of China 21573235the National Natural Science Foundation of China U1632159the National Natural Science Foundation of China 21875249

Figures(7)

A new 3d transition-metal molybdate-tellurite (NH₄)₂Co(TeMo₂O₉)₂ was obtained through a conventional hydrothermal method. This compound was confirmed to crystallize in the monoclinic system of space group P2₁/c with a = 10.5133(5), b = 10.6456(5), c = 7.6078(5) Å, β = 108.879(6)º, V = 805.66(8) Å³, Z = 2, M_r = 1021.97, D_c = 4.213 g/cm³, μ = 7.685 mm^–1, F(000) = 930, the final R = 0.0399 and wR = 0.1025 for 1580 observed reflections with I > 2σ(I), showing a tunnel structure with spin triangle-lattice composed by CoO₆ octahedra. Magnetic and heat capacity measurements confirmed a paramagnetic behavior down to 2 K with a negative Weiss temperature of –20 K, suggesting remarkable spin frustration in the system.
- molybdate-tellurite,
- triangular spin-lattice,
- crystal structure,
- magnetic properties
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